Synthesis of nano-crystallite hydroxyapatites in different media and a comparative study for estimation of crystallite size using Scherrer method, Halder-Wagner method size-strain plot, and Williamson-Hall model.

Hydroxyapatite (HAp) [Ca10(PO4)6(OH)2] is remarkably similar to the hard tissue of the human body and the uses of this material in various fields in addition to the medical sector are increasing day by day. In this research, mustered oil, soybean oil, as well as coconut oil were employed as liquid media for synthesizing nanocrystalline HAp using a wet chemical precipitation approach. The X-ray diffraction (XRD) study verified the crystalline phase of the HAp in all the indicated media and discovered similarities with the standard database. Several prominent models such as the Scherrer's Method (SM), Halder-Wagner Method (HWM), linear straight-line method (LSLM), Williamson-Hall Method (W-M), Monshi Scherrer Method (MSM), Size-Strain Plot Method (SSPM), Sahadat-Scherrer Method (S-S) were applied for the determination of crystallite size. The stress, strain, and energy density were also computed from the above models. All the models, without the Linear straight-line technique of Scherrer's equation, resulted in an appropriate value of crystallite size for synthesized products. The calculated crystallite sizes were 6.5 nm for HAp in master oil using Halder-Wagner Method, and 143 nm for HAp in coconut oil using the Scherrer equation which were the lowest and the largest, respectively.

Preparation and characterization of short date palm mat (DPM) fiber reinforced polystyrene composites: Effect of gamma radiation.

The utilization of natural fiber reinforced polymer composites is growing fast in numerous sectors. In this study, the effect of the addition of short date palm mat (DPM) fibers in polystyrene matrix on the physico-mechanical and thermal properties were studied. Short DPM fiber reinforced polystyrene composites were produced by compression moulding process and the fiber content was 5, 10, 15, 20 and 25 wt%. Physico-mechanical and thermal properties were examined. Scanning electron microscopy (SEM) and Fourier-transform infrared (FT-IR) analysis of the composites were also done. The findings from the investigates exposed that the composites with 10 % fiber content showed improved mechanical and thermal characteristics as compared to other composites. The morphological analysis also supported the results where good interfacial bonding among fiber and polystyrene matrix was found for the composites with 10 % fiber content. The optimized (10 % fiber content) composites were exposed to gamma radiation (2.5-7.5 kGy) and the best result was found at 5.0 kGy radiation dose. Degradation of gamma irradiated composites was conducted in four different media such as water, acid, base, and brine.

Nano-crystallite bones of Oreochromis niloticus and Katsuwonus pelamis for the photocatalytic degradation of Congo red dye.

The bones of two fish species, Oreochromis niloticus and Katsuwonus pelamis, were chosen in this research for evaluating their photocatalytic efficacy under solar radiation. The fish bones were isolated and conditioned before analyzing crystallographic parameters. The samples were characterized by using different instrumental techniques such as Fourier Transform Infrared (FTIR), X-ray diffraction (XRD), Energy Dispersive X-ray (EDX), Field Emission Scanning Electronic Microscopy (FESEM), and optical bandgap. From the XRD data, various types of crystallographic information such as crystallite size, microstrain, lattice parameters, dislocation density, degree of crystallinity, crystallinity index, Hydroxylapatite (HAp), the volume fraction of ß-TCP, ß-Tricalcium phosphate (ß-TCP) percentage, and specific surface area were evaluated. Different model equations such as the Sahadat-Scherrer model, Linear Straight-line model, Monshi-Scherrer's method, and Williamson-Hall plot were employed to justify the nano-crystallite size. The photocatalytic efficacy of the two types of samples was explored by changing the catalyst concentration, dye concentration, interaction time, pH of the solution, etc. under solar irradiation.

Calcined chicken eggshell-derived biomimetic nano-hydroxyapatite as a local drug-delivery aid for doxycycline hyclate: characterization, bio-activity, cytotoxicity, antibacterial activity and in vitro release study.

