Ozone pollution contributes to the yield gap for beans in Uganda, East Africa, and is co-located with other agricultural stresses.

Air quality negatively impacts agriculture, reducing the yield of staple food crops. While measured data on African ground-level ozone levels are scarce, experimental studies demonstrate the damaging impact of ozone on crops. Common beans (Phaseolus vulgaris), an ozone-sensitive crop, are widely grown in Uganda. Using modelled ozone flux, agricultural surveys, and a flux-effect relationship, this study estimates yield and production losses due to ozone for Ugandan beans in 2015. Analysis at this scale allows the use of localised data, and results can be presented at a sub-regional level. Soil nutrient stress, drought, flood risk, temperature and deprivation were also mapped to investigate where stresses may coincide. Average bean yield losses due to ozone were 17% and 14% (first and second growing season respectively), equating to 184 thousand tonnes production loss. However, for some sub-regions, losses were up to 27.5% and other crop stresses also coincided in these areas. This methodology could be applied widely, allowing estimates of ozone impact for countries lacking air quality and/or experimental data. As crop productivity is below its potential in many areas of the world, changing agricultural practices to mitigate against losses due to ozone could help to reduce the crop yield gap.

Representation of investigation results of microplastics on sandy beaches-accumulation rate and abundance in the entire study site.

Long-term microplastics (MPs) environmental pollution trends cannot be understood only by investigating their presence on beaches. Without estimating MPs for the entire beach, comparisons between multiple beaches cannot be made. In this study, Nagasaki Prefecture was selected as the study site, we measured MPs accumulation rate to express the MPs pollution trend and weighted the measurement results to enable comparison of MPs content among multiple sandy beaches. The MPs accumulation rate in the study site was measured by periodic investigation at fixed spots. The average in the supratidal zone was 1.5 ± 0.9 mg-MPs/(m2-sand⋅ d) (n = 15). The weighting of the MPs content in hot spots and non-hot spots by their respective areas enabled us to obtain the representative value and the dispersion of the MPs content in the entire study site. The MPs contents in the three beaches were 298 ± 144, 1,115 ± 518, and 4,084 ± 2,243 mg-MPs/(m2-sand), respectively. Using these values, it is possible to compare the MPs contents of multiple beaches.

Environmental plastics in the context of UV radiation, climate change, and the Montreal Protocol.

There are close links between solar UV radiation, climate change, and plastic pollution. UV-driven weathering is a key process leading to the degradation of plastics in the environment but also the formation of potentially harmful plastic fragments such as micro- and nanoplastic particles. Estimates of the environmental persistence of plastic pollution, and the formation of fragments, will need to take in account plastic dispersal around the globe, as well as projected UV radiation levels and climate change factors.

Climate warming shifts riverine macroinvertebrate communities to be more sensitive to chemical pollutants.

Freshwaters are highly threatened ecosystems that are vulnerable to chemical pollution and climate change. Freshwater taxa vary in their sensitivity to chemicals and changes in species composition can potentially affect the sensitivity of assemblages to chemical exposure. Here we explore the potential consequences of future climate change on the composition and sensitivity of freshwater macroinvertebrate assemblages to chemical stressors using the UK as a case study. Macroinvertebrate assemblages under end of century (2080-2100) and baseline (1980-2000) climate conditions were predicted for 608 UK sites for four climate scenarios corresponding to mean temperature changes of 1.28 to 3.78°C. Freshwater macroinvertebrate toxicity data were collated for 19 chemicals and the hierarchical species sensitivity distribution model was used to predict the sensitivity of untested taxa using relatedness within a Bayesian approach. All four future climate scenarios shifted assemblage compositions, increasing the prevalence of Mollusca, Crustacea and Oligochaeta species, and the insect taxa of Odonata, Chironomidae, and Baetidae species. Contrastingly, decreases were projected for Plecoptera, Ephemeroptera (except for Baetidae) and Coleoptera species. Shifts in taxonomic composition were associated with changes in the percentage of species at risk from chemical exposure. For the 3.78°C climate scenario, 76% of all assemblages became more sensitive to chemicals and for 18 of the 19 chemicals, the percentage of species at risk increased. Climate warming-induced increases in sensitivity were greatest for assemblages exposed to metals and were dependent on baseline assemblage composition, which varied spatially. Climate warming is predicted to result in changes in the use, environmental exposure and toxicity of chemicals. Here we show that, even in the absence of these climate-chemical interactions, shifts in species composition due to climate warming will increase chemical risk and that the impact of chemical pollution on freshwater macroinvertebrate biodiversity may double or quadruple by the end of the 21st century.

