1.
Chem Commun (Camb)
; 55(76): 11446-11449, 2019 Sep 19.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31486470
RESUMO
Yb6(BDC)7(OH)4(H2O)4 contains both bridging hydroxyls and metal-coordinated waters, possessing Brønsted and Lewis acid sites. The material crystallises from water at 200 °C. Using the solid as a heterogenous catalyst, glucose is converted into 5-hydroxymethylfurfural, via fructose, with a total selectivity of â¼70% after 24 hours at 140 °C in water alone: the material is recyclable with no loss of crystallinity.