The integration of bioactive substances with antibiotics has been extensively pursued for the treatment of osteomyelitis. These materials, also known as biomaterials, can serve both as bone replacements and targeted drug delivery systems for antibiotics. In this study, biomimetic nano-hydroxyapatite (nHAp) was synthesized via the coprecipitation technique where waste chicken eggshell (WCE) was employed as the source of Ca. Heat treatment was performed at four different temperatures (100 °C, 300 °C, 600 °C and 900 °C). Subsequently, the samples were characterized using XRD, FTIR spectroscopy, Raman spectroscopy, FESEM, EDX, XPS, DLS hydrodynamic size and zeta potential analysis. Also, their biomedical effectiveness was evaluated in terms of cytotoxicity, hemolysis, antibacterial performance, and bioactivity. Doxycycline hyclate (DOXh) was loaded in the synthesized nHAp samples, and subsequently its in vitro release was studied under stirring in simulated body fluid (SBF). The DOXh release kinetics was evaluated, and it was found that the first-order model was the best fitted kinetic model describing the release of DOXh from the nHAp samples, except for nHAp100, which was best described by the Korsmeyer-Peppas model. The nHAp synthesized utilizing WCE showed excellent potential for biomedical application and can be used as a drug delivery agent for antibiotics, such as DOXh.

Synthesis of nano-crystallite gypsum and bassanite from waste Pila globosa shells: crystallographic characterization.

For the first time, in this work, waste Pila globosa shells have been used to synthesize two industrially valuable materials, gypsum and bassanite. In the first stage, gypsum was synthesized using a wet chemical precipitation method. Subsequently, bassanite was produced by the heat treatment of gypsum at a certain temperature (200 °C), which was chosen after TGA and DSC analysis. The synthesized gypsum and bassanite phases were confirmed by XRD with the assistance of FTIR spectroscopy. Various crystallographic parameters of gypsum and bassanite were investigated, such as the crystallite size (a number of models were employed along with the Scherrer equation), crystallinity index, lattice parameters, unit cell volume, dislocation density, relative intensity, preference growth, specific surface area, microstrain (models were also engaged), and residual stress using the XRD-sin2 Ψ technique.

Covid-19 waste facemask conundrum: A facile way of utilization through fabricating composite material with unsaturated polyester resin and evaluation of its mechanical properties.

Since the outbreak of novel coronavirus (COVID-19), the use of personal protective equipment (PPE) has increased profusely. Among all the PPEs, face masks are the most picked ones by the mass people for protective purpose. This spawned extensive daily use of face masks and production of masks had to augment to keep up this booming demand. Such extensive use of face masks has resulted in a huge waste generation. Lack of proper disposal, waste management and waste recycling have already led this waste to pervade in the environment. In quest of finding a solution, here in this research, a composite material was fabricated utilizing waste face mask (WFM) with unsaturated polyester resin (UPR) and the mechanical properties were evaluated. The composites were fabricated by incorporating 1%, 2%, 3%, 4% and 5% WFM (by weight) within the UPR matrix in the shredded form following hand lay-up technique. Tensile properties, i.e., tensile strength (TS), tensile modulus (TM) and percentage elongation at break (% EB) as well as flexural properties, i.e., bending strength (BS) and bending modulus (BM) were evaluated for the fabricated composites. According to the results obtained, the 2% WFM loaded composites showed highest values of TS, TM, BS and BM which are 31.61 N/mm2, 1551.41 N/mm2, 66.53 N/mm2 and 4632.71 N/mm2 respectively. These values of 2% WFM loaded composite are 69.58%, 107.78%, 129.49% and 152% higher than the values of the control sample (UPR). Such results depict the successfulness of WFM's incorporation as a reinforcing material in the composite materials. Attenuated Total Reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), scanning electron microscopy (SEM), water uptake and thickness swelling tests were also carried out for the fabricated composites. FTIR of the collected WFM revealed the fiber to be of polypropylene and the existing functional groups were also identified. The SEM images confirmed the proper adhesion of WFM and UPR in terms of mechanical bonding rather than chemical bonding. Water absorption and dimension change was investigated by water uptake and thickness swelling test. To sum up, the way we have utilized WFM as a reinforcing agent in a composite material, this could be a possible solution for the face mask's waste conundrum.

