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Forty years ago, it was proposed that gas-phase organic chemistry in the interstellar medium can be initiated by the methyl cation CH3+ (refs. 1-3), but so far it has not been observed outside the Solar System4,5. Alternative routes involving processes on grain surfaces have been invoked6,7. Here we report James Webb Space Telescope observations of CH3+ in a protoplanetary disk in the Orion star-forming region. We find that gas-phase organic chemistry is activated by ultraviolet irradiation.
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New data are presented on the resonant Auger decay of iodobenzene (C6H5I) in the region of the I 4d-1 ionization threshold. The excited molecules decay by participator and spectator processes to populate single-hole valence states and two-hole, one-particle excited states of the cation, providing new information on the structure of C6H5I+. Excitation of dissociative C6H5I (I 4d5/2,3/2-1)σ* resonances can, in principle, result in ultrafast dissociation to C6H5 + I** and the subsequent autoionization of I**, but no evidence for this process is observed. The results are compared with our recent study of the resonant Auger decay of methyl iodide (CH3I).
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Resonant Auger processes provide a unique perspective on electronic interactions and excited vibrational and electronic states of molecular ions. Here, new data are presented on the resonant Auger decay of excited CH3I in the region just below the I 4d-1 ionization threshold. The resonances include the Rydberg series converging to the five spin-orbit and ligand-field split CH3I (I 4d-1) thresholds, as well as resonances corresponding to excitation from the I 4d5/2,3/2 orbitals into the σ* lowest unoccupied molecular orbital. This study focuses on participator decay that populates the lowest lying states of CH3I+, in particular, the XÌ2E3/2 and 2E1/2 states, and on spectator decay that populates the lowest-lying (CH3I2+)σ* states of CH3I+. The CH3I (I 4d-1)σ* resonances are broad, and dissociation to CH3 + I competes with the autoionization of the core-excited states. Auger decay as the molecule dissociates produces a photoelectron spectrum with a long progression (up to v3+ â¼ 25) in the C-I stretching mode of the XÌ2E3/2 and 2E1/2 states, providing insights into the shape of the dissociative core-excited surface. The observed spectator decay processes indicate that CH3I+ is formed on the repulsive wall of the lower-lying (CH3I2+)σ* potentials, and the photon-energy dependence of the processes provides insights into the relative slopes of the (4d-1)σ* and (CH3I2+)σ* potential surfaces. Data are also presented for the spectator decay of higher lying CH3I (I 4d-1)nl Rydberg resonances. Photoelectron angular distributions for the resonant Auger processes provide additional information that helps distinguish these processes from the direct ionization signal.
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Fluorinated species have a pivotal role in semiconductor material chemistry and some of them have been detected beyond the Earth's atmosphere. Achieving good energy accuracy on fluorinated species using quantum chemical calculations has long been a challenge. In addition, obtaining direct experimental thermochemical quantities has also proved difficult. Here, we report the threshold photoelectron and photoion yield spectra of SiF and CF radicals generated with a fluorine reactor. The spectra were analysed with the support of ab initio calculations, resulting in new experimental values for the adiabatic ionisation energies of both CF (9.128 ± 0.006 eV) and SiF (7.379 ± 0.009 eV). Using these values, the underlying thermochemical network of Active Thermochemical Tables was updated, providing further refined enthalpies of formation and dissociation energies of CF, SiF, and their cationic counterparts.
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We provide compelling experimental and theoretical evidence for the transition state nature of the cyclopropyl cation. Synchrotron photoionization spectroscopy employing coincidence techniques together with a novel simulation based on high-accuracy ab initio calculations reveal that the cation is unstable via its allowed disrotatory ring-opening path. The ring strains of the cation and the radical are similar, but both ring opening paths for the radical are forbidden when the full electronic symmetries are considered. These findings are discussed in light of the early predictions by Longuet-Higgins alongside Woodward and Hoffman; we also propose a simple phase space explanation for the appearance of the cyclopropyl photoionization spectrum. The results of this work allow the refinement of the cyclopropane C-H bond dissociation energy, in addition to the cyclopropyl radical and cation cyclization energies, via the Active Thermochemical Tables approach.
