Mechanism of Mg extraction from MgMn2O4 during acid digestion.

MgMn2O4 having a spinel structure is a very attractive material for the positive electrode in Mg-ion batteries, since its reversible Mg extraction/insertion reaction can lead to a large reversible capacity. While the Mg extraction from MgMn2O4 has been reported, the reaction mechanism remains unclear. In this paper, Mg ions were chemically extracted from MgMn2O4 by acid digestion at various concentrations to produce MgxMn2O4 (0 < x < 1). The results showed that Mg extraction from MgMn2O4 is a two-step two-phase reaction, via the intermediate Mg0.5Mn2O4 to the fully oxidised Mn2O4. The kinetics of Mg extraction was clarified using acid digestion experiments of different durations, and the direct reaction pathway of MgMn2O4 oxidation to λ-MnO2 was the fastest process. This may explain the difficulty in Mg extraction from MgMn2O4 using electrochemical methods.

Fast-forward assisted STIRAP.

We consider combined stimulated Raman adiabatic passage (STIRAP) and fast-forward field (FFF) control of selective vibrational population transfer in a polyatomic molecule. The motivation for using this combination control scheme is 2-fold: (i) to overcome transfer inefficiency that occurs when the STIRAP fields and pulse durations must be restricted to avoid excitation of population transfers that compete with the targeted transfer and (ii) to overcome transfer inefficiency resulting from embedding of the actively driven subset of states in a large manifold of states. We show that, in a subset of states that is coupled to background states, a combination of STIRAP and FFFs that do not individually generate processes that are competitive with the desired population transfer can generate greater population transfer efficiency than can ordinary STIRAP with similar field strength and/or pulse duration.

A model study of assisted adiabatic transfer of population in the presence of collisional dephasing.

Previous studies have demonstrated that when experimental conditions generate non-adiabatic dynamics that prevents highly efficient population transfer between states of an isolated system by stimulated Raman adiabatic passage (STIRAP), the addition of an auxiliary counter-diabatic field (CDF) can restore most or all of that efficiency. This paper examines whether that strategy is also successful in a non-isolated system in which the energies of the states fluctuate, e.g., when a solute is subject to collisions with solvent. We study population transfer in two model systems: (i) the three-state system used by Demirplak and Rice [J. Chem. Phys. 116, 8028 (2002)] and (ii) a four-state system, derived from the simulation studies of Demirplak and Rice [J. Chem. Phys. 125, 194517 (2006)], that mimics HCl in liquid Ar. Simulation studies of the vibrational manifold of HCl in dense fluid Ar show that the collision induced vibrational energy level fluctuations have asymmetric distributions. Representations of these asymmetric energy level fluctuation distributions are used in both models (i) and (ii). We identify three sources of degradation of the efficiency of STIRAP generated selective population transfer in model (ii): too small pulse areas of the laser fields, unwanted interference arising from use of strong fields, and the vibrational detuning. For both models (i) and (ii), our examination of the efficiency of STIRAP + CDF population transfer under the influence of the asymmetric distribution of the vibrational energy fluctuations shows that there is a range of field strengths and pulse durations under which STIRAP + CDF control of population transfer has greater efficiency than does STIRAP generated population transfer.

High-fidelity rapid ground-state loading of an ultracold gas into an optical lattice.

A protocol is proposed for the rapid coherent loading of a Bose-Einstein condensate into the ground state of an optical lattice, without residual excitation associated with the breakdown of adiabaticity. The driving potential required to assist the rapid loading is derived using the fast-forward technique, and generates the ground state in any desired short time. We propose an experimentally feasible loading scheme using a bichromatic lattice potential, which approximates the fast-forward driving potential with high fidelity.

Measurement-based preparation of stable coherent states of a Kerr parametric oscillator.

Kerr parametric oscillators (KPOs) have attracted increasing attention in terms of their application to quantum information processing and quantum simulations. The state preparation and measurement of KPOs are typical requirements when used as qubits. The methods previously proposed for state preparations of KPOs utilize modulation of external fields such as a pump and drive fields. We study the stochastic state preparation of stable coherent states of a KPO with homodyne detection, which does not require modulation of external fields, and thus can reduce experimental efforts and exclude unwanted effects of possible imperfection in control of external fields. We quantitatively show that the detection data, if averaged over an optimal averaging time to decrease the effect of measurement noise, has a strong correlation with the state of the KPO, and therefore can be used to estimate the state (stochastic state preparation). We examine the success probability of the state estimation taking into account the measurement noise and bit flips. Moreover, the proper range of the averaging time to realize a high success probability is obtained by developing a binomial-coherent-state model, which describes the stochastic dynamics of the KPO under homodyne detection.

