Validation of a Lumped Parameter Model of the Battery Thermal Management System of a Hybrid Train by Means of Ultrasonic Clamp-On Flow Sensor Measurements and Hydronic Optimization.

Electrification of the field of transport is one of the key elements needed to reach the targets of greenhouse gas emissions reduction and carbon neutrality planned by the European Green Deal. In the railway sector, the hybrid powertrain solution (diesel-electric) is emerging, especially for non-electrified lines. Electric components, especially battery power systems, need an efficient thermal management system that guarantees the batteries will work within specific temperature ranges and a thermal uniformity between the modules. Therefore, a hydronic balancing needs to be realized between the parallel branches that supply the battery modules, which is often realized by introducing pressure losses in the system. In this paper, a thermal management system for battery modules (BTMS) of a hybrid train has been studied experimentally, to analyze the flow rates in each branch and the pressure losses. Since many branches of this system are built inside the battery box of the hybrid train, flow rate measurements have been conducted by means of an ultrasonic clamp-on flow sensor because of its minimal invasiveness and its ability to be quickly installed without modifying the system layout. Experimental data of flow rate and pressure drop have then been used to validate a lumped parameter model of the system, realized in the Simcenter AMESim® environment. This tool has then been used to find the hydronic balancing condition among all the battery modules; two solutions have been proposed, and a comparison in terms of overall power saved due to the reduction in pressure losses has been performed.

Polyalkylene Glycol Based Lubricants and Tribological Behaviour: Role of Ionic Liquids and Graphene Oxide as Additives.

The polyalkylene glycol (PAG) lubricants are widely used as gear, bearing and compressor oils in refrigerant systems. They are designed to provide outstanding benefits in terms of efficiency, long oil life, and equipment protection. These fully synthetic lubricants have been developed for use under operating conditions beyond the capabilities of other synthetic lubricants and mineral oils as their characteristic low pour point ensures excellent fluidity at low-temperature. On the other hand, the main drawback of PAG oils is the marked hygroscopicity, i.e., they absorb and bind moisture from the ambient air. In this paper, the results from tribological testing of PAG oil featuring 46 cSt at 40 °C with solid (graphene oxide) and liquid (ionic liquids) additives are discussed. Moreover, in this study the influence of absorbed moisture from ambient air has been investigated. Preliminary experiments with ball-on-flat setup by using reciprocatory tribometer tested the response of base oil PAG 46 blended with 1-Ethyl-3-methylimidazolium acetate or graphene oxide, alternatively. In such a way, the individual influence of each additive was questioned. Based on preliminary analysis, this research focuses on hybrid formulations to substantiate potential improvements of anti-friction and anti-wear PAG 46 performance over broad range of lubrication regimes. Experimental tests have been carried out by using rotational disc tribometer in ball-on-disc configuration. Additional experiments after samples exposure to ambient air and ensuing moisture absorption were carried out. The results highlight that in most cases limited absorbed moisture does not introduce detrimental effects on the tribological performances of the tested oil samples: indeed, water content could reduce wear of the sliding steel surfaces over the whole testing spectrum and in most of the cases the frictional energy dissipation.

Oil lubricant tribological behaviour improvement through dispersion of few layer graphene oxide.

Few layer graphene oxide (GO) nanosheets were prepared by a very fast modified Hummers method and widely characterized. Avoiding further chemical reactions, trying to take advantage of the easy exfoliation of GO favoring the formation of a tribofilm, and using a methodology well known to the lubricant industry, they were added to a mineral oil by the help of a dispersant. The tribological behaviour of GO in mineral oil was investigated under a wide spectrum of conditions, from boundary and mixed lubrication to elastohydrodynamic regimes. A ball on disc setup tribometer has been used to verify the friction reduction due to nanosheets dispersed in mineral oil. Their good friction and anti-wear properties may possibly be attributed to the small and extremely thin laminated structure, which offer lower shear stress and prevent interaction between metal interfaces. Furthermore, the results clearly prove that graphene platelets in oil easily form a protective film to prevent the direct contact between steel surfaces and, thereby, improving the frictional behaviour of the base oil. This evidence is also related to the frictional coefficient trend in boundary regime.