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A new experimental method has been developed to record photoelectron spectra based on the well-established pulsed-field-ionization zero-kinetic-energy photoelectron spectroscopy technique and inspired by the data treatment employed in slow photoelectron spectroscopy. This method has been successfully applied to two well-known systems: the X+2Πg,1/2(v+ = 0) â X1Σ+g(v = 0) and the X+1Σ+(v+ = 2) â X2Π1/2(v = 0) ionizing transitions of CO2 and NO, respectively. The first results highlight several advantages of our technique such as an improved signal-to-noise ratio without degrading the spectral resolution and a direct field-free energy determination. The data obtained for NO indicate that this method might be useful for studying field-induced autoionization processes.
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The first measurement of the photoelectron spectrum of the silylidyne free radical, SiH, is reported between 7 and 10.5 eV. Two main photoionizing transitions involving the neutral ground state, X+1Σ+ â X2Π and a+3Π â X2Π, are assigned by using ab initio calculations. The corresponding adiabatic ionization energies are derived, IEad(X+1Σ+) = 7.934(5) eV and IEad(a+3Π) = 10.205(5) eV, in good agreement with our calculated values and the previous determination by Berkowitz et al. [J. Chem. Phys. 86, 1235 (1987)] from a photoionization mass spectrometric study. The photoion yield of SiH recorded in this work exhibits a dense autoionization landscape similar to that observed in the case of the CH free radical [Gans et al., J. Chem. Phys. 144, 204307 (2016)].
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The NH2 radical is a key component in many astrophysical environments, both in its neutral and cationic forms, being involved in the formation of complex N-bearing species. To gain insight into the photochemical processes into which it operates and to model accurately the ensuing chemical networks, the knowledge of its photoionization efficiency is required, but no quantitative determination has been carried out so far. Combining a flow-tube H-abstraction radical source, a double imaging photoelectron-photoion spectrometer, and a vacuum-ultraviolet synchrotron excitation, the absolute photoionization cross section of the amino radical has been measured in the present work for the first time at two photon energies: σionNH2(12.7 eV) = 7.8 ± 2.2 Mb and σionNH2(13.2 eV) = 7.8 ± 2.0 Mb. These values have been employed to scale the total ion yield previously recorded by Gibson et al. ( J. Chem. Phys. 1985, 83, 4319-4328). The resulting cross section curve spanning the 11.1-15.7 eV energy range will help in refining the current astrophysical models.
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The photoelectron spectroscopy of CH2NC (isocyanomethyl) radical species is investigated for the first time between 9.3 and 11.2 eV in the vicinity of the first photoionizing transition X+1A1â X 2B1. The experiment combines a microwave discharge flow-tube reactor to produce the radicals through the CH3NC + F â CH2NC + HF reaction, a VUV synchrotron radiation excitation, and a double imaging electron/ion coincidence spectrometer which allows the recording of mass-selected threshold photoelectron spectra. Assignment of the observed vibrational structure of the CH2NC+ cation is guided by ab initio calculations and Franck-Condon simulations. From the experimental spectrum, the first adiabatic ionization energy of the CH2NC radical is measured as 9.439(6) eV. Fundamental wavenumbers are determined for several vibrational modes of the cation: [small nu, Greek, tilde]1+(CH2 symmetric stretch) = 2999(80) cm-1, [small nu, Greek, tilde]2+(NC stretch) = 1925(40) cm-1, [small nu, Greek, tilde]4+(H2C-N stretch) = 1193(40) cm-1, [small nu, Greek, tilde]6+(CNC out-of-plane bend) = 237(50) cm-1, and [small nu, Greek, tilde]8+(CH2 rock) = 1185(60) cm-1.