Plastics and the Sustainable Development Goals: From waste to wealth with microbial recycling and upcycling.

Plastics pollution has become one of the greatest concerns of the 21st century. To date, around 10 billion tons of plastics have been produced almost exclusively from non-renewable sources, and of these, <10% have been recycled. The majority of discarded plastic waste (>70%) is accumulating in landfills or the environment, causing severe impacts to natural ecosystems and human health. Considering how plastics are present in every aspect of our daily lives, it is evident that a transition towards a Circular Economy of plastics is essential to achieve several of the Sustainable Development Goals. In this editorial, we highlight how microbial biotechnology can contribute to this shift, with a special focus on the biological recycling of conventional plastics and the upcycling of plastic-waste feedstocks into new value-added products. Although important hurdles will need to be overcome in this endeavour, recent success stories highlight how interdisciplinary approaches can bring us closer to a bio-based economy for the sustainable management of plastics.

Pollution levels and probability risk assessment of potential toxic elements in soil of Pb-Zn smelting areas.

Soil pollution around Pb-Zn smelters has attracted widespread attention around the world. In this study, we compiled a database of eight potentially toxic elements (PTEs) Pb, Zn, Cd, As, Cr, Ni, Cu, and Mn in the soil of Pb-Zn smelting areas by screening the published research papers from 2000 to 2023. The pollution assessment and risk screening of eight PTEs were carried out by geo-accumulation index (Igeo), potential ecological risk index (PERI) and health risk assessment model, and Monte Carlo simulation employed to further evaluate the probabilistic health risks. The results suggested that the mean values of the eight PTEs all exceeded the corresponding values in the upper crust, and more than 60% of the study sites had serious Pb and Cd pollution (Igeo > 4), with Brazil, Belgium, China, France and Slovenia having higher levels of pollution than other regions. Besides, PTEs in smelting area caused serious ecological risk (PERI = 10912.12), in which Cd was the main contributor to PREI (86.02%). The average hazard index (HI) of the eight PTEs for adults and children was 7.19 and 9.73, respectively, and the average value of total carcinogenic risk (TCR) was 4.20 × 10-3 and 8.05 × 10-4, respectively. Pb and As are the main contributors to non-carcinogenic risk, while Cu and As are the main contributors to carcinogenic risk. The probability of non-carcinogenic risk in adults and children was 84.05% and 97.57%, while carcinogenic risk was 92.56% and 79.73%, respectively. In summary, there are high ecological and health risks of PTEs in the soil of Pb-Zn smelting areas, and Pb, Cd, As and Cu are the key elements that cause contamination and risk, which need to be paid attention to and controlled. This study is expected to provide guidance for soil remediation in Pb-Zn smelting areas.

Comparative analysis of sediment quality indices using different reference values in an environmental protection area in Southeastern Brazil.

Contamination of aquatic ecosystems by potentially toxic elements (PTEs) is a concerning environmental issue, given their persistence, toxicity potential, and ability to accumulate in living organisms. Several studies have been conducted to assess the contamination of aquatic ecosystems by PTEs, using pollution and ecological risk indices that rely on the concentration of these elements in aquatic sediments. However, many of these studies use global reference values for calculating the indices, which can lead to misleading interpretations due to substantial variations in PTEs concentrations influenced by the geological characteristics of each region. Therefore, the use of regional reference values is more appropriate when available. This study aimed to investigate variations in the results of five indices, employing global, regional, and quality reference values, based on sediment samples collected from rivers in the Ipanema National Forest, a protected area in Brazil exposed to various anthropogenic pressures. The results revealed that elements such as Al, Fe, and Mn exceeded the limits allowed by legislation in water samples, while As and Cr surpassed the limits in sediment samples. Comparative analysis highlighted significant discrepancies in the results of the indices when global reference values were used compared to regional and quality reference values, especially for As and Ba. Thus, this study underscores the importance of establishing specific regional values for an accurate assessment of sediment quality and the risks associated with contamination by PTEs in different regions worldwide.

