On-Chip Meta-Optics for Engineering Arbitrary Trajectories with Longitudinal Polarization Variation.

On-chip integrated meta-optics promise to achieve high-performance and compact integrated photonic devices. To arbitrarily engineer the optical trajectory along the propagation path in an on-chip integrated scheme is of significance in fundamental physics and various emerging applications. Here, we experimentally demonstrate an on-chip metasurface integrated on a waveguide to enable predefined arbitrary optical trajectories in the visible regime. By transformation of the transverse phase to generate longitudinal mapping, the guided waves are extracted and molded into any different optical trajectories (parabola, hyperbola, and cosine). More intriguingly, predefined polarization states with longitudinal variation are also successfully imparted along the trajectory. Owing to the on-chip propagation scheme, the trajectories are uniquely free from zero-order diffraction interference, naturally having a higher signal-to-noise ratio beyond conventional free-space forms. Overall, such on-chip optical trajectory engineering allows for miniaturized integration and can find paths in potential applications of complex optical manipulation, advanced laser fabrication, and microscopic imaging.

Double Superconducting Dome of Quasi Two-Dimensional TaS2 in Non-Centrosymmetric van der Waals Heterostructure.

Two-dimensional van der Waals heterostructures (2D-vdWHs) based on transition metal dichalcogenides (TMDs) provide unparalleled control over electronic properties. However, the interlayer coupling is challenged by the interfacial misalignment and defects, which hinders a comprehensive understanding of the intertwined electronic orders, especially superconductivity and charge density wave (CDW). Here, by using pressure to regulate the interlayer coupling of non-centrosymmetric 6R-TaS2 vdWHs, we observe an unprecedented phase diagram in TMDs. This phase diagram encompasses successive suppression of the original CDW states from alternating H-layer and T-layer configurations, the emergence and disappearance of a new CDW-like state, and a double superconducting dome induced by different interlayer coupling effects. These results not only illuminate the crucial role of interlayer coupling in shaping the complex phase diagram of TMD systems but also pave a new avenue for the creation of a novel family of bulk heterostructures with customized 2D properties.

Pressure-Induced Re-Entrant Superconductivity in Transition Metal Dichalcogenide TiSe2.

Transition metal dichalcogenide TiSe2 exhibits a superconducting dome within a low pressure range of 2-4 GPa, which peaks with the maximal transition temperature Tc of ≈1.8 K. Here it is reported that applying high pressure induces a new superconducting state in TiSe2, which starts at ≈16 GPa with a substantially higher Tc that reaches 5.6 K at ≈21.5 GPa with no sign of decline. Combining high-throughput first-principles structure search, X-ray diffraction, and Raman spectroscopy measurements up to 30 GPa, It is found that TiSe2 undergoes a first-order structural transition from the 1T phase under ambient pressure to a new 4O phase under high pressure. Comparative ab initio calculations reveal that while the conventional phonon-mediated pairing mechanism may account for the superconductivity observed in 1T-TiSe2 under low pressure, the electron-phonon coupling of 4O-TiSe2 is too weak to induce a superconducting state whose transition temperature is as high as 5.6 K under high pressure. The new superconducting state found in pressurized TiSe2 requires further study on its underlying mechanism.

Monolithic MOF-Based Metal-Insulator-Metal Resonator for Filtering and Sensing.

Metal-insulator-metal (MIM) configurations based on Fabry-Pérot resonators have advanced the development of color filtering through interactions between light and matter. However, dynamic color changes without breaking the structure of the MIM resonator upon environmental stimuli are still challenging. Here, we report monolithic metal-organic framework (MOF)-based MIM resonators with tunable bandwidth that can boost both dynamic optical filtering and active chemical sensing by laser-processing microwell arrays on the top metal layer. Programmable tuning of the reflection color of the MOF-based MIM resonator is achieved by controlling the MOF layer thicknesses, which is demonstrated by simulation of light-matter interactions on subwavelength scales. Laser-processed microwell arrays are used to boost sensing performance by extending the pathway for diffusion of external chemicals into nanopores of the MOFs. Both experiments and molecular dynamics simulations demonstrate that tailoring the period and height of the microwell array on the MIM resonator can advance the high detection sensitivity of chemicals.