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The C2 carbon cluster is found in a large variety of environments including flames, electric discharges, and astrophysical media. Due to spin-selection rules, assessing a complete overview of the dense vibronic landscape of the C2 + cation starting from the ground electronic state X Σg+1 of the neutral is not possible, especially since the C2 + ground state is of X+ Σg-4 symmetry. In this work, a flow-tube reactor source is employed to generate the neutral C2 in a mixture of both the lowest singlet X Σg+1 and triplet a 3Πu electronic states. We have investigated the vibronic transitions in the vicinity of the first adiabatic ionization potential via one-photon ionization with vacuum ultraviolet synchrotron radiation coupled with electron/ion double imaging techniques. Using ab initio calculations and Franck-Condon simulations, three electronic transitions are identified and their adiabatic ionization energy is determined Ei(a+ 2ΠuâX 1Σg +)=12.440(10) eV, Ei(X+ 4Σg -âa 3Πu)=11.795(10) eV, and Ei(a+2Πu â a3Πu) = 12.361(10) eV. From the three origin bands, the following energy differences are extracted: ΔE(a - X) = 0.079(10) eV and ΔE(a+ - X+) = 0.567(10) eV. The adiabatic ionization potential corresponding to the forbidden one-photon transition X+ â X is derived and amounts to 11.873(10) eV, in very good agreement with the most recent measurement by Krechkivska et al. [J. Chem. Phys. 144, 144305 (2016)]. The enthalpy of formation of the doublet ground state C2 + cation in the gas phase is determined at 0 K, ΔfH0(0K)(C2 +(Πu2))=2019.9(10) kJ mol-1. In addition, we report the first experimental ion yield of C2 for which only a simple estimate was used up to now in the photochemistry models of astrophysical media due to the lack of experimental data.
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The vacuum-ultraviolet threshold photoelectron spectrum of methyl isocyanate CH3NCO has been recorded from 10.4 eV to 12 eV using synchrotron radiation and a coincidence technique allowing for a mass-discrimination of the photoelectron signal. A significant improvement is achieved over previous investigations as this experimental setup leads to a much more resolved spectrum. Ten sharp peaks and a broad feature spanning 1.2 eV were recorded. This spectrum consists of XÌ+ 2Aâ³âXÌ 1A' and Ã+ 2A'âXÌ 1A' ionizing transitions. For the former, the adiabatic ionization energy was determined experimentally to be 10.596(6) eV; for the latter, its value was estimated to be 10.759(50) eV. Seven sharp peaks could be assigned to vibrational modes of the cation XÌ+ 2Aâ³ and neutral XÌ 1A' ground electronic states involving only the NCO group atoms. Theoretical modeling of the threshold photoelectron spectrum has proven difficult as methyl isocyanate is a non-rigid molecule displaying large amplitude internal rotation of the methyl group and â CNC bending mode, leading to the quasi-symmetry. With the help of ab initio calculations, a theoretical model in which these two large amplitude motions are included in addition to the five small amplitude vibrational modes involving NCO group atoms is proposed. Comparison with the experimental spectrum shows that the broad feature and the strongest peak line positions are well accounted for; their intensities are also fairly well reproduced after adjusting a few parameters.
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We present the absolute photoionization cross-section of the mercapto radical, SH, recorded from its first ionization energy at 10.4 eV up to a photon energy of 15 eV. The absolute scale was calibrated at the fixed photon energy of 11.2 eV using the known values of H2S and S as references. SH and S were produced in a microwave discharge flow-tube reactor by hydrogen abstraction of the H2S precursor. The measured photoionization cross-section of SH dramatically differs from the one currently employed to model the presence of this species in a number of astronomical environments, where SH along with its ionic counterpart SH+ have been detected. The cation spectroscopy and fragmentation of H2S, SH and S in the 9.2-15.0 eV energy range obtained using threshold photoelectron techniques is also presented and discussed in the context of existing literature.
