Measurement of volatile organic compounds and associated risk assessments through ingestion and dermal routes in Dongjiang Lake, China.

This study aims to investigate the occurrence, distribution and risk assessment of volatile organic compounds (VOCs) in Dongjiang Lake of China. Twenty two kinds of VOCs were detected, and the major VOCs were alkene compounds. The total concentration of VOCs (∑VOCs) ranged from 2.93 to 4.69 µg/L, and none of the VOCs detected in Dongjiang Lake exceeded the concentration limits set in the National Drinking Water Quality Standards (GB5749-2006) or the National Environmental Quality Standards for Surface Water (GB3838-2002) of China. Risk quotients (RQ) model, Multimedia Environment Pollutant Assessment System (MEPAS) and value of odor hazard index (OHI) were used to assess the ecological risk, lifetime carcinogenic risk and olfactory risk of VOCs in Dongjiang Lake, respectively. The RQtotal values varied from 3.95 × 10-3 to 0.34 and the RQ values for all the 22 detected VOCs in 12 sample locations of Dongjiang Lake were below 0.01, which means negligible risk to aquatic organisms. The cancerous and non-cancerous risk indices were in the range of 2.31 × 10-9-5.16 × 10-7 and 1.68 × 10-7-1.45 × 10-2, respectively. Bromodichloromethane and 1,1-dichloroethene were associated with the highest and lowest carcinogenic risks in all 12 sample locations. Results also demonstrated that the olfactory risk in Dongjiang Lake is negligible. These data suggest that the VOCs in Dongjiang Lake may not lead great ecological and health risks for organism and human.

Experimental Study of Multispectral Characteristics of an Unmanned Aerial Vehicle at Different Observation Angles.

This study investigates multispectral characteristics of an unmanned aerial vehicle (UAV) at different observation angles by experiment. The UAV and its engine are tested on the ground in the cruise state. Spectral radiation intensities at different observation angles are obtained in the infrared band of 0.9-15 µm by a spectral radiometer. Meanwhile, infrared images are captured separately by long-wavelength infrared (LWIR), mid-wavelength infrared (MWIR), and short-wavelength infrared (SWIR) cameras. Additionally, orientation maps of the radiation area and radiance are obtained. The results suggest that the spectral radiation intensity of the UAV is determined by its exhaust plume and that the main infrared emission bands occur at 2.7 µm and 4.3 µm. At observation angles in the range of 0°-90°, the radiation area of the UAV in MWIR band is greatest; however, at angles greater than 90°, the radiation area in the SWIR band is greatest. In addition, the radiance of the UAV at an angle of 0° is strongest. These conclusions can guide IR stealth technique development for UAVs.

Dynamic modulation transfer function of a retina-like sensor.

In this paper, we propose a method to deduce the dynamic modulation transfer function (DMTF) of a space-variant sampling retina-like sensor and demonstrate its utilization in the forward motion imaging process. With the analysis of sampling and the motion imaging property of the sensor, DMTF has been derived. Next, the performance of DMTF between a retina-like sensor and a rectilinear sensor is compared, and the results show that the degradation of DMTF in forward motion is less than that of a rectilinear sensor. Then, the output images are obtained through simulation based on DMTF, and they are compared with that obtained from a CMOS camera with the same forward motion conditions. The Pearson correlation coefficients between the two kinds of images are all larger than 0.85. Thus, the effectiveness of DMTF is shown.

Performance of wetland applied to ecological remediation of abandoned fish ponds: A case study in Gonghu Bay, Tai lake.

