Solidification/stabilization of lead-contaminated soil using alkali-activated volcanic ash.

The bioaccumulation of lead in soil poses a significant human health risk. The solidification/stabilization (S/S) technique, employing binders like Portland cement or lime, is a common method for remediating lead-contaminated soil. However, cement production has adverse environmental impacts, prompting the exploration of eco-friendly alternatives like alkali-activated materials (AAMs). This study assesses AAM efficacy in the S/S of lead-contaminated soil. The effects of several factors, including varying amounts of volcanic ash (VA), lead concentration, curing temperatures, and curing times are investigated. Unconfined compressive strength (UCS), toxicity characteristic leaching procedure test (TCLP), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), and field emission scanning electron microscope-energy-dispersive spectroscopy-mapping analyses (FESEM/EDS/mapping) analyses are used to study the specimens. The findings indicated a substantial increase in the UCS of lead-contaminated soil treated with 15% VA (under oven curing (OC) conditions), and 10% VA (under ambient curing (AC) conditions) exhibited remarkable increases of up to 600% and 458%, respectively. Moreover, the leaching of Pb2+ ions from samples contaminated with 10,000 mg/kg (under OC conditions) and 2500 mg/kg (under AC conditions) experienced significant reductions of 87% (from 135.14 to 13.36 ppm) and 91% (from 26.32 to 2.21 ppm), respectively. The S/S process in these samples operated through three primary mechanisms of chemical bonding, physical encapsulation, and the formation of insoluble silicate. The formation of N-A-S-H and hydroxy sodalite structures played a vital role in facilitating these mechanisms. Therefore, alkali-activated VA demonstrated excellent performance in the remediation of lead-contaminated soil.

Properties of Lime-Cement Concrete Containing Various Amounts of Waste Tire Powder under Different Ground Moisture Conditions.

Lime-cement concrete (LCC) is a non-structural concrete in which lime and cement are used as the main binders. However, although LCC has many applications in reducing the settlement of foundations and providing a support layer for shallow foundations, little research has been conducted to evaluate its behaviour in various moisture conditions. Previous researchers have studied the feasibility of using waste tires in conventional concrete to alleviate their negative environmental impacts. However, in field projects, rubber has not been widely used because its application leads to the strength reduction of concrete. In the case of LCC, attaining high strengths is not required and thus application of waste tire particles sounds reasonable. This research evaluated the impact of various rubber powder contents on the fresh, geotechnical and durability properties of LCC at different saturation degrees induced by the capillary action and groundwater level increment, which has not been studied before. The results of more than 320 tests showed that the application of tire powder increases workability and decreases the water absorption of LCC. Moreover, all 60-day cured specimens exposed to 100% saturation degree experienced a strength reduction of less than 10% by using rubber powder contents varying from 0 to 20%. Moreover, increasing the saturation degree from 0 to 100% decreased the average compressive strength by 13.5 and 22% for 60-day cured samples of two different mix designs. The results of this research confirm that LCC containing up to 10% rubber powder could be promisingly used underneath or close to the groundwater table without its strength and geotechnical properties being jeopardized due to rubber employment and/or exposure to ground moisture.

Fresh, Mechanical, and Durability Properties of Self-Compacting Mortar Incorporating Alumina Nanoparticles and Rice Husk Ash.

This paper presents a comprehensive evaluation on self-compacting (SC) mortars incorporating 0, 1, 3, and 5% alumina nanoparticles (NA) as well as 0% and 30% rice husk ash (RHA) used as Portland cement replacement. To evaluate the workability, mechanical, and durability performance of SC mortars incorporating NA and RHA, the fresh properties (slump flow diameter and V-funnel flow time), hardened properties (compressive strength, flexural strength, and ultrasonic pulse velocity), and durability properties (water absorption, rapid chloride permeability, and electrical resistivity) were determined. The results indicated that the addition of NA and RHA has negligible effect on the workability and water absorption rate of the SC mortars. However, significant compressive and flexural strength development was observed in the SC mortars treated with NA or the combination of NA and RHA. The introduction of RHA and NA also reduced the rapid chloride permeability and enhanced the electrical resistivity of the SC mortars significantly. It is concluded that the coexistence of 30% RHA and 3% NA as cement replacement in SC mortars can provide the best mechanical and durability performance.

Mechanical Properties of Recycled Aggregate Concretes Containing Silica Fume and Steel Fibres.

In this study, the impact of steel fibres and Silica Fume (SF) on the mechanical properties of recycled aggregate concretes made of two different types of Recycled Coarse Aggregates (RCA) sourced from both low- and high-strength concretes were evaluated through conducting 60 compressive strength tests. The RCAs were used as replacement levels of 50% and 100% of Natural Coarse Aggregates (NCA). Hook-end steel fibres and SF were also used in the mixtures at the optimised replacement levels of 1% and 8%, respectively. The results showed that the addition of both types of RCA adversely affected the compressive strength of concrete. However, the incorporation of SF led to compressive strength development in both types of concretes. The most significant improvement in terms of comparable concrete strength and peak strain with ordinary concrete at 28 days was observed in the case of using a combination of steel fibres and SF in both recycled aggregate concretes, especially with RCA sourced from high strength concrete. Although using SF slightly increased the elastic modulus of both recycled aggregate concretes, a substantial improvement in strength was observed due to the reinforcement with steel fibre and the coexistence of steel fibre and SF. Moreover, existing models to predict the elastic modulus of both non-fibrous and fibrous concretes are found to underestimate the elastic modulus values. The incorporation of SF changed the compressive stress-strain curves for both types of RCA. The addition of steel fibre and SF remarkably improved the post-peak ductility of recycled aggregates concretes of both types, with the most significant improvement observed in the case of RCA sourced from a low-strength parent concrete. The existing model to estimate the compressive stress-strain curve for steel fibre-reinforced concrete with natural aggregates was found to reasonably predict the compressive stress-strain behaviour for steel fibres-reinforced concrete with recycled aggregate.