Acceleration and deceleration of quantum dynamics based on inter-trajectory travel with fast-forward scaling theory.

Quantum information processing requires fast manipulations of quantum systems in order to overcome dissipative effects. We propose a method to accelerate quantum dynamics and obtain a target state in a shorter time relative to unmodified dynamics, and apply the theory to a system consisting of two linearly coupled qubits. We extend the technique to accelerate quantum adiabatic evolution in order to rapidly generate a desired target state, thereby realizing a shortcut to adiabaticity. Further, we address experimental limitations to the rate of change of control parameters for quantum devices which often limit one's ability to generate a desired target state with high fidelity. We show that an initial state following decelerated dynamics can reach a target state while varying control parameters more slowly, enabling more experimentally feasible driving schemes.

Controls of a superconducting quantum parametron under a strong pump field.

Pumped at approximately twice the natural frequency, a Josephson parametric oscillator called parametron or Kerr parametric oscillator shows self-oscillation. Quantum annealing and universal quantum computation using self-oscillating parametrons as qubits were proposed. However, controls of parametrons under the pump field are degraded by unwanted rapidly oscillating terms in the Hamiltonian, which we call non-resonant rapidly oscillating terms (NROTs) coming from the violation of the rotating wave approximation. Therefore, the pump field can be an intrinsic origin of the imperfection of controls of parametrons. Here, we theoretically study the influence of the NROTs on the accuracy of controls of a parametron: a cat-state creation and a single-qubit gate. It is shown that there is a trade-off relationship between the suppression of the nonadiabatic transitions and the validity of the rotating wave approximation in a conventional approach. We also show that the tailored time dependence of the detuning of the pump field can suppress both of the nonadiabatic transitions and the disturbance of the state of the parametron due to the NROTs.

Observation of microwave absorption and emission from incoherent electron tunneling through a normal-metal-insulator-superconductor junction.

We experimentally study nanoscale normal-metal-insulator-superconductor junctions coupled to a superconducting microwave resonator. We observe that bias-voltage-controllable single-electron tunneling through the junctions gives rise to a direct conversion between the electrostatic energy and that of microwave photons. The measured power spectral density of the microwave radiation emitted by the resonator exceeds at high bias voltages that of an equivalent single-mode radiation source at 2.5 K although the phonon and electron reservoirs are at subkelvin temperatures. Measurements of the generated power quantitatively agree with a theoretical model in a wide range of bias voltages. Thus, we have developed a microwave source which is compatible with low-temperature electronics and offers convenient in-situ electrical control of the incoherent photon emission rate with a predetermined frequency, without relying on intrinsic voltage fluctuations of heated normal-metal components or suffering from unwanted losses in room temperature cables. Importantly, our observation of negative generated power at relatively low bias voltages provides a novel type of verification of the working principles of the recently discovered quantum-circuit refrigerator.

Quantum-circuit refrigerator.

Quantum technology promises revolutionizing applications in information processing, communications, sensing and modelling. However, efficient on-demand cooling of the functional quantum degrees of freedom remains challenging in many solid-state implementations, such as superconducting circuits. Here we demonstrate direct cooling of a superconducting resonator mode using voltage-controllable electron tunnelling in a nanoscale refrigerator. This result is revealed by a decreased electron temperature at a resonator-coupled probe resistor, even for an elevated electron temperature at the refrigerator. Our conclusions are verified by control experiments and by a good quantitative agreement between theory and experimental observations at various operation voltages and bath temperatures. In the future, we aim to remove spurious dissipation introduced by our refrigerator and to decrease the operational temperature. Such an ideal quantum-circuit refrigerator has potential applications in the initialization of quantum electric devices. In the superconducting quantum computer, for example, fast and accurate reset of the quantum memory is needed.

Rotation of the Orientation of the Wave Function Distribution of a Charged Particle and its Utilization.

We describe a method for selecting and sorting particles in an ion trap with respect to charge and mass. The method exploits a so-called shortcut to adiabatic passage, specifically the fast-forward field protocol, to design an electromagnetic field that rotates the spatial orientation of the wave function of the desired ion. The electromagnetic field forces ions that have different mass and electrical charge from the desired ionic species out of the trapping potential without exciting the desired ionic species, leaving the latter undisturbed in the trap.