Global warming potential assessment under reclaimed water and livestock wastewater irrigation coupled with co-application of inhibitors and biochar.

The application of nitrification inhibitors (nitrapyrin) and urease inhibitors (N-(N-butyl) thiophosphoric triamide) under conventional water resources has been considered as an effective means to improve nitrogen utilization efficiency and mitigate soil greenhouse gas emissions. However, it is not known whether the inhibitors still have an inhibitory effect under unconventional water resources (reclaimed water and livestock wastewater) irrigation and whether their use in combination with biochar improves the mitigation effect. Therefore, unconventional water resources were used for irrigation, with groundwater (GW) control. Nitrapyrin and N-(N-butyl) thiophosphoric triamide were used alone or in combination with biochar in a pot experiment, and CO2, N2O, and CH4 emissions were measured. The results showed that irrigation of unconventional water resources exacerbated global warming potential (GWP). All exogenous substance treatments increased CO2 and CH4 emissions and suppressed N2O emissions, independent of the type of water, compared to no substances (NS). The inhibitors were ineffective in reducing the GWP whether or not in combination with biochar, and the combined application of inhibitors with biochar further increased the GWP. This study suggests that using inhibitors and biochar in combination to regulate the greenhouse effect under unconventional water resources irrigation should be done with caution.

The energy metabolism of Balantidium polyvacuolum inhabiting the hindgut of Xenocypris davidi.

Anaerobic parasitic ciliates are a specialized group of ciliates that are adapted to anoxic and oxygen-depleted habitats. Among them, Balantidium polyvacuolum, which inhabits the hindgut of Xenocyprinae fishes, has received very limited scientific attention, so the molecular mechanism of its adaptation to the digestive tract microenvironment is still unclear. In this study, transmission electron microscopy (TEM) and single-cell transcriptome analysis were used to uncover the metabolism of B. polyvacuolum. Starch granules, endosymbiotic bacteria, and multiple specialized mitochondrion-related organelles (MROs) of various shapes were observed. The MROs may have completely lost the electron transport chain (ETC) complexes I, III, IV, and V and only retained succinate dehydrogenase subunit A (SDHA) of complex II. The tricarboxylic acid (TCA) cycle was also incomplete. It can be inferred that the hypoxic intestinal environment has led to the specialization of the mitochondria in B. polyvacuolum. Moreover, carbohydrate-active enzymes (CAZymes), including carbohydrate esterases, enzymes with a carbohydrate-binding module, glycoside hydrolases, and glycosyltransferases, were identified, which may constitute evidence that B. polyvacuolum is able to digest carbohydrates and starch. These findings can improve our knowledge of the energy metabolism and adaptive mechanisms of B. polyvacuolum.

Pressure-Modulated Anomalous Organic-Inorganic Interactions Enhance Structural Distortion and Second-Harmonic Generation in MHyPbBr3 Perovskite.

Organic-inorganic halide perovskites possess unique electronic configurations and high structural tunability, rendering them promising for photovoltaic and optoelectronic applications. Despite significant progress in optimizing the structural characteristics of the organic cations and inorganic framework, the role of organic-inorganic interactions in determining the structural and optical properties has long been underappreciated and remains unclear. Here, by employing pressure tuning, we realize continuous regulation of organic-inorganic interactions in a lead halide perovskite, MHyPbBr3 (MHy+ = methylhydrazinium, CH3NH2NH2+). Compression enhances the organic-inorganic interactions by strengthening the Pb-N coordinate bonding and N-H···Br hydrogen bonding, which results in a higher structural distortion in the inorganic framework. Consequently, the second-harmonic-generation (SHG) intensity experiences an 18-fold increase at 1.5 GPa, and the order-disorder phase transition temperature of MHyPbBr3 increases from 408 K under ambient pressure to 454 K at the industrially achievable level of 0.5 GPa. Further compression triggers a sudden non-centrosymmetric to centrosymmetric phase transition, accompanied by an anomalous bandgap increase by 0.44 eV, which stands as the largest boost in all known halide perovskites. Our findings shed light on the intricate correlations among organic-inorganic interactions, octahedral distortion, and SHG properties and, more broadly, provide valuable insights into structural design and property optimization through cation engineering of halide perovskites.

