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Niobium pentoxide (Nb2O5)-based materials have attracted significant interest for application in diverse fields. Unfortunately, the employment of these materials as electrodes of lithium-ion batteries (LIBs) is limited by several inherent drawbacks. The present study demonstrated the synthesis of composites comprising homogeneous graphene-wrapped niobium pentoxide (GNbO) encapsulated in carbon nanofibers (CNFs) for utilization as binder- and additive-free anodes in LIBs. The composites were synthesized via electrospinning and subsequent carbonization; the presence of graphene (G) ensured the homogenous dispersion of the Nb2O5particles in the CNF matrix. The CNFs formed a highly conductive network that resulted in high physical flexibility, electrical conductivity, and structural stability during charge-discharge cycles, thereby facilitating rapid ion/electron transmission. Consequently, the CNF/GNbO composite anodes exhibited outstanding electrochemical performances. CNF/GNbO_5 (one of the synthesized composites with an Nb2O5concentration of 5 wt% relative to GO) delivered a specific capacity of 361 mAh g-1after 100 cycles, corresponding to a capacity retention of 58.3%. In addition, it exhibited an excellent rate capability with a capacity of 317 mAh g-1at 10 C. The outcomes of the present study will facilitate the extensive application of the synthesized composites as high-performance anodes in next-generation LIBs.
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It is important to fabricate nanostructured architectures comprised of functional components for a wide variety of applications because precise structural control in the nanometer regime can yield unprecedented, fascinating properties. Owing to their well-defined microstructural characteristics, it has been popular to use carbon nanospecies, such as nanotubes and graphene, in fabricating nanocomposites and nanohybrids. Nevertheless, it still remains hard to control and manipulate nanospecies for specific applications, thus preventing their commercialization. Herein, first, we report unique one-dimensional nanoarchitectures with meso-/macropores, consisting of single-walled nanotubes (SWNTs), graphene, and polyacrylonitrile, in which poly(vinyl alcohol) was employed as a dispersing agent and sacrificial porogen. One-dimensional SWNTs and two-dimensional graphene pieces were combined in the confined interior space of electrospun nanofibers, which led to unique microstructural characteristics such as enhanced ordering of SWNTs, graphene pieces, and polymer chains in the nanofiber interior. Next, the SWNT/graphene-in-polymer nanofiber (SGPNF) structures were converted into carbonized products (SGCNFs) with effective porosity and tunable electrochemical properties. Similar to SGPNFs, the microstructural and electrical properties of the SGCNFs depended on the incorporated amount of SWNT and graphene. At higher SWNT content, the mesopore volume proportion and specific discharge capacitance of the SGCNFs increased by max. 63 and 598%, respectively. The SGCNFs showed strong potential as a high-performance electrode material for electrochemical capacitors (max. capacitance: nonactivated â¼390 F g-1 and activated â¼750 F g-1). Flexible, all solid-state capacitor cells based on SGCNFs were also successfully demonstrated as a model application. The SGCNFs can be further functionalized by various methods, which will impart attractive properties for extended applications.
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Nanostructured poly(m-aminophenol) (PmAP) coated freestanding carbon nanofiber (CNF) mats were fabricated through simple in situ rapid-mixing polymerization of m-aminophenol in the presence of a CNF mat for flexible solid-state supercapacitors. The surface compositions, morphology and pore structure of the hybrid mats were characterized by using various techniques, e.g., FTIR, Raman, XRD, FE-SEM, TEM, and N2 absorption. The results show that the PmAP nanoparticles were homogeneously deposited on CNF surfaces and formed a thin flexible hybrid mat, which were directly used to made electrodes for electrochemical analysis without using any binders or conductive additives. The electrochemical performances of the hybrid mats were easily tailored by varying the PmAP loading on a hybrid electrode. The PmAP/CNF-10 hybrid electrode with a relatively low PmAP loading (> 42 wt%) showed a high specific capacitance of 325.8 F g-1 and a volumetric capacitance of 273.6 F cm-3 at a current density of 0.5 A g-1, together with a specific capacitance retention of 196.2 F g-1 at 20 A g-1. The PmAP/CNF-10 hybrid electrode showed good cycling stability with 88.2% capacitance retention after 5000 cycles. A maximum energy density of 45.2 Wh kg-1 and power density of 20.4 kW kg-1 were achieved for the PmAP/CNF-10 hybrid electrode. This facile and cost-effective synthesis of a flexible binder-free PmAP/CNF hybrid mat with excellent capacitive performances encourages its possible commercial exploitation.
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A new synthetic method is demonstrated for transforming rice husks into bulk amounts of graphene through its calcination and chemical activation. The bulk sample consists of crystalline nano-sized graphene and corrugated individual graphene sheets; the material generally contains one, two, or a few layers, and corrugated graphene domains are typically observed in monolayers containing topological defects within the hexagonal lattice and edges. Both types of graphenes exhibit atomically smooth surfaces and edges.