To restore the abandoned fish ponds to "near natural" state, the wetland restoration was carried out in Gonghu Bay lakeside, and its long-term performance of controlling external load was studied for 5 years. The findings showed that water quality and biodiversity had been improved dramatically after the preliminary transformation. The concentrations of permanganate index (CODMn), total nitrogen (TN), and total phosphorus (TP) obviously decreased from 12.91 mg L-1 to 4.32 mg L-1, from 3.46 mg L-1 to 1.42 mg L-1, and from 0.27 mg L-1 to 0.04 mg L-1, respectively. The proportion of Cyanophyta was effectively reduced from 31.82% to 18.89%, and favored the growth of diatoms (31.82%-37.78%) to be the dominant algae species. Aquatic plant species and coverage gradually increased from 16 to 56 and from 5% to 60%, respectively. An in-deep monitoring done for 5 years (2013-2017) showed that the wetland achieved a satisfactory removal efficiency of 58.95% for TN, 64.60% for TP, and up to 77.83% for chlorophyll-a. Besides, three pollution scenarios, such as stormwater runoff, algal bloom, and continuous water transfer, were selected to explore the tolerance of the wetland to the suddenly increased pollution loads. The results dedicated that even if the inlet load was up to 1.0 × 105 m3 d-1, the removal rate coefficients of wetland for chlorophyll-a, TP, and TN were 0.135-0.239 d-1, 0.041-0.112 d-1, and 0.030-0.109 d-1, respectively, which were equivalent to the well-running wetlands. This study confirmed that the wetland was not only a promising ecological remediation technique to contaminated abandoned fish ponds, but also could withstand high pollution load, which had the prospect of sustainable utilization.

Occurrence, spatial distribution, source, and ecological risk assessment of organochlorine pesticides in Dongting Lake, China.

The occurrence, distribution, sources, and ecological risks of organochlorine pesticides in Dongting Lake of China were investigated. The average concentrations of organochlorine pesticides (OCPs) in 22 surface water samples and 14 sediment samples were 90.07 ng/L and 80.65 ng/g dw, respectively. Sixteen types of OCPs, dominated by HCHs, DDTs and heptachlor, were detected in the Dongting Lake. The relationships of OCP residues between Dongting Lake and its tributary rivers have been discussed and the hydraulic connections with the Yangtze River and the Three Gorges Dam (TGD) were also considered. Results showed that the shortage of runoff, earlier dry season, and reduction of sediment deposition extremely deteriorated the hydraulic conditions, magnified the water cycle, and restrained the self-purification of OCPs. The ∑OCPs in surface water were concentrated in the inlets of Yangtze River, Lishui River, Zishui River, Yuanshui River, and Xiangjiang River. Moreover, the ∑OCPs in the outlet of the Yangtze River also maintained a high level, indicating that OCPs posed adverse effects on the Yangtze River. Risk assessments of OCPs in the surface water of Dongting Lake were estimated according to available water quality guidelines and health risk assessment models. The results indicated that OCPs in the surface water of Dongting Lake were safe for aquatic organisms and human health. In addition, sediment quality guidelines (SQGs) were also applied to evaluate the potential ecotoxicological risks of OCPs in sediments. The results presented that contaminants of γ-HCH; o,p'-DDD; and dieldrin in sediment had adverse effects on benthic organisms, indicating that fundamental solutions should be proposed to control OCP contamination in Dongting Lake.

Occurrence and health risk assessment of volatile organic compounds in the surface water of Poyang Lake in March 2017.

An investigation into the occurrence of volatile organic compounds (VOCs) in the surface water of Poyang Lake was conducted. The determination of 54 different kinds of VOCs was performed with a purge and trap-gas chromatography-mass spectrometry method at 28 sampling points. Twenty-two types of VOCs were detected; methylene chloride had the highest mean concentration of 708.19 ng L-1, followed by 1,2-dichloroethane and chloroform, with mean concentrations of 376.78 and 187.26 ng L-1, respectively. The distribution of VOCs in the areas of Poyang Lake from low to high was as follows: west and south < east and central; the highest ∑VOC concentration occurred at the sample site of Zhangsihe. The health risks of VOCs in Poyang Lake were also determined by calculating the cancer and non-cancer risk from the two exposure routes of ingestion and dermal adsorption. The results showed that VOCs have no carcinogenicity risk, while only methylene chloride has a certain carcinogenic risk to the human body.

The application of molecularly imprinted polymers in passive sampling for selective sampling perfluorooctanesulfonic acid and perfluorooctanoic acid in water environment.