Enhancement of photocatalytic efficacy by exploiting copper doping in nano-hydroxyapatite for degradation of Congo red dye.

This research deals with the photocatalytic activity of hydroxyapatite and the improvement of efficiency by doping various percentages of copper; the catalysts were synthesized by the wet-chemical method. Pure and copper-doped photocatalysts were characterized by several techniques including X-ray diffraction (XRD), Fourier Transform Infrared (FTIR) spectroscopy, Raman spectroscopy, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), dynamic scanning calorimetry (DSC), and UV-Vis spectroscopy. The competency of pure and copper-doped hydroxyapatite as photocatalysts was assessed by their interaction with Congo red dye. The crystallographic parameters of the catalysts were also estimated by employing the XRD technique, and a relationship was established between the calculated parameters and photocatalytic performance. Crystallite size was calculated from various model equations, which revealed an acceptable crystallite size of 42-68 nm. Copper doping in hydroxyapatite impressively augmented the photocatalytic efficacy, for example 99% dye was degraded upon 0.63% Cu-doping compared to 75% for the pure HAp, which was exemplified not only by the reaction rate but also by the quantum yield. The degradation percentages changed with time but became fixed at 200 min. The molar extinction coefficient was estimated by employing the Beer-Lambert law and further utilized to compute the photonic efficiency of the catalysts. In the study of the photochemical reaction, a simplified reaction process was proposed, and the potentials of the conduction band and valence band were assessed, which influenced the activity. The doping of Cu in crystalline hydroxyapatite will enhance the photocatalytic activity towards Congo red dye under all experimental conditions.

Redispersible polymer powder modified cementitious tile adhesive as an alternative to ordinary cement-sand grout.

With the advent of technologies on modern structural and building materials, adaptation of such technological features has been the pivotal concern of researchers. Ceramic tiles attained a distinctive focus due to its decorative feature for both indoor and outdoor conditions and also for their ease of implementation. The purpose of exploiting ceramic tiles is not only to impart structural strength but also the aesthetical characteristics that seem to matter a great deal. When it comes to the adhesion of these tiles onto the substrate wall, traditional method exerts the use of sand-cement grout. This faces some drawbacks including poor water retention property, hard and brittleness of the surface, much higher drying time, no flexibility, higher thickness of the paste and so on. These difficulties can be overcome by the addition of redispersible polymer powder (RPP) along with other cementitious constituents. The blended polymers interact with cement components to improve the physical and mechanical properties such as increased adhesion strength, reduced shrinkage and lower water absorption. This review article made an effort to provide the generalized idea about the cementitious tile adhesive (CTA) and its components. Focus was made onto the commercially available RPP and formulation of CTA with the inclusion of RPP. Critical analysis of the repercussions of RPP fortification was also carried out based on different researcher's findings.

Coupled effect of particle size of the source materials and calcination temperature on the direct synthesis of hydroxyapatite.

We report the effect of controlled particle size (obtained by using 80, 100, 120, 140 and 200 mesh) of the source materials on the synthesis of a well-known biomaterial, hydroxyapatite (Hap). In addition to this, we have also mapped the consequence of applied temperature (700°C, 800°C and 900°C) on the crystallographic properties and phase composition of the obtained Hap. Nevertheless, although with Hap, in each case, ß-tricalcium phosphate (ß-TCP) was registered as the secondary phase the ANOVA test revealed that the results of the crystallographic parameters are significantly different for the applied sintering temperature 700°C and 800°C (p < 0.05), while the data obtained for calcination temperature 800°C are not significantly different from that acquired at 900°C (p > 0.05). Fourier transform infrared spectrophotometer data ensured that, irrespective of mesh size and calcination temperature, the synthesized Hap samples were of carbonated apatite with B-type substitution. Interestingly, for all cases, the % of carbonate content was below the maximum limit (8%) of the CO 3 2 - ion present in bone tissue hydroxyapatite.