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The photoelectron spectrum of the X1Σ+ â X+2Σ+ ionizing transition of hydrogen isocyanide (HNC) is measured for the first time at a fixed photon energy (13 eV). The assignment of the spectrum is supported by wave-packet calculations simulating the photoionization transition spectrum and using ab initio calculations of the potential energy surfaces for the three lowest electronic states of the cation. The photoelectron spectrum allows the retrieval of the fundamental of the CN stretching mode of the cationic ground state ([small nu, Greek, tilde]3 = 2260 ± 80 cm-1) and the adiabatic ionization energy of hydrogen isocyanide: IE(HNC) = 12.011 ± 0.010 eV, which is far below that of HCN (IE(HCN) = 13.607 eV). In light of this latter result, the thermodynamics of the HCN+/HNC+ isomers is discussed and a short summary of the values available in the literature is given.
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We report on the photoionization of the resonance-stabilized anilino radical (C6H5NH) formed by H atom abstraction from aniline by F atoms in a flow tube. The spectra were recorded from 7.8 to 9.7 eV by using a double-imaging photoelectron/photoion coincidence spectrometer with VUV radiation provided by the DESIRS beamline at the SOLEIL synchrotron. The vibrationally resolved recorded threshold photoelectron spectrum of the anilino radical showed transitions to the ground X+1A' â X2Aâ³ and first excited states a+3Aâ³ â X2Aâ³ of the cation, which were assigned through comparison with theoretically simulated spectra, yielding an adiabatic ionization energy of 8.02 ± 0.02 eV. These results are discussed in light of existing data on the picolyl structural isomers and are of interest for the analytical applications of coincidence techniques in real-time combustion analysis where these intermediates are found.
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The results of an extensive ab initio study of the cyanobutadiyne cation, initially motivated by threshold-photoelectron spectroscopy experiments [see the study by Gans et al., J. Chem. Phys. 150, 244304 (2019)], are reported in the present paper. Calculations at the internally contracted multireference configuration interaction level of theory have been performed to derive the rovibronic properties of the seven lowest electronic states of HC5N+. Equilibrium geometries, rotational constants, vibrational frequencies, electric dipole moments, and spin-orbit constants have been calculated and compared with experimental data when available. Adiabatic and vertical ionization energies from the neutral ground state as well as transition energies within the cation electronic manifold are predicted, using the convergence to the complete basis set limit. The accurate description of the complex energy landscape up to 32 000 cm-1 above the ionization potential allows us to perform Franck-Condon simulations of the photoionization spectrum to the X+ 2Π, A+ 2Π, B+ 2Σ+, and C+ 2Π states and allows us to simulate the A+ 2Π â X+ 2Π emission spectrum. The vibronic perturbations occurring on the excited potential energy surfaces are revealed and discussed, in particular, for the 3 2Π surface, which presents a double-well topography.
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We report the vacuum-ultraviolet threshold-photoelectron spectrum of HC5N recorded over a wide spectral range, from 84 000 to 120 000 cm-1, with a 120 cm-1 spectral resolution, better than what was achieved in previous photoelectron studies, and with mass selectivity. The adiabatic ionization potential of cyanobutadiyne is measured at 85 366 (±40) cm-1. Assignment of the vibrational bands of the four lowest electronic states X+2Π, A+2Π, B+2Σ+, and C+2Π are performed, supported by high level ab initio calculations which are fully detailed in Paper II [B. Gans et al., J. Chem. Phys. 150, 244303 (2019)] and by Franck-Condon simulations. Only vibrational stretching modes are observed in the threshold-photoelectron spectra. The ground state of HC5N+ exhibits a vibrational progression in the ν2 stretching mode involving mainly the elongation of the C≡C triple bonds, whereas the A+ and C+ excited electronic states show a progression in the stretching mode mainly associated with the elongation of the C≡N bond, i.e., ν4 and ν3, respectively. The B+ state appears almost as a vibrationless structure in close vicinity to the A+ state.
