Your browser doesn't support javascript.

Portal Regional da BVS

Informação e Conhecimento para a Saúde

Home > Pesquisa > ()
XML
Imprimir Exportar

Formato de exportação:

Exportar

Email
Adicionar mais destinatários
| |

CsPbSnIBr Based All-Inorganic Perovskite Solar Cells with Exceptional Efficiency and Stability.

J Am Chem Soc; 139(40): 14009-14012, 2017 10 11.
Artigo em Inglês | MEDLINE | ID: mdl-28933843
The emergence of perovskite solar cells (PSCs) has generated enormous interest in the photovoltaic research community. Recently, cesium metal halides (CsMX, M = Pb or Sn; X = I, Br, Cl or mixed halides) as a class of inorganic perovskites showed great promise for PSCs and other optoelectronic devices. However, CsMX-based PSCs usually exhibit lower power conversion efficiencies (PCEs) than organic-inorganic hybrid PSCs, due to the unfavorable band gaps. Herein, a novel mixed-Pb/Sn mixed-halide inorganic perovskite, CsPbSnIBr, with a suitable band gap of 1.79 eV and an appropriate level of valence band maximum, was prepared in ambient atmosphere without a glovebox. After thoroughly eliminating labile organic components and noble metals, the all-inorganic PSCs based on CsPbSnIBr and carbon counter electrodes exhibit a high open-circuit voltage of 1.26 V and a remarkable PCE up to 11.33%, which is record-breaking among the existing CsMX-based PSCs. Moreover, the all-inorganic PSCs show good long-term stability and improved endurance against heat and moisture. This study indicates a feasible way to design inorganic halide perovskites through energy-band engineering for the construction of high-performance all-inorganic PSCs.