In-plane emission manipulation of random optical modes by using a zero-index material.

In this work, we have proposed to implement a zero-index material (ZIM) to control the in-plane emission of planar random optical modes while maintaining the intrinsic disordered features. Light propagating through a medium with near-zero effective refractive index accumulates little phase change and is guided to the direction determined by the conservation law of momentum. By enclosing a disordered structure with a ZIM based on all-dielectric photonic crystal (PhC), broadband emission directionality improvement can be obtained. We find the maximum output directionality enhancement factor reaches 30, around 6-fold increase compared to that of the random mode without ZIM. The minimum divergence angle is ∼6° for single random optical mode and can be further reduced to ∼3.5° for incoherent multimode superposition in the far field. Despite the significant directionality enhancement, the random properties are well preserved, and the Q factors are even slightly improved. The method is robust and can be effectively applied to the disordered medium with different structural parameters, e.g., the filling fraction of scatterers, and different disordered structure designs with extended or strongly localized modes. The output direction of random optical modes can also be altered by further tailoring the boundary of ZIM. This work provides a novel and universal method to manipulate the in-plane emission direction as well as the directionality of disordered medium like random lasers, which might enable its on-chip integration with other functional devices.

Nanoscale and ultra-high extinction ratio optical memristive switch based on plasmonic waveguide with square cavity.

A resistive switch effect-based optical memristive switch with an ultra-high extinction ratio and ultra-compact size working at 1550 nm is proposed. The device is composed of a metal-insulator-metal waveguide and a square resonator with active electrodes. The formation and rupture of conductive filaments in the resonant cavity can alter the resonant wavelength, which triggers the state of the optical switch ON or OFF. The numerical results demonstrate that the structure has an ultra-compact size (less than 1 µm) and ultra-high extinction ratio (37 dB). The proposed device is expected to address the problems of high-power consumption and large-scale optical switches and can be adopted in optical switches, optical modulation, optical storage and computing, and large-scale photonic integrated devices.

Combination of intercropping maize and soybean with root exudate additions reduces metal mobility in soil-plant system under wastewater irrigation.

The effects of root exudates and irrigation with treated wastewater on heavy metal mobility and soil bacterial composition under intercropping remain poorly understood. We conducted a pot experiment with maize and soybean grown in monocultures or intercultures, irrigated with either groundwater or treated wastewater. In addition, the pre-collected root exudates from hydroponic culture with mono- or inter-cropped maize and soybean were applied to the soil at four levels (0 %, 16 %, 32 % and 64 %). The results showed that application of root exudates increased plant growth and soil nutrient content. The analysis of "Technique for Order of Preference by Similarity to Ideal Solution" for higher plant biomass and lower soil Cd and Pb concentrations indicated that the best performance of soybean under treated wastewater irrigation was recorded under intercropping applied with 64 % of exudates, with a performance score of 0.926 and 0.953 for Cd and Pb, respectively. The second-best performance of maize under treated wastewater irrigation was also observed under intercropping applied with 64 % of exudates. Root exudate application reduced heavy metals migration in the soil-plant system, with a greater impact in intercropping than in monocropping. In addition, certain soil microorganisms were also increased with root exudate application, regardless of irrigation water. This study suggests that appropriate application of root exudates could potentially improve plant growth and soil health, and reduce toxic heavy metal concentrations in soils and plants irrigated with treated wastewater.

Free-Space Optical Merging via Meta-Grating Inverse-Design.

Despite various advances in achieving arbitrary optics steering, one of the longstanding challenges is to achieve optical merging for combining multidirectional beams through single-time reflection/transmission in free space. Typically, dual-directional beam merging is conducted by combining half-transmission and half-reflection using beam splitters; however, it leads to a bulky system with stray light and low merging efficiency. The difficulty of free-space beam merging lies in imparting respective distinct wavevectors to different directional beams. Herein, we originally proposed and successfully demonstrated the free-space optical merging (FOM) functionality based on the inverse-designed meta-grating architecture in the visible regime. By utilizing the inverse problem solver, two proposed meta-grating schemes experimentally enable merging of dual-directional beams into the same outgoing angle for the first time merely through single-time reflection. We envision that the creation of free-space merging performance can be widely applicable to the future optical system and facilitate the miniature optical devices and integration.

