Your browser doesn't support javascript.

Portal Regional da BVS

Informação e Conhecimento para a Saúde

Home > Pesquisa > ()
XML
Imprimir Exportar

Formato de exportação:

Exportar

Email
Adicionar mais destinatários
| |

Fabrication and understanding of Cu Si-Si@carbon@graphene nanocomposites as high-performance anodes for lithium-ion batteries.

Nanoscale; 10(47): 22203-22214, 2018 Dec 21.
Artigo em Inglês | MEDLINE | ID: mdl-30277255
Besides silicon's low electronic conductivity, another critical issue for using silicon as the anode for lithium-ion batteries (LIBs) is the dramatic volume variation (>300%) during lithiation/delithiation processes, which can lead to rapid capacity fading and poor rate capability, thereby hampering silicon's practical applications in batteries. To mitigate these issues, herein, we report our findings on the design and understanding of a self-supported Cu Si-Si@carbon@graphene (Cu Si-SCG) nanocomposite anode. The nanocomposite is composed of Cu Si-Si core and carbon shell with core/shell particles uniformly encapsulated by graphene nanosheets anchored directly on a Cu foil. In this design, the carbon shell, the highly elastic graphene nanosheet, and the formed conductive and inactive Cu Si phase in Si serve as buffer media to suppress volume variation of Si during lithiation/delithiation processes and to facilitate the formation of a stable solid electrolyte interface (SEI) layer as well as to enable good transport kinetics. Chemomechanical simulation results quantitatively coincide with the in situ TEM observations of volume expansion and provide process details not seen in experiments. The optimized Cu Si-SCG nanocomposite anode exhibits good rate performance and delivers reversible capacity of 483 mA h g (based on the total weight of Cu Si-SCG) after 500 cycles with capacity retention of about 80% at high current density of 4 A g , rendering the nanocomposite a desirable anode candidate for high-performance LIBs.