Experimental and computational characterisation of an artificial light harvesting complex.

Photosynthesis has been shown to be a highly efficient process for energy transfer in plants and bacteria. Like natural photosynthetic systems, the artificial light harvesting complex (LHC) BODIPY pillar[5]arene exhibits Förster resonance energy transfer (FRET). However, extensive characterisation of the BODIPY pillar[5]arene LHC to determine its suitability as an artificial LHC has yet to occur. In this paper we experimentally and computationally investigate the photophysical properties of the LHC by comparing the light absorption of the BODIPY LHC to individual BODIPY chromophores. Our results show evidence for quantum coherence, with oscillation frequencies of 100 cm-1 and 600 cm-1, which are attributable to vibronic, or exciton-phonon type coupling. Computational analysis suggests strong couplings of the molecular orbitals of the LHC resulting from the stacking of neighbouring BODIPY chromophore units. Interestingly, we find a 40% reduction in the absorbance of light for the BODIPY LHC compared to the individual chromophores which we attribute to electronic interactions between the conjugated π-systems of the BODIPY chromophores and the pillar[5]arene backbone.

Berry Phase from the Entanglement of Future and Past Light Cones: Detecting the Timelike Unruh Effect.

The Unruh effect can not only arise out of the entanglement between modes of left and right Rindler wedges, but also between modes of future and past light cones. We explore the geometric phase resulting from this timelike entanglement between the future and past, showing that it can be captured in a simple Λ system. This provides an alternative paradigm to the Unruh-deWitt detector. The Unruh effect has not been experimentally verified because the accelerations needed to excite a response from Unruh-deWitt detectors are prohibitively large. We demonstrate that a stationary but time-dependent Λ-system detects the timelike Unruh effect with current technology.

Erratum: Gravitational Casimir Effect [Phys. Rev. Lett. 114, 081104 (2015)].

This corrects the article DOI: 10.1103/PhysRevLett.114.081104.

Gravitational Casimir effect.

We derive the gravitonic Casimir effect with nonidealized boundary conditions. This allows the quantification of the gravitonic contribution to the Casimir effect from real bodies. We quantify the meagerness of the gravitonic Casimir effect in ordinary matter. We also quantify the enhanced effect produced by the speculated Heisenberg-Couloumb (HC) effect in superconductors, thereby providing a test for the validity of the HC theory, and, consequently, the existence of gravitons.

Transformation optics for cavity array metamaterials.

Cavity array metamaterials (CAMs), composed of optical microcavities in a lattice coupled via tight-binding interactions, represent a novel architecture for engineering metamaterials. Since the size of the CAMs' constituent elements are commensurate with the operating wavelength of the device, it cannot directly utilise classical transformation optics in the same way as traditional metamaterials. By directly transforming the internal geometry of the system, and locally tuning the permittivity between cavities, we provide an alternative framework suitable for tight-binding implementations of metamaterials. We develop a CAM-based cloak as the case study.

Superabsorption in an organic microcavity: Toward a quantum battery.

The rate at which matter emits or absorbs light can be modified by its environment, as markedly exemplified by the widely studied phenomenon of superradiance. The reverse process, superabsorption, is harder to demonstrate because of the challenges of probing ultrafast processes and has only been seen for small numbers of atoms. Its central idea­superextensive scaling of absorption, meaning larger systems absorb faster­is also the key idea underpinning quantum batteries. Here, we implement experimentally a paradigmatic model of a quantum battery, constructed of a microcavity enclosing a molecular dye. Ultrafast optical spectroscopy allows us to observe charging dynamics at femtosecond resolution to demonstrate superextensive charging rates and storage capacity, in agreement with our theoretical modeling. We find that decoherence plays an important role in stabilizing energy storage. Our work opens future opportunities for harnessing collective effects in light-matter coupling for nanoscale energy capture, storage, and transport technologies.

Reconfigurable quantum metamaterials.

By coupling controllable quantum systems into larger structures we introduce the concept of a quantum metamaterial. Conventional meta-materials represent one of the most important frontiers in optical design, with applications in diverse fields ranging from medicine to aerospace. Up until now however, metamaterials have themselves been classical structures and interact only with the classical properties of light. Here we describe a class of dynamic metamaterials, based on the quantum properties of coupled atom-cavity arrays, which are intrinsically lossless, reconfigurable, and operate fundamentally at the quantum level. We show how this new class of metamaterial could be used to create a reconfigurable quantum superlens possessing a negative index gradient for single photon imaging. With the inherent features of quantum superposition and entanglement of metamaterial properties, this new class of dynamic quantum metamaterial, opens a new vista for quantum science and technology.

Quantum chaos and entanglement in ergodic and nonergodic systems.

We study entanglement entropy (EE) as a signature of quantum chaos in ergodic and nonergodic systems. In particular we look at the quantum kicked top and kicked rotor as multispin systems and investigate the single-spin EE which characterizes bipartite entanglement of this spin with the rest of the system. We study the correspondence of the Kolmogorov-Sinai entropy of the classical kicked systems with the EE of their quantum counterparts. We find that EE is a signature of global chaos in ergodic systems and local chaos in nonergodic systems. In particular, we show that EE can be maximized even when systems are highly nonergodic, when the corresponding classical system is locally chaotic. In contrast, we find evidence that the quantum analog of Kolmogorov-Arnol'd-Moser (KAM) tori are tori of low entanglement entropy. We conjecture that entanglement should play an important role in any quantum KAM theory.