Scalable Hydrogel-Based Nanocavities for Switchable Meta-Holography with Dynamic Color Printing.

Devices used for meta-optics display are currently undergoing a revolutionary transition from static to dynamic. Despite various tuning strategy demonstrations such as mechanical, electrical, optical, and thermal tunings, a longstanding challenge for their practical application has been the achievement of a conveniently accessible real-life tuning scheme for realizing versatile functionality dynamics outside the laboratory. In this study, we demonstrate a practical tuning strategy to realize a dynamic color printing with a switchable meta-holography exhibition based on hydrogel-based nanocavities. On the basis of the inflation sensitivity of a hydrogel to humidity alteration, its transmissive color was notably tuned from 450 to 750 nm. More intriguingly, by controlling the sample dry/immersed states in real time, we successfully enabled dual-channel switchable meta-holography. With the advantages of facile architecture, daily stimulus with large-area modulation, and high chromaticity, our proposed hydrogel-based nanocavities provide a promising path toward tunable display/encryption, optical sensors, and next-generation display technology.

Immersion-Triggered Active Switch for Spin-Decoupled Meta-Optics Multi-Display.

Meta-optics exhibits many promising applications in various fields of optical displays, imaging, and information encryption. However, heading towards next-generation intelligent displays, its broad implementation is critically restricted by the lack of practical active tuning capability. Beyond the conventional electrical/optical/mechanical/thermal tuning methods, liquid immersion has recently emerged as a facile mechanism for active spectral tuning. To further conquer the challenge in achieving active complicated optical-field manipulation, here, an environment-compliant switch for meta-optics multi-display is originally proposed and experimentally realized via the liquid immersion tuning scheme. By designing the spin-decoupled phase array for left-/right-handed circular polarizations, it flexibly presents quad-fold independent-encoded phase distributions for different medium-relevant and polarization-controlled channels, thus enabling four switchable holographic images through immersion tuning. Such a proposed immersion tuning design is quite a straightforward approach for meta-optics holographic displays, enjoying full-spatial usage, design flexibility, and large-scale facile implementation. Overall, the proposed liquid immersion tuning strategy for a meta-optics multi-display would strongly benefit the practical applications in biochemical sensing, environment-adaptive displays, and information encryption.

Hydrogel-Based, Dynamically Tunable Plasmonic Metasurfaces with Nanoscale Resolution.

Flat metasurfaces with subwavelength meta-atoms can be designed to manipulate the electromagnetic parameters of incident light and enable unusual light-matter interactions. Although hydrogel-based metasurfaces have the potential to control optical properties dynamically in response to environmental conditions, the pattern resolution of these surfaces has been limited to microscale features or larger, limiting capabilities at the nanoscale, and precluding effective use in metamaterials. This paper reports a general approach to developing tunable plasmonic metasurfaces with hydrogel meta-atoms at the subwavelength scale. Periodic arrays of hydrogel nanodots with continuously tunable diameters are fabricated on silver substrates, resulting in humidity-responsive surface plasmon polaritons (SPPs) at the nanostructure-metal interfaces. The peaks of the SPPs are controlled reversibly by absorbing or releasing water within the hydrogel matrix, the matrix-generated plasmonic color rendering in the visible spectrum. This work demonstrates that metasurfaces designed with these spatially patterned nanodots of varying sizes benefit applications in anti-counterfeiting and generate multicolored displays with single-nanodot resolution. Furthermore, this work shows system versatility exhibited by broadband beam-steering on a phase modulator consisting of hydrogel supercell units in which the size variations of constituent hydrogel nanostructures engineer the wavefront of reflected light from the metasurface.

On-chip asymmetric beam-steering for broadband visible light.