Fabrication and characterization of eco-friendly composite materials from natural animal fibers.

A large amount of useless portion, which is discharging from leather industries, pollutes the environment immensely. The discarded part needs to be recycled to yield other valuable products to subside environmental pollution. In this research, we utilized a rejected part (cow hair) of leather industries and unsaturated polyester resin (UPR) to fabricate valued composites to confine atmospheric pollution. A hand-lay-up technique, which is an easy and economical approach, was employed for composites fabrication. A number of cow hair fiber percentages (2, 5, 7, 10, 12, 15, and 20% by weight) were taken into consideration to investigate the impact of fiber loading on composites. Prepared composites were characterized by a few mechanical properties such as tensile strength (TS), tensile modulus (TM), elongation at break (EB), bending strength (BS), and bending modulus (BM). Fourier Transform Infrared (FTIR), Electron Scanning Microscopy (SEM), and water absorption were also performed to support the data in favor of mechanical properties. Optimum mechanical properties which were supported by the other analysis were achieved for 5% cow hair containing composites.

UV-assisted synthesis of hydroxyapatite from eggshells at ambient temperature: cytotoxicity, drug delivery and bioactivity.

Hydroxyapatite [Ca10(PO4)6(OH)2], an important biomaterial, retains a chemical structure that is similar to the mineral phase of bone. Consequently, the ability of hydroxyapatite (Hap) to augment bone growth within bone tissue has made it a potential candidate for use as a hard tissue-implant material. In this work, adopting a UV-mediated solid-state method for the first time, hydroxyapatite was synthesized from eggshells and no thermal treatment was used but ambient temperature was maintained. This simple synthesis process involved a combination of ball milling of the starting materials followed by UV-irradiation. UV-excitation of the Ca and P precursors resulted in the desired Hap and X-ray diffraction (XRD), Fourier-transform infrared (FT-IR) and Raman spectroscopic techniques were used for characterization. The potency of UV-Hap as a biomaterial was examined via the bioactivity, cytotoxicity and the drug (ciprofloxacin) loading-releasing response, which was encouraging. The results of the cell viability assays complied an insignificant cytotoxicity and the simulated body fluid immersion test indicated the bioactivity was within the acceptable range. On the other hand, to better understanding the drug ejection and associated transport phenomenon, two kinetic models (Higuchi and Ritger-Peppas models) were used and a diffusion controlled ciprofloxacin release mechanism was observed using the Higuchi model. However, the experimental outcomes of a drug delivery response exposed UV-Hap as a favorable vehicle for drug loading and release. Hence, this research highlights the prospects of a UV-assisted synthesis method as a green route for the synthesis of Hap to be applied in biomedical fields.

The effects of daily cover soils on shear strength of municipal solid waste in bioreactor landfills.

Bioreactor landfills are operated to enhance refuse decomposition, gas production, and waste stabilization. The major aspect of bioreactor landfill operation is the recirculation of collected leachate back through the refuse mass. Due to the accelerated decomposition and settlement of solid waste, bioreactor landfills are gaining popularity as an alternative to the conventional landfill. The addition or recirculation of leachate to accelerate the waste decomposition changes the geotechnical characteristics of waste mass. The daily cover soils, usually up to 20-30% of total MSW volumes in the landfill, may also influence the decomposition and shear strength behavior of MSW. The objective of this paper is to study the effects of daily covers soils on the shear strength properties of municipal solid waste (MSW) in bioreactor landfills with time and decomposition. Two sets of laboratory-scale bioreactor landfills were simulated in a laboratory, and samples were prepared to represent different phases of decomposition. The state of decomposition was quantified by methane yield, pH, and volatile organic content (VOC). Due to decomposition, the matrix structure of the degradable solid waste component was broken down and contributed to a significant decrease in the reinforcing effect of MSW. However, the daily cover soil, a non-degradable constituent of MSW, remains constant. Therefore, the interaction between daily cover soil particles and MSW particles will affect shear strength behavior. A number of triaxial tests were performed to evaluate the shear strength of MSW. The test results indicated that the shear strength of MSW was affected by the presence of cover soils. The friction angle of MSW with the presence of cover soil is higher than the friction angle of MSW without any cover soils. The friction angle of MSW increased from 27 degrees to 30 degrees due to the presence of cover soils for Phase 1 samples. The increased strength was attributed to the friction nature of sandy soil that was used as daily covers soils. Therefore, the effects of cover soils on the shear strength properties of MSW should be evaluated and taken into consideration during stability analyses and design.