Assuntos
Grafite/química , Cristalização , Cristalografia por Raios X , Grafite/isolamento & purificação , Química Verde , Hidróxidos , Microscopia Eletrônica de Transmissão , Nanoestruturas/química , Nanoestruturas/ultraestrutura , Nanotecnologia , Oryza/química , Espectroscopia Fotoeletrônica , Compostos de Potássio , Análise Espectral Raman , TermogravimetriaRESUMO
The boric oxide deposition was performed to improve the oxidation resistivity of carbon nanofiber (CNF) from electrospinning at elevated temperatures. The stabilized electrospun polyacrylonitrile (PAN) nanofibers were coated with boric oxide, followed by heat treatment up to 1000, 1200, and 1400 degrees C in an inert nitrogen atmosphere. The relative oxidation resistance of boric oxide-coated CNFs showed oxidation resistive property, which was determined by weight loss after running a thermogravimetric analyzer (TGA) under air flow. The data were used for the calculations of activation energies through Arrhenius plot. The oxidation resistance of the boric oxide-coated CNFs was depended on the heat treatment temperature, the higher the temperature more resistive to oxidation. The boric oxide-coated CNFs showed extended oxidation resistivity as remaining 40-83% (w) of the original weight at the high temperature 1000 degrees C under air.
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The generation of silver nanoparticle/bis(o-phenolpropyl)silicone composites have been facilitated by the addition of sodium tetrachloroaurate or gold(Ill) chloride (< 1 wt% of NaAuCl4 or AuCl3) to the reaction of silver nitrate (AgNO3) with bis(o-phenolpropyl)silicone [BPPS, (o-phenolpropyl)2(SiMe2O)n, n = 2,3,8,236]. TEM and FE-SEM data showed that the silver nanoparticles having the size of < 20 nm are well dispersed throughout the BPPS silicone matrix in the composites. XRD patterns are consistent with those for polycrystalline silver. The size of silver nanoparticles augmented with increasing the relative molar concentration of AgNO3 added with respect to BPPS. The addition of gold complexes (1-3 wt%) did not affect the size distribution of silver nanoparticles appreciably. In the absence of BPPS, the macroscopic precipitation of silver by agglomeration, indicating that BPPS is necessary to stabilize the silver nanoparticles surrounded by coordination.
Assuntos
Cristalização/métodos , Ouro/química , Nanopartículas Metálicas/química , Nanopartículas Metálicas/ultraestrutura , Silicones/química , Prata/química , Catálise , Teste de Materiais , Conformação Molecular , Tamanho da Partícula , Propriedades de SuperfícieRESUMO
Combinative one-pot Si-Si/Si-O dehydrocoupling of hydrosilanes with alcohols (1:1.5 mole ratio), mediated by a mixture of AgNO3-AuCl3 (100/1 mole ratio) rapidly produced poly(alkoxysilane)s in reasonably high yield. The addition of small amount of gold complex to the reaction mixture effectively accelerated the coupling reaction compared to the reaction rate with AgNO3 alone. The hydrosilanes include p-X-C6H4SiH3 (X = H, CH3, OCH3, F), PhCH2SiH3, and (PhSiH2)2. The alcohols include MeOH, EtOH, iPrOH, PhOH, and CF3(CF2)2CH2OH. The weight average molecular weight and polydispersity of the poly(alkoxysilane)s were in the range of 1,600-8,000 Dalton and 1.4-3.5, respectively. The dehydrocoupling reactions of phenylsilane with ethanol (1:3 mole ratio) in the presence of the Ag-Au complexes gave only triethoxyphenylsilane.
Assuntos
Álcoois/química , Cristalização/métodos , Ouro/química , Nanoestruturas/química , Nanoestruturas/ultraestrutura , Silanos/química , Prata/química , Catálise , Substâncias Macromoleculares/química , Teste de Materiais , Conformação Molecular , Tamanho da Partícula , Propriedades de SuperfícieRESUMO
The one-pot synthesis and characterization of silver nanoparticle-poly(p-Br-phenylsilane) composites have been carried out. The conversion of silver(+1) salt to stable silver(0) nanoparticles is promoted by poly(p-Br-phenylsilane), Br-PPS possessing both possible reactive Si-H bonds in the polymer backbone and C-Br bonds in the substituents. The composites were characterized using XRD, TEM, FE-SEM, and solid-state UV-vis analytical techniques. TEM and FE-SEM data show the formation of the composites where large number of silver nanoparticles (less than 30 nm of size) are well dispersed throughout the Br-PPS matrix. XRD patterns are consistent with that for fcc-typed silver. The elemental analysis for Br atom and the polymer solubility confirm that the cleavage of C-Br bond and the Si-Br dative bonding were not occurred appreciably at ambient temperature. Nonetheless, TGA data suggest that some sort of cross-linking was occurred at high temperature. The size and processability of such nanoparticles depend on the ratio of metal to Br-PPS. In the absence of Br-PPS, most of the silver particles undergo macroscopic aggregation, which indicates that the polysilane is necessary for stabilizing the silver nanoparticles.