Artificial optical nanostructures including three-dimensional (3D) metamaterials and two-dimensional (2D) metasurfaces have shown overwhelming capability to control electromagnetic waves in desirable manners. However, the challenges of manufacturing a complex 3D bulk architecture or achieving nanoscale alignment between multilayers limit their practical applications, and they are unable to be used in on-chip integrated photonic devices. Therefore, the emerging dimensionality-reduction to on-chip metadevices would be of promising research value. Here, we propose a visible-frequency on-chip dual-layer design by cascading one-dimensional (1D) plasmonic metawires with metagratings, which can effectively manipulate surface plasmon polariton (SPP) wavefronts and exhibit on-chip asymmetric beam-steering functionality. Our 1D metawires consist of trapezoidal plasmonic nanoantennas and can enable broadband (460-700 nm) on-chip beam-deflection with a high conversion efficiency. The cascading plasmonic coupling between metawires/metagrating is further demonstrated with broadband asymmetric propagation performance, which is crucial for on-chip plasmonic device development. Finally, we study and theoretically verify a cascade system that integrates a dual-functional (convergent/divergent) lens for the forward/backward propagation, respectively. Compared with conventional free-space multilayer metasurfaces, on-chip 1D metawires enjoy single-time lithography processing and no alignment requirement for implementation in multifunctional devices. We believe that the proof-of-concept on-chip metawires study will pave a new, to the best of our knowledge, way for creating multifunctional photonic integrated devices and hold tremendous potential in realizing on-chip transformation optics, information processing, spectrometers, as well as optical sensors.

The unique features of SARS-CoV-2 transmission: Comparison with SARS-CoV, MERS-CoV and 2009 H1N1 pandemic influenza virus.

From 2002 to 2019, three deadly human coronaviruses (hCoVs), severe acute respiratory syndrome coronavirus (SARS-CoV), Middle Eastern respiratory syndrome coronavirus (MERS-CoV) and severe acute respiratory syndrome coronavirus-2 (SARS-CoV-2) emerged to produce outbreaks of SARS, MERS and coronavirus disease 2019 (Covid-19), respectively. All three hCoVs are members of the Betacoronavirus genus in the subfamily Orthocoronavirinae and share many similarities in virology and epidemiology. However, the pattern and scale of Covid-19 global spread is similar to 2009 pandemic H1N1 influenza (H1N1pdm09), rather than SARS or MERS. Covid-19 exhibits high viral shedding in the upper respiratory tract at an early stage of infection, and has a high proportion of transmission competent individuals that are pre-symptomatic, asymptomatic and mildly symptomatic, characteristics seen in H1N1pdm09 but not in SARS or MERS. These two traits of Covid-19 and H1N1pdm09 result in reduced efficiency in identification of transmission sources by symptomatic screening and play important roles in their ability to spread unchecked to cause pandemics. To overcome these attributes of Covid-19 in community transmission, identifying the transmission source by testing for virus shedding and interrupting chains of transmission by social distancing and public masking are required.

Mechanism of endometrial MUC2 in reproductive performance in mice through PI3K/AKT signaling pathway after lipopolysaccharide treatment.

The objective of this study was to investigate the effects of exposure to endotoxin on the reproductive performance of humans and animals in pregnancy and delivery period. Mucin is considered to play a critical role in protecting the tissue epithelium. At pregnancy period, the MUC2 expression of uterus in the High LPS group was significantly higher than that in the Control group. The glycosaminoglycans of gland cells were secreted into the uterine cavity to protect the uterus. Then, the MUC2 layer became thinner, and LPS entered the lamina propria of the uterus. The mRNA expression of tight junction proteins showed a marked drop, and morphological damage of the uterus occurred. Subsequently, the glycosaminoglycans of gland cells in the High LPS and Low LPS groups increased with the increasing LPS dose, and the damage to the endometrial epithelium was repaired in female mice at Day 5 postdelivery. A low dose of LPS activated the PI3K/AKT signaling pathways to increase the glycosaminoglycans particles, while a high dose of LPS inhibited the PI3K/AKT signaling pathway to decrease the glycosaminoglycans particles. Taken together, our results suggest that gland cells secreted glycosaminoglycans particles into the uterine cavity by exocytosis to increase the thickness of the mucus layer to protect the uterus and that this process was regulated by PI3K/AKT signaling pathways.

3D Meta-Prisms for Versatile Beam Steering by Hybridizing Plasmonic and Diffractive Effect in the Broadband Visible Regime.