Pollution and Perceptions of Lead in Automobile Repair Shops in Dhaka, Bangladesh.

BACKGROUND: Lead acid batteries are widely used, dependable, and inexpensive. Lead from these batteries can contaminate the surrounding ecosystem due to improper disposal and contribute to lead poisoning. Lead poisoning is an important public health issue that can cause adverse human health impacts. OBJECTIVES: The present study aimed to assess exposure to lead released from automobile repair shops handling lead acid batteries in the city of Dhaka, Bangladesh, as well as shop owner and worker perceptions of lead pollution. METHODS: Ten dust samples were collected for atomic absorption spectrophotometer analysis to determine the concentration of lead. In addition, a questionnaire survey (N=75) was conducted to determine the level of knowledge of lead exposure and associated risks. RESULTS: Lead contamination was found in all dust samples, with lead concentrations ranging from 11.40 ppm to greater than 1000 ppm. In addition, 80% of respondents did not have any knowledge about the harmful effects of lead pollution. CONCLUSIONS: The present study suggests the importance of defining permissible air lead levels and improving worker education on lead pollution. ETHICS APPROVAL: The study was approved by the Ethics Committee of the Department of Environmental Science, Stamford University, Bangladesh. COMPETING INTERESTS: The authors declare no competing financial interests.

Monitoring extent of moisture variations due to leachate recirculation in an ELR/bioreactor landfill using resistivity imaging.

Bioreactor or enhanced leachate recirculation (ELR) landfills are designed and operated for accelerated waste stabilization, accelerated decomposition, and an increased rate of gas generation. The major aspects of a bioreactor landfill are the addition of liquid and the recirculation of collected leachate back into the waste mass through the subsurface leachate recirculation system (LRS). The performance of the ELR landfill largely depends on the existing moisture content within the waste mass; therefore, it is of utmost importance to determine the moisture variations within the landfill. Traditionally, the moisture variation of the ELR landfill is determined by collecting samples through a bucket auger boring from the landfill, followed by laboratory investigation. Collecting the samples through a bucket auger boring is time consuming, labor intensive, and cost prohibitive. Moreover, it provides the information for a single point within the waste mass, but not for the moisture distribution within the landfill. Fortunately, 2D resistivity imaging (RI) can be performed to assess the moisture variations within the landfill and provide a continuous image of the subsurface, which can be utilized to evaluate the performance of the ELR landfill. During this study, the 2D resistivity imaging technique was utilized to determine the moisture distribution and moisture movement during the recirculation process of an ELR landfill in Denton, Texas, USA. A horizontal recirculation pipe was selected and monitored periodically for 2.5years, using the RI technique, to investigate the performance of the leachate recirculation. The RI profile indicated that the resistivity of the solid waste decreased as much as 80% with the addition of water/leachate through the recirculation pipe. In addition, the recirculated leachate traveled laterally between 11m and 16m. Based on the resistivity results, it was also observed that the leachate flow throughout the pipe was non-uniform. The non-uniformity of the leachate flow confirms that the flow of leachate through waste is primarily through preferential flow paths due the heterogeneous nature of the waste.

Investigation of degree of saturation in landfill liners using electrical resistivity imaging.

