Day-night cloud asymmetry prevents early oceans on Venus but not on Earth.

Earth has had oceans for nearly four billion years1 and Mars had lakes and rivers 3.5-3.8 billion years ago2. However, it is still unknown whether water has ever condensed on the surface of Venus3,4 because the planet-now completely dry5-has undergone global resurfacing events that obscure most of its history6,7. The conditions required for water to have initially condensed on the surface of Solar System terrestrial planets are highly uncertain, as they have so far only been studied with one-dimensional numerical climate models3 that cannot account for the effects of atmospheric circulation and clouds, which are key climate stabilizers. Here we show using three-dimensional global climate model simulations of early Venus and Earth that water clouds-which preferentially form on the nightside, owing to the strong subsolar water vapour absorption-have a strong net warming effect that inhibits surface water condensation even at modest insolations (down to 325 watts per square metre, that is, 0.95 times the Earth solar constant). This shows that water never condensed and that, consequently, oceans never formed on the surface of Venus. Furthermore, this shows that the formation of Earth's oceans required much lower insolation than today, which was made possible by the faint young Sun. This also implies the existence of another stability state for present-day Earth: the 'steam Earth', with all the water from the oceans evaporated into the atmosphere.

Possible Effects of Volcanic Eruptions on the Modern Atmosphere of Venus.

This work reviews possible signatures and potential detectability of present-day volcanically emitted material in the atmosphere of Venus. We first discuss the expected composition of volcanic gases at present time, addressing how this is related to mantle composition and atmospheric pressure. Sulfur dioxide, often used as a marker of volcanic activity in Earth's atmosphere, has been observed since late 1970s to exhibit variability at the Venus' cloud tops at time scales from hours to decades; however, this variability may be associated with solely atmospheric processes. Water vapor is identified as a particularly valuable tracer for volcanic plumes because it can be mapped from orbit at three different tropospheric altitude ranges, and because of its apparent low background variability. We note that volcanic gas plumes could be either enhanced or depleted in water vapor compared to the background atmosphere, depending on magmatic volatile composition. Non-gaseous components of volcanic plumes, such as ash grains and/or cloud aerosol particles, are another investigation target of orbital and in situ measurements. We discuss expectations of in situ and remote measurements of volcanic plumes in the atmosphere with particular focus on the upcoming DAVINCI, EnVision and VERITAS missions, as well as possible future missions.

Sulfur monoxide dimer chemistry as a possible source of polysulfur in the upper atmosphere of Venus.

The abundance of SO dimers (SO)2 in the upper atmosphere of Venus and their implications for the enigmatic ultraviolet absorption has been investigated in several studies over the past few years. However, the photochemistry of sulfur species in the upper atmosphere of Venus is still not well understood and the identity of the missing ultraviolet absorber(s) remains unknown. Here we update an existing photochemical model of Venus' upper atmosphere by including the photochemistry of SO dimers. Although the spectral absorption profile of SO dimers fits the unknown absorber, their abundance is found to be too low for them to contribute significantly to the absorption. It is more likely that their photolysis and/or reaction products could contribute more substantively. Reactions of SO dimers are found to be important sources of S2O, and possibly higher order SnO species and polysulfur, Sn. All of these species absorb in the critical ultraviolet region and are expected to be found in both the aerosol and gas phase. indicating that in-situ high resolution aerosol mass spectrometry might be a useful technique for identifying the ultraviolet absorber on Venus.