As two independent optical sub-fields, diffraction optics and plasmonics both have been used for wavefront shaping and beam steering. However, the two separate concepts have always been developing as two parallel directions, which have not met for studying their structural hybridization to discover new potentials. For instance of the flat metasurfaces, even though the geometric parameters including shape, size, and periodicity have been studied, it remains mostly unexplored for the 3D spatial height variation. Here, a new type of all-metallic 3D meta-prism is proposed and experimentally demonstrated by hybridizing the localized surface plasmonic resonances (LSPR) and the blazed grating diffraction, which enables strong polarization-dependent behaviors to steer broadband visible light to drastically inverse directions. The nanofabrication of 3D meta-prism is achieved by nanostencil lithography with electron-beam evaporation. Such meta-prism could also enable to split different visible light (green, blue, and red) with high-efficiency contrast (≈10). By the mirror-symmetry arrangement, a multifunctional surface is demonstrated with polarization-/wavelength-multiplexing wavefront-shaping functions (concave, convex, or flat mirror). This unique 3D meta-prism enjoys great simplicity and versatility in broadband beam steering through the incorporation of plasmonic and diffractive effects and can be utilized in various applications including dichroic-prism splitters, multifunctional meta-mirrors, etc.

Dual-encryption freedom via a monolayer-nanotextured Janus metasurface in the broadband visible.

As an emerging category of two-faced 2D architecture, the Janus metasurface aims to explore another universal optical property, that is, the wavevector direction (k-direction), and to enable the asymmetric transmission between the opposite directional incidences. It exhibits significant potential in creating versatile multiplexing metasurfaces and an optical isolator in optical communication applications. However, most previous asymmetric functionality shows merely one-way functionality with the other-way simply muted or demands multilayered nanostructure fabrication and alignment. Hence, it remains a great challenge to make a monolayer-nanotextured Janus metasurface with dual-encryption freedom and conquering the difficulty for multilayer alignment and practical operation bandwidth. In this work, we have proposed and experimentally demonstrated a new strategy of a dual-encryption Janus metasurface design with a simple monolayer-nanotextured metasurface coupled with a commercialized film of the half-wave plate. Utilizing the hybridization from two independent geometrical dimensions of rectangular-antennas, our approach ingeniously transforms the polarization-multiplexing into the dual-directional channels. A series of calculations and experimental results demonstrate that our asymmetric approach simultaneously constructs completely independent imaging encryptions for both forward and backward directions. Additionally, our proposed approach becomes a practical scheme with broadband visible-frequency operation and great simplicity in design and nanofabrication. We believe the universal scheme could facilitate to increase the information encoding capacity and holographic multiplexing channels by expanding the illumination wavevector to the full-space (+/-), and it paves the route toward the potential applications in on-chip integration, telecommunications, encryption, information processing, and communication.

Polarization-insensitive broadband visible-light steering with tunable direction enabled by scalable plasmonics meta-gratings.

As an emerging field in the discipline of optics, plasmonics and metasurfaces have been demonstrated to enable a new degree of freedom to manipulate light for arbitrary beam steering, spectral splitting as well as precise wavefront shaping. However, it has been mostly studied in parallel with the field of diffractive optics, and awaits the unveiling of how the hybridizations between plasmonic effect and diffraction effect interact and impact. Here, we have theoretically proposed a new type of polarization-insensitive meta-grating structure across the broadband visible regime. The structure design combines the width gradient (critical resonant length) from a trapezoid-nanoantenna with the height gradient from a blazed grating profile. The hybridized meta-grating creates both plasmonic effect and grating effect, which enables all the optical incident photons to be directed to the same orientation regardless of the light polarization. As we know, both metasurfaces and diffractive optical elements (such as gratings) are, more often than not, quite sensitive to the incident light polarization. Moreover, if placing our meta-grating on a flexible/stretchable substrate (such as polydimethylsiloxane), the outgoing angle can be effectively adjusted by tuning the period or density of meta-grating arrays. Such meta-grating architectures can be potentially manufactured by existing photolithography and nanoimprint techniques, and can easily find a wide range of practical polarization-insensitive applications, including broadband deflector and emitter, tunable display and imaging device, high signal-to-noise ratio spectrometer, polarization-insensitive plasmonic coupler, etc.