During construction of compacted clay liners and evapotranspiration (ET) covers, quality control involves laboratory and field tests in individual lifts. However, the available methods may be inadequate to determine non-uniform compaction conditions, poor bonding of lifts, and/or variable soil composition. Moreover, the applicability of the available methods is restricted, in many instances, when spatial variability of the subsurface is expected. Resistivity Imaging (RI) is a geophysical method employed to investigate a large area in a rapid and non-destructive way. High resistivity of clay liner soil is an indication of a low degree of saturation, high air-filled voids, and poor lift bonding. To utilize RI as a quality control tool in a landfill liner, it is important to determine the saturation condition of the compacted soils because compaction and permeability of liner soil are functions of degrees of saturation. The objective of the present study is to evaluate the degree of saturation of a municipal solid waste (MSW) landfill liner, using RI. Electrical resistivity tests were performed in the laboratory, at varied moisture contents and dry unit weights, on four types of soil samples, i.e., highly plastic clay (CH), low plastic clay (CL), Ca-bentonite, and kaolinite. According to the experimental results, electrical resistivity of the specimens decreased as much as 15.3 times of initial value with increase in the degrees of saturation from 23% to 100%. In addition, cation exchange capacity (CEC) substantially affected resistivity. A multiple linear regression (MLR) model was developed to correlate electrical resistivity with degree of saturation and CEC using experimental results. Additionally, RI tests were conducted on compacted clay liners to determine the degrees of saturation, and predicted degrees of saturation were compared with the in-situ density tests. The study results indicated that the developed model can be utilized for liner soils having CEC, resistivity and degrees of saturation between 13.3 and 79cmol+/kg, and 2.6 and 504.3Ohmm, and 21.8% to 100%; respectively.

E-waste: A Challenge for Sustainable Development.

BACKGROUND: E-waste has been identified as the fastest growing waste stream in the world at present. Rapid socio-economic development and technological advancement are the main drivers of this trend. The hazardous chemical components of e-waste have potential adverse impacts on ecosystems and human health if not managed properly. This represents an imminent challenge to achieving sustainable development goals. Although technologically developed countries are the main source of e-product production and e-waste generation, the generated volume has also been increasing in developing countries and those in transition due to transport and transfer from e-waste source countries. Consequently, developing countries are in a vulnerable situation due to their lack of inventory data, waste management policies and advanced technology for environmentally sound management. OBJECTIVES: This study aims to demonstrate that the present global e-waste scenarios and health hazards could prolong the achievement of sustainable development targets. This study illustrates scenarios from different perspectives and raises concerns about e-waste, identifies information gaps, and provides a basis for knowledge and awareness building and technological improvement to facilitate global long-term sustainable development. DISCUSSION: Total and per capita global e-waste generation has been increased along with socio-economic development. These products present a significant global challenge due to the hazardous chemicals they contain, their highly technical recycling requirements and the high overhead and costs of environmentally sound management, as well as their adverse impacts to human health. Although high-income countries are the main sources of this waste, low-income countries are experiencing an increase in e-waste due to the shifting process of both recently produced and used electric and electronic equipment (UEEE), as well as cheap management overhead costs. Consequently, they bear the greatest burden of adverse health hazards and ecosystem degradation, prolonging their achievement of sustainable development goals. CONCLUSIONS: Sustainability is being prioritized for all development activities by integrating societal, economic, environmental, technological, cultural, and gender perspectives. Considering the adverse potential eco-toxicological impacts and diverse health effects of e-waste, an urgent global multilateral agreement is needed addressing its management (i.e., handling, storage, transportation, recycling, and final disposal), whether by land filling or incineration. Due to the global nature of the issue and the difficulty of establishing sustainable and environmentally sound processing of e-waste in low-income countries, multinational negotiation and collaboration is the only realistic solution. Furthermore, comprehensive global e-waste management and policies could help to off-set the hazards of e-waste and are the best approach for achieving sustainable development.