New 'chimie douce' approach to the synthesis of hybrid nanosheets of MoS2 on CNT and their anti-friction and anti-wear properties.

Hybrid organic-inorganic oleylamine@MoS2-CNT nanocomposites with different compositions were obtained by thermal decomposition of tetrathiomolybdate in the presence of oleylamine and high quality multiwalled carbon nanotubes (CNTs) previously prepared by the CCVD technique. The nanocomposite samples were characterized by the TEM, SEM TG-MS, Raman and XRD techniques and successfully tested as anti-friction and anti-wear additives for grease lubricants.

An Integrated Approach for the Environmental Characterization of a Wide Potentially Contaminated Area in Southern Italy.

This paper deals with the environmental characterization of a large and densely populated area, with a poor reputation for contamination, considering the contribution of environmental features (air, soil, soil hydraulic and groundwater) and the potential effects on human health. The use of Geographic Information System (GIS) has made possible a georeferenced inventory and, by overlaying environmental information, an operational synthesis of comprehensive environmental conditions. The cumulative effects on environmental features were evaluated, taking into account superposition effects, by means of the Spatial MultiCriteria Decision Analysis (S-MCDA). The application of the S-MCDA for converging the combination of heterogeneous factors, related to soil, land and water, deeply studied by heterogeneous groups of experts, constitutes the novelty of the paper. The results confirmed an overall higher potential of exposure to contaminants in the environment and higher mortality rates in the study area for some tumours, but hospital admissions for tumours were generally similar to the regional trend. Besides, mortality data may be strictly dependent on the poor socioeconomic conditions, quality of therapy and a lack of welfare in the area relative to the rest of Italy. Finally, as regards the possible relationship between presence of contaminants in the environment and health conditions of the population no definite conclusions can be drawn, although the present study encourages the use of the new proposed methods, that increase the possibilities for studying the combined effect of more environmental factors.

Brassica carinata as an alternative oil crop for the production of biodiesel in Italy: engine performance and regulated and unregulated exhaust emissions.

A comparison of the performance of Brassica carinata oil-derived biodiesel with a commercial rapeseed oil-derived biodiesel and petroleum diesel fuel is discussed as regards engine performance and regulated and unregulated exhaust emissions. B. carinata is an oil crop that can be cultivated in coastal areas of central-southern Italy, where it is more difficult to achieve the productivity potentials of Brassica napus (by far the most common rapeseed cultivated in continental Europe). Experimental tests were carried out on a turbocharged direct injection passenger car diesel engine fueled with 100% biodiesel. The unregulated exhaust emissions were characterized by determining the SOOT and soluble organic fraction content in the particulate matter, together with analysis of the content and speciation of polycyclic aromatic hydrocarbons, some of which are potentially carcinogenic, and of carbonyl compounds (aldehydes, ketones) that act as ozone precursors. B. carinata and commercial biodiesel behaved similarly as far as engine performance and regulated and unregulated emissions were concerned. When compared with petroleum diesel fuel, the engine test bench analysis did not show any appreciable variation of output engine torque values, while there was a significant difference in specific fuel consumption data at the lowest loads for the biofuels and petroleum diesel fuel. The biofuels were observed to produce higher levels of NOx concentrations and lower levels of PM with respect to the diesel fuel. The engine heat release analysis conducted shows that there is a potential for increased thermal NOx generation when firing biodiesel with no prior modification to the injection timing. It seems that, for both the biofuels, this behavior is caused by an advanced combustion evolution, which is particularly apparent at the higher loads. When compared with petroleum diesel fuel, biodiesel emissions contain less SOOT, and a greater fraction of the particulate was soluble. The analysis and speciation of the soluble organic fraction of biodiesel particulate suggest that the carcinogenic potential of the biodiesel emissions is probably lower than that of petroleum diesel. Its better adaptivity and productivity in clay and sandy-type soils and in semiarid temperate climate and the fact that the performance of its derived biodiesel is quite similar to commercial biodiesel make B. carinata a promising oil crop that could offer the possibility of exploiting the Mediterranean marginal areas for energetic purposes.