Modeling and predicting of a novel polar organic chemical integrative sampler (POCIS) for sampling of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) using molecularly imprinted polymers (MIPs) as receiving phase are presented in this study. Laboratory microcosm experiments were conducted to investigate the uptake kinetics, effects of flow velocity, pH, and dissolved organic matter (DOM), and also the selectivity of the POCIS. In this study, uptake study of PFOA and PFOS sampling on MIP-POCIS, over 14 days, was investigated. Laboratory calibrations of MIP-POCIS yielded sampling rate (Rs) values for PFOA and PFOS were 0.387 and 0.229 L/d, higher than POCIS using commercial sorbent WAX as receiving phase (0.133 and 0.141 L/d for PFOA and PFOS, respectively) in quiescent condition. The Rs values for PFOA and PFOS sampling on MIP-POCIS were increased to 0.591 and 0.281 L/d in stirred condition (0.01 m/s), and no significant increase occurred when the flow velocity was further increased. The Rs values were kept relatively high in the solution of which the pH was lower than the isoelectric point (IEP) of MIP-sorbent and decreased when the solution pH was extend the IEP value. Under the experimental conditions, DOM seemed to slightly facilitate the Rs values of PFOA and PFOS in MIP-POCIS. The results showed that the interaction between the target compounds and the receiving phase was fully integrated by the imprinting effects and also the electrostatic interaction. Finally, comparing the sampling rate of WAX-POCIS and the MIP-POCIS, the MIP-POCIS offers promising perspectives for selective sampling ability for PFOA and PFOS.

Desorption of atrazine in biochar-amended soils: Effects of root exudates and the aging interactions between biochar and soil.

The effects of wheat root exudates and the aging interactions between biochar and soil on atrazine desorption from biochar-amended soil were carefully examined. Compared with CaCl2 solution, wheat root exudates significantly increase the desorption of atrazine from biochar, mainly by promoting the desorption of atrazine adsorbed on biochar with specific forces. Wheat root exudates were effectively separated into three components with different electrical properties, namely, anionic, neutral, and cationic components. Mainly due to the carboxyl-containing compounds, the anionic component was the main active component in the wheat root exudates that enhances the desorption of atrazine from the biochar. Additionally, wheat root exudates can increase the desorption of atrazine from biochar-amended soil. The promotion of atrazine desorption by root exudates was more obvious in soils with low organic matter contents, where atrazine was mainly adsorbed by biochar. The aging interaction between the biochar and soil increased the total desorption rate and rapid desorbing fraction of the atrazine in the soil, most likely due to the reduction of the biochar sorption capacity in the aged biochar-amended soil.

Synthesis and evaluation of molecularly imprinted polymers with binary functional monomers for the selective removal of perfluorooctanesulfonic acid and perfluorooctanoic acid.

This work describes a novel method for the synthesis of molecularly imprinted polymers (MIPs) using 2-(trifluoromethyl) acrylic acid (TFMAA) and 4-vinyl pyridine (4-Vpy) as binary functional monomers, perfluorooctanoic acid (PFOA) as template, and ethyleneglycol dimethacrylate (EGDMA) as cross-linker in the presence of azobisisobutyronitrile (AIBN). The binary functional monomer MIPs were applied to selective recognition for PFOA and perfluorooctanesulfonic acid (PFOS) from aqueous environment. The MIPs were characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM) and microscopic electrophoresis. Thereafter, the adsorption capacity and selectivity of the synthesized MIPs for PFOA and PFOS were evaluated by batch adsorption experiments. The maximum adsorption capacities of the MIPs for PFOA and PFOS were 6.42 and 6.27mg/g, respectively. It was also found that the adsorption capacities remained constant with increasing the solution pH in the range of 2.0-5.0, and then decreased when the pH was further increased. Finally, the novel MIPs can be reused after five cycles of adsorption-desorption-adsorption with no significant decrease of removal rate and have an effective performance in selective removal of PFOA and PFOS in real lake water samples. All the results indicate that the binary functional monomer MIPs have great potential to remove PFOA and PFOS in aqueous environment.

The changes in biochar properties and sorption capacities after being cultured with wheat for 3 months.

Biochars that were produced from pig manure at three different temperatures were amended to sand and cropped with wheat to examine the effect of wheat roots on biochar properties and its sorption capacity. After being aged with wheat roots for three months, the biochar samples showed significant changes in their physicochemical properties, which depended on biochar types and their distances from the roots. In general, the ash content and micropores decreased and the polarity increased after root aging. The changes in the biochar properties in turn affected biochar sorption capacities. The sorption of atrazine and phenanthrene by the biochar that was produced at 300 °C (BC300) both increased by different extents after aging, significantly decreased for BC700, and there were little changes for BC500. The complex changes were due to the different dominant sorption mechanisms for different biochars and different chemicals. For BC700, hydrophobic partition and pore-filling were the main processes, especially for phenanthrene, whereas for BC300, polar interactions dominated.