RESUMO
The title compound, C(23)H(30)ClN(5)O(3) (2+)·2Cl(-)·0.5H(2)O, was synthesized by N-alkyl-ation of 1-({[5-(4-chloro-phen-yl)-2-furan-yl]methyl-ene}amino)-2,4-imidazolidinedione with 1-bromo-4-chloro-butane, and N-methyl-piperazine. In the crystal, the cations, anions and water mol-ecules are linked by O-Hâ¯Cl and N-Hâ¯Cl hydrogen bonds.
RESUMO
In the title mol-ecule, C(13)H(14)O(3)S(2), the thio-phene and benzene rings form a dihedral angle of 13.86â (13)°. In the crystal, weak inter-molecular C-Hâ¯O hydrogen bonds link the mol-ecules into layers parallel to the ab plane.
RESUMO
In the title compound, C(27)H(30)O(6), also known as sofalcone, an anti-ulcer agent used for the protection of gastric mucosa-, the two benzene rings form a dihedral angle of 6.78â (11)°. Inter-molecular O-Hâ¯O hydrogen bonds link the mol-ecules into centrosymmetric dimers, which are further linked by weak C-Hâ¯O inter-actions into ribbons propagated in [2[Formula: see text]0]. Finally, π-π inter-actions between the benzene rings [centroid-centroid distance = 3.583â (13)â Å] stabilize the crystal packing.
RESUMO
In the title compound, C(8)H(6)ClNO(4), the nitro and acet-oxy groups attached to the benzene ring at neighbouring positions are twisted from its plane by 29.4â (1) and 49.7â (1)°, respectively. In the crystal, weak C-Hâ¯O hydrogen bonds link mol-ecules into layers parallel to (101). The crystal packing exhibits short inter-molecular Câ¯O distances of 2.925â (3)â Å.
RESUMO
The title compound, C(15)H(17)ClNO(2)S(+)·C(10)H(15)O(4)S(-)·C(3)H(6)O, was synthesized by N-alkyl-ation of α-amino-(2-chloro-phen-yl)acetate with 2-thienylethyl p-toluene-sulfonate, followed by reaction with (+)-camphor-10-sulfonic acid. In the crystal, the cations and anions are linked through N-Hâ¯O hydrogen bonds. The thio-phene ring of the cation was found to be disordered over two sites, with refined occupancies of 0.798â (4) and 0.202â (4).