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We present the photoelectron spectra of C3Hx (x = 0-3) formed in a microwave discharge flow-tube reactor by consecutive H abstractions from C3H4 (C3Hx + F â C3Hx-1 + HF (x = 1-4)), but also from F + CH4 schemes by secondary reactions. The spectra were obtained combining tunable VUV synchrotron radiation with double imaging electron/ion coincidence techniques, yielding mass-selected threshold photoelectron spectra. The obtained results complement not only existing ones, but for the first time the photoelectron spectra of C3, cyclic and linear C3H (c,l-C3H) as well as of the excited states of C3H3 are reported. In the case of c-C3H, l,t-C3H2 and C3H3, Franck-Condon simulations have been performed in order to assign the vibrational structure. The adiabatic ionization energies of these radicals are reported and compared to ab initio calculated values as well as to theoretical values using known enthalpies of formation.
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The line intensity of photoelectron spectra when either the neutral or cationic species display a Renner-Teller coupling is derived and applied to the modeling of the photoelectron spectra of CNC, CCN, and HCCN. The rovibronic energy levels of these three radicals and of their cations are investigated starting from ab initio results. A model treating simultaneously the bending mode and the overall rotation is developed to deal with the quasilinearity problem in CNC+, CCN+, and HCCN and accounts for the large amplitude nature of their bending mode. This model is extended to treat the Renner-Teller coupling in CNC, CCN, and HCCN+. Based on the derived photoelectron line intensity, the photoelectron spectra of all three molecules are calculated and compared to the experimental ones.
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We present the photoelectron spectroscopy of four radical species, CHxCN (x = 0-2) and CNC, formed in a microwave discharge flow-tube reactor by consecutive H abstractions from CH3CN (CHxCN + F â CHx-1CN + HF (x = 1-3)). The spectra were obtained combining tunable vacuum ultraviolet synchrotron radiation with double imaging electron/ion coincidence techniques, which yielded mass-selected threshold photoelectron spectra. The results obtained for H2CCN complement existing ones while for the other radicals the data represent the first observation of their (single-photon) ionizing transitions. In the case of H2CCN, Franck-Condon calculations have been performed in order to assign the vibrational structure of the X+ 1A1âX 2B1 ionizing transition. A similar treatment for the HCCN, CCN, and CNC radicals appeared to be more complicated mainly because a Renner-Teller effect strongly affects the vibrational levels of the ground electronic state of the HCCN+, CCN, and CNC species. Nevertheless, the first adiabatic ionization energies of these radicals are reported and compared to our ab initio calculated values, leading to new values for enthalpies of formation (ΔfH2980(HCCN+(X2A'))=1517±12kJmol-1,ΔfH2980(CCN(X2Π))=682±13kJmol-1, and ΔfH2980(CNC(X2Πg))=676±12kJmol-1), which are of fundamental importance for astrochemistry.
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Vacuum-ultraviolet pulsed-field-ionization zero-kinetic-energy photoelectron spectra of X+Π2âXΣ+1 and B+Π2âXΣ+1 transitions of the HC314N and HC315N isotopologues of cyanoacetylene have been recorded. The resolution of the photoelectron spectra allowed us to resolve the vibrational structures and the spin-orbit splittings in the cation. Accurate values of the adiabatic ionization potentials of the two isotopologues (EI/hc(HC314N)=93 909(2) cm-1 and EI/hc(HC315N)=93 912(2) cm-1), the vibrational frequencies of the ν2, ν6, and ν7 vibrational modes, and the spin-orbit coupling constant (ASO = -44(2) cm-1) of the X+Π2 cationic ground state have been derived from the measurements. Using ab initio calculations, the unexpected structure of the B+Π2âXΣ+1 transition is tentatively attributed to a conical intersection between the A+ and B+ electronic states of the cation.