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Codehydrocoupling (in the presence of various inorganic B, Al-hydrides) followed by borane-capping (with Ph2BCl) of 1,1-dihydrotetraphenylsilole (1) and 1,1-dihydrotetraphenylgermole (2) (9:1 mole ratio) gave electroluminescent poly(silole-co-germole)s containing borane-ends (3) in high yield. The polymerization yield and molecular weight with Selectrides increase in the order L-Selectride < N-Selectride < K-Selectride. The molecular weights with B, Al-inorganic hydrides increase in the order L-Selectride < Red-Al
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A simple one-step method was used for preparing the beta-cyclodextrin/polyacrylonitrile (PAN) nanofibers deposited with silver nanoparticles by electrospinning and followed by the reduction of the Ag+ ions. The nano-composite fibers were stabilized at 280 degrees C in air and activated at 800 degrees C for 1 h in steam/N2. The structures of nano-composite fibers were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), fourier-transform infrared (FTIR) spectroscopy, and X-ray diffraction analysis (XRD). The electrochemical behaviors of the composite of carbon nano-fibers were investigated by cyclic voltammetry and charge/discharge tests.
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The electron beam (EB) irradiation effects of TiO2 deposited on carbon nanofibers (CNFs) were studied aiming the improvement of the photocatalytic activity. The EB irradiation contributed to an increase in crystallinity of the anatase resulting an improvement of the photocatalytic activity through the oxidation (ionization) of the doped TiO2 and leading to uniform distribution TiO2 particles on the CNFs surface. The photoactivity of the catalyst was measured by the decoloration of the methylene blue (MB) with time under UV irradiation.
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To improve the anti-oxidation properties of carbon fibers (CFs), the sol-gel method followed by pyrolysis was used to coat CFs with SiC/SiO2 ceramic coatings. The SiO2 sol-gel coating was performed by dip coating a PAN(polyacrylonitrile)-based stabilized fiber (PSF) in a silica sol prepared by the polycondensation of tetraethylorthosilicate (TEOS) in the presence of an acidic catalyst. The PSF coated with SiO2 sol then underwent heat treatments at high temperatures in an inert atmosphere to deposit the SiC/SiO2 and carbonize the deposited fibers. The surface morphology of the CFs deposited with SiC/SiO2 was characterized using a scanning electron microscope (SEM). The relative oxidation resistance of the SiC/SiO2 layer deposited on the CFs was determined by the weight loss due to the use of a thermogravimetric analyzer (TGA) under flowing air, and the data were used to calculate the activation energies through an Arrhenius plot.
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Silver nanoparticle/bis(o-phenolpropyl)silicone composites have been synthesized by the reduction of silver nitrate with bis(o-phenolpropyl)silicone BPPS [(o-phenolpropyl)2(SiMe2O)n, n = 2, 3, 8, 236]. TEM and FE-SEM data clearly show that the silver nanoparticles with the size of < 20 nm are well dispersed throughout the BPPS matrix in the composites. XRD patterns are consistent with those for multicrystalline silver. The size of silver nanoparticles increased with increasing the relative molar concentration of silver salts added. It was found that in the absence of BPPS, most of the silver nanoparticles undergo macroscopic precipitation by agglomeration, indicating that BPPS is essential to stabilize the silver nanoparticles.
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Si-Si/Si-O dehydrocoupling of hydrosilanes with alcohols (1:1.5 mole ratio), catalyzed by AgNO3 which converted to Ag(0) colloidal nanoparticles, gave poly(alkoxysilane)s in one-pot in moderate to high yield. The hydrosilanes include p-X-C6H4SiH3 (X = H, CH3, OCH3, F), PhCH2SiH3, and (PhSiH2)2. The alcohols include MeOH, EtOH, (i)PrOH, PhOH, and CF3(CF2)2CH2OH. The weight average molecular weight and polydispersity of the poly(alkoxysilane)s were in the range of 1,600 approximately 8,000 Dalton and 1.4 approximately 3.5. The dehydrocoupling reactions of phenylsilane with ethanol (1:3 mole ratio) in the presence of the silver nanocolloid catalyst produced only triethoxyphenylsilane as product.
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The formation of silver nanoparticle/bis(o-phenolpropyl)silicone composites have been promoted by the addition of chloroplatinic acid (<2 wt%) to the reaction of silver nitrate with bis(o-phenolpropyl)silicone BPPS [(o-phenolpropyl)2(SiMe2O)n, = 2, 3, 8, 236]. TEM and FE-SEM data exhibit that the silver nanoparticles having the size of <20 nm are well dispersed throughout the BPPS matrix in the composites. XRD patterns are consistent with those for polycrystalline silver. The addition of small amount of platinum to the silver accelerated the rate of composite formation by forming a Ag-Pt bimetallic alloy. The size of silver nanoparticles increased with increasing the relative molar concentration of silver salts added with respect to BPPS. However, the addition of platinum (1-5 wt%) to the AgNO3-BPPS mixture did not affect the size distribution of silver nanoparticles appreciably. It was found that in the absence of BPPS, most of the silver nanoparticles undergo macroscopic precipitation by agglomeration, indicating that BPPS is essential to stabilize the silver nanoparticles by coordination.
