Electron tunneling spectroscopy of SmB6 studied by in situ nano-break-junction method.

Tunneling spectra of intermediate-valence semiconductor SmB6 are reported for in-situ break junctions, being able to make nano-scale planar tunnel junctions. The electron tunneling using break junction method is a powerful probe of the intrinsic energy gap. The investigated tunneling conductance dI/dV curves are mostly reproducible and symmetric with respect to the applied voltage. Two kinds of characteristic energy gaps are observed at 2E(d) = 20 mV and 2E(a) = 9 mV, which coincides well with those previously studied by point-contact spectroscopy and the activation energy fitted by our electrical resistivity data. The positions of the gap structures are independent of the zero-bias conductance, implying no additional voltage drop induced by the break junctions. The small anomaly at the activation energy 2E(a) indicates a relatively low density of in-gap states. Furthermore, the results of magnetic properties reveal the ratio of Sm2+:Sm3+ = 3.7:6.3 and the antiferromagnetic nature at high temperature.

Interface effect of magnetic properties in Ni nanoparticles with a hcp core and fcc shell structure.

We have fabricated hexagonal close-packed (hcp) Ni nanoparticles covered by a face-centered cubic (fcc) Ni surface layer by polyol method. The magnetic properties have been investigated as a function of temperature and applied magnetic field. The magnetic behavior reveals that the system should be divided magnetically into three distinct phases with different origins. The fcc Ni phase on the shell contributes to the superparamagnetism through a wide temperature range up to 360 K. The hcp Ni phase at the core is associated with antiferromagnetic nature below 12 K. These observations are in good agreement with the X-ray absorption spectroscopy and magnetic circular dichroism measurements. In our particular case, the unique hcp core and fcc shell structure gives rise to an additional anomaly at 20 K in the zero-field-cooled magnetization curve. Its position is barely affected by the magnetic field but its structure disappears above 30 kOe, showing a metamagnetic transition in the magnetization versus magnetic field curve. This new phase originates from the magnetic exchange at the interface between the hcp and fcc Ni sublattices.