RESUMO
Electrocatalytic carbon-dioxide reduction reactions (ECO2 RR) are one of the most rational techniques to control one's carbon footprint. The desired product formation depends on deliberate reaction kinetics and a choice of electron-proton contribution. Herein the usage of novel CuS active centers decorated over stable 1T metallic N-WS2 /WO3 nanohybrids as an efficient selective formate conversion electrocatalyst with regard to ECO2 RR is reported. The preferred reaction pathway is identified as *OCHO, which is reduced (by gaining H+ + e- ) to HCOO- (HCOO- path) as the primary product. More significantly, at -1.3 V versus RHE yield of FEHCOO - is 55.6% ± 0.5 with a Jgeo of -125.05 mA cm-2 for CuS@1T-N-WS2 /WO3 nanohybrids. In addition, predominant catalytic activity, selectivity, and stability properties are observed; further post-mortem analysis demonstrates the choice of material importance. The present work describes an impressive approach to develop highly active electrocatalysts for selective ECO2 RR applications.