Methylated derivatives of polycyclic aromatic hydrocarbons in road dust, green belt soil and parking lot dust: occurrence, spatial distribution and emission sources.

Convenient transportation facilities not only bring the higher standard of living to big cities, but also bring some environmental pollution problems. In order to understand the presence and sources of methylated polycyclic aromatic hydrocarbons (Me-PAHs) in environmental samples and their association with total organic carbon (TOC), 49 Me-PAHs were analyzed in road dust, green belt soil and parking lot dust samples in Harbin. The results showed that the ranges of the total Me-PAHs (ΣMe-PAHs) content in road dust were 221-5826 ng/g in autumn and 697-7302 ng/g in spring, and those in green belt soil were 170-2509 ng/g and 155-9215 ng/g in autumn and spring, respectively. And ΣMe-PAHs content in parking lot dust ranged from 269 to 2515 ng/g in surface parking lots and from 778 to 10,052 ng/g in underground parking lots. In these samples, the composition profile of Me-PAHs was dominated by 4-ring Me-PAHs. The results of diagnostic ratios and principal component analysis (PCA) indicated that petrogenic and pyrogenic sources were the main sources of Me-PAHs in the samples. Spearman correlation analysis showed that there was no correlation for Me-PAHs in road dust and green belt soil on the same road. Furthermore, there was a significant positive relationship (0.12 ≤ R2 ≤ 0.67, P < 0.05) between Me-PAHs concentrations and the TOC content. This study demonstrated the presence of Me-PAHs with high concentrations in the road environment samples of Harbin.

Bibliometric analysis of global performance and trends of research on combined sewer overflows (CSOs) from 1990 to 2022.

Combined sewer overflows (CSOs) are one of the main sources of pollution in urban water systems and significantly impede the restoration of water body functionalities within urban rivers and lakes. To understand the research and frontier trends of CSOs comprehensively and systematically, a visual statistical analysis of the literature related to CSOs in the Web of Science core database from 1990 to 2022 was conducted using the bibliometric method using HistCite Pro and VOSviewer. The results reveal a total of 1,209 pertinent publications related to CSOs from 1990 to 2022, and the quantity of CSOs-related publications indicated an increasing trend. Investigations of the distribution and fate of typical pollutants in CSOs and their ecological effects on receiving waters and studies on pollution control technologies (source reduction, process control, and end-of-pipe treatment) are the current focus of CSOs research. CSOs pollution control technologies based on source reduction and the monitoring and control of emerging contaminants are at the forefront of scientific investigations on CSOs. This study systematically and comprehensively summarized current research topics and future research directions of CSOs, thus providing a reference for CSOs control and water environment management research.

Investigation of organic micropollutant pollution in Izmit Bay: a comparative study of passive sampling and instantaneous sampling techniques.

In this study, we used a comprehensive array of sampling techniques to examine the pollution caused by organic micropollutants in Izmit Bay for the first time. Our methodology contains spot seawater sampling, semi-permeable membrane devices (SPMDs) passive samplers for time-weighted average (TWA), and sediment sampling for long-term pollution detection in Izmit Bay, together. Additionally, the analysis results obtained with these three sampling methods were compared in this study. Over the course of two seasons in 2020 and 2021, we deployed SPMDs for 21 days in the first season and for 30 days in the second season. This innovative approach allowed us to gather sea water samples and analyze them for the presence of polycyclic aromatic hydrocarbons (Σ15 PAHs), polychlorinated biphenyls (Σ7 PCBs), and organochlorine pesticides (Σ11 OCPs). Using SPMD-based passive sampling, we measured micropollutant concentrations: PAHs ranged from 1963 to 10342 pg/L in 2020 and 1338 to 6373 pg/L in 2021; PCBs from 17.46 to 61.90 pg/L in 2020 and 8.37 to 78.10 pg/L in 2021; and OCPs from 269.2 to 8868 pg/L in 2020 and 141.7 to 1662 pg/L in 2021. Our findings revealed parallels between the concentrations of PAHs, PCBs, and OCPs in both SPMDs and sediment samples, providing insights into the distribution patterns of these pollutants in the marine ecosystem. However, it is worth noting that due to limited data acquisition, the suitability of spot sampling in comparison to instantaneous sampling remains inconclusive, highlighting the need for further investigation and data collection.

Evaluation of soil pollution by heavy metal using index calculations and multivariate statistical analysis.

This study aims to assess the extent of heavy metals (HMs) pollution in soil and identify its potential sources using single and integrated pollution index calculations, and multivariate statistical analysis. The HM concentrations of soil samples were analyzed using ICP-MS. The concentrations (mg/kg) of arsenic (As) ranged from 2.8 to 208.1, cadmium (Cd) from 0.1 to 0.3, cobalt (Co) from 1.9 to 20.5, copper (Cu) from 3.7 to 17.7, nickel (Ni) from 14.7 to 110.6, and lead (Pb) from 6.7 to 37.3. High levels of As contents and physicochemical parameters were found in the northeastern parts of the study area, while levels of other HMs were high in the remaining parts. The HM contents of some soil samples exceeded the average values of basalt and limestone in the study area, as well as the upper, bulk, and lower continental crusts, shale, and soil (worldwide). Multiple index methods were used to assess the pollution risk, and it was determined that some soil samples were moderately to considerably contaminated with varying levels of As, Cd, Co, Ni, and Pb. Multivariate statistical analyses provided that the source of HMs contamination in the soil was a result of geogenic and/or anthropogenic activities. Geogenic sources were associated with weathering rock units, while anthropogenic sources were linked to industrial activities, traffic emissions, and agricultural applications. The findings are useful for detecting contamination by HMs in soil, and they could contribute to future monitoring programs to prevent soil contamination and protect the health of living organisms.

Associations between transport modes and site-specific cancers: a systematic review and meta-analysis.

BACKGROUND: Physical inactivity is a global public health problem. A practical solution would be to build physical activity into the daily routine by using active modes of transport. Choice of transport mode can influence cancer risk through their effects on levels of physical activity, sedentary time, and environmental pollution. This review synthesizes existing evidence on the associations of specific transport modes with risks of site-specific cancers. METHODS: Relevant literature was searched in PubMed, Embase, and Scopus from 1914 to 17th February 2023. For cancer sites with effect measures available for a specific transport mode from two or more studies, random effects meta-analyses were performed to pool relative risks (RR) comparing the highest vs. lowest activity group as well as per 10 Metabolic Equivalent of Task (MET) hour increment in transport-related physical activity per week (∼150 min of walking or 90 min of cycling). RESULTS: 27 eligible studies (11 cohort, 15 case-control, and 1 case-cohort) were identified, which reported the associations of transport modes with 10 site-specific cancers. In the meta-analysis, 10 MET hour increment in transport-related physical activity per week was associated with a reduction in risk for endometrial cancer (RR: 0.91, 95% CI: 0.83-0.997), colorectal cancer (RR: 0.95, 95% CI: 0.91-0.99) and breast cancer (RR: 0.99, 95% CI: 0.89-0.996). The highest level of walking only or walking and cycling combined modes, compared to the lowest level, were significantly associated with a 12% and 30% reduced risk of breast and endometrial cancers respectively. Cycling, compared to motorized modes, was associated with a lower risk of overall cancer incidence and mortality. CONCLUSION: Active transport appears to reduce cancer risk, but evidence for cancer sites other than colorectum, breast, and endometrium is currently limited.

The end-of-life power battery recycling & remanufacturing center location-adjustment problem considering battery capacity and quantity uncertainty.

The booming electric vehicle market has led to an increasing number of end-of-life power batteries. In order to reduce environmental pollution and promote the realization of circular economy, how to fully and effectively recycle the end-of-life power batteries has become an urgent challenge to be solved today. The recycling & remanufacturing center is an extremely important and key facility in the recycling process of used batteries, which ensures that the recycled batteries can be handled in a standardized manner under the conditions of professional facilities. In reality, different adjustment options for existing recycling & remanufacturing centers have a huge impact on the planning of new sites. This paper proposes a mixed-integer linear programming model for the siting problem of battery recycling & remanufacturing centers considering site location-adjustment. The model allows for demolition, renewal, and new construction options in planning for recycling & remanufacturing centers. By adjusting existing sites, this paper provides an efficient allocation of resources under the condition of meeting the demand for recycling of used batteries. Next, under the new model proposed in this paper, the uncertainty of the quantity and capacity of recycled used batteries is considered. By establishing different capacity conditions of batteries under multiple scenarios, a robust model was developed to determine the number and location of recycling & remanufacturing centers, which promotes sustainable development, reduces environmental pollution and effectively copes with the risk of the future quantity of used batteries exceeding expectations. In the final results of the case analysis, our proposed model considering the existing sites adjustment reduces the cost by 3.14% compared to the traditional model, and the average site utilization rate is 15.38% higher than the traditional model. The results show that the model has an effective effect in reducing costs, allocating resources, and improving efficiency, which could provide important support for decision-making in the recycling of used power batteries.

Current situation and prospects for the clean utilization of gold tailings.

Gold tailings are characterized by low-grade, complex composition, fine embedded particle size, environmental pollution, and large land occupation. This paper describes the mineralogical properties of gold tailings, including chemical composition, phase composition, particle size distribution, and microstructure; summarizes the recycling and utilization of components such as mica, feldspar, and valuable metals in gold tailings; reviews harmless treatment measures for harmful elements in gold tailings; and adumbrated the research progress of gold tailings in the application fields of building materials, ceramics, and glass materials. Based on these discussions, a new technology roadmap that combines multistage magnetic separation and cemented filling is proposed for the clean utilization of all components of gold tailings.

Revisiting the relationship between natural resources and environmental quality- can ICT break the "resource curse" in the environment?

Despite the prevalence of discussions on the "resource curse", the impact of natural resources on environmental quality for better or for worse has not been clearly answered, this study aims to answer the question by introducing the role of Information and Communication Technologies (ICT). To that end, by using the Instrumental Variable Generalized Method of Moments (IV GMM) estimator and a sample of 102 developing and emerging economies from 2006 to 2016, this paper studies the impact of ICT on the relationship between natural resources and environmental quality. Specially, the Environmental Performance Index (EPI) captures the environmental quality. The results show that natural resources have a significant negative effect on EPI, specially, EPI decreases by one unit with a 1% increase in natural resource rents. ICT significantly mitigates this adverse effect, and marginal effects analysis further confirms its positive moderate effects. The results proved to be robust by Lewbel 2SLS and Driscoll-Kraay techniques or other robust tests. It is noteworthy that the adverse effect of natural resources on EPI is greater and the mitigating effect of ICT is more pronounced in low-income countries and lower-middle income countries. Overall, these results remind resource-based countries to vigorously develop ICT, and apply intelligent exploration, digital monitoring, or other digital technologies to realize the high-efficiency use of natural resources, reducing environmental pollution and ecological damage.

Analysis of heavy metal and polycyclic aromatic hydrocarbon pollution characteristics of a typical metal rolling industrial site based on data mining.

With the transformation and upgrading of industries, the environmental problems caused by industrial residual contaminated sites are becoming increasingly prominent. Based on actual investigation cases, this study analyzed the soil pollution status of a remaining sites of the copper and zinc rolling industry, and found that the pollutants exceeding the screening values included Cu, Ni, Zn, Pb, total petroleum hydrocarbons and 6 polycyclic aromatic hydrocarbon monomers. Based on traditional analysis methods such as the correlation coefficient and spatial distribution, combined with machine learning methods such as SOM + K-means, it is inferred that the heavy metal Zn/Pb may be mainly related to the production history of zinc rolling. Cu/Ni may be mainly originated from the production history of copper rolling. PAHs are mainly due to the incomplete combustion of fossil fuels in the melting equipment. TPH pollution is speculated to be related to oil leakage during the industrial use period and later period of vehicle parking. The results showed that traditional analysis methods can quickly identify the correlation between site pollutants, while SOM + K-means machine learning methods can further effectively extract complex hidden relationships in data and achieve in-depth mining of site monitoring data.

Impact of sanitary and phytosanitary measures on agri-products quality upgrading and environmental protection.

Protecting human, animal, and plant life or health from additives, toxins, and contaminants in agri-products and promoting green free trade are the main components of Sanitary and Phytosanitary (SPS) measures. However, the SPS measures are heterogeneous. This study examines the impact of SPS measures on the measured export quality and discusses their influence on the environmental protection of the exporting country. International heterogeneous measures do not necessarily promote quality upgrading but greatly increase transaction costs. By contrast, China's agri-product' quality upgrading and environmental pollution are in sharp contrast. Based on a heterogeneous firm-trade model, this study obtains three hypothetical propositions and conducts empirical regressions using the Tobit method. This study finds that heterogeneous SPS measures hinder quality upgrading because firms present a different quality upgrading trend, which in turn impedes the environmental protection of the exporting country; the quality upgrading made by diversified SOEs is higher than that of foreign firms and private firms; the quality upgrading made by general firms is higher than that of processing firms; and protective SPS measures have a stronger negative effect on quality upgrading and environmental protection.

Can arsenic bioavailability be predicted in soils using in vitro gastro-intestinal simulation?

Many gastrointestinal simulation methods have been used to predict bioavailability, but the suitability of different methods for the same metal(loid)s varies widely, which inevitably affects the accuracy of human health risk assessment. Arsenic is a common and important contaminant in many contaminated land situations. It can be readily absorbed and has teratogenic and mutagenic toxicity. Therefore, in this study, four the most commonly used in vitro simulation methods (the Physiologically Based Extraction Test (PBET), In Vitro Gastrointestinal Method (IVG), Soluble Bioavailability Research Consortium (SBRC), the Unified BARGE Method (UBM)) were tested against an in vivo animal live model, to evaluate their effectiveness for the prediction of soil As bioavailability in 10 industrially contaminated soils. The soil As relative bioavailability (RBA) varied between 15% and 68% in the different soils. As bioaccessibility differed between the 4 gastro-intestinal simulation methods. Gastric phase of UBM (UBMG) predicted As relative bioavailability the best of the 4 assays (R2 = 0.81). This study provides theoretical and technical support to refine human health risk assessment of As in soils from urban industrial legacy contaminated sites.

Thermal sensitivity of Rhinella arenarum tadpole at low concentrations of dimethoate pesticides.

One of the main causes of contamination of aquatic environments, which affects biotic communities, is the use of pesticides in agricultural regions. Amphibians are considered good bio-indicators of aquatic pollution, because they are one of the most susceptible groups to pollution. Several studies suggest that both pollution and climate change produce synergistic effects in amphibians which amplify the toxicity afecting survival, and malformations with an increase in temperature. We studied the sensitivity of sublethal concentrations of dimethoate in Rhinella arenarum tadpoles on two fitness related thermal traits including locomotor swimming performance and thermal tolerance limits (CTmax = critical thermal maximum and CTmin = critical thermal minimum). The locomotor performance of R. arenarum tadpoles decreased with increasing sublethal dimethoate concentrations up to ∼60 % at intermediates dimethoate concentration. The tadpoles showed a tendency to decrease their tolerance to high temperatures (CTmax) with increasing dimethoate concentration around ∼0.5 °C, however no significant differences were found among treatments. Similarly, tadpoles showed decreases in their cold resistance (CTmin) with dimethoate concentrations, around 1 °C the high concentrations of dimethoate. The increase of atypical climatic events, such as heat waves may put R. arenarum tadpoles at greater risk when exposed to dimethoate. Our results show that the sublethal concentrations of the dimethoate pesticide may affect the fitness and survival of the larvae of R. arenarum in natural, and seminatural enviroments.

Effects of environmental awareness training and environmental commitment on firm's green innovation performance: Empirical insights from medical equipment suppliers.

In recent years, the intensification of global industrialization coupled with the enterprise's production and operating activities have caused pollution, increasing the current environmental pressure. Relevant government departments in China have instituted several stringent measures (environmental protection sensitization and awareness activities, training sessions, and exchange activities targeted towards enterprise managers) to address these rising environmental problems. Though these measures have gained traction over the years, there is a dearth of research on their effectiveness on the green innovation performance of enterprises. To bridge the gap, this research explores the effect of environmental awareness training, knowledge exchange activities, and commitment on green innovation performance with survey data from 285 medical equipment manufacturing companies in China. It further expands the theoretical application of environmental awareness training, commitment, and innovation performance from the lens of the Knowledge-Based View. The findings depict a positive relationship between environmental awareness training and innovation performance. It also finds a mediating influence of environmental commitment in the relationship between environmental awareness training and green innovation performance. Furthermore, environmental knowledge exchange activities positively moderate the relationship between environmental awareness training and environmental commitment. These findings offer valuable insights for the green development of medical equipment manufacturing enterprises and the government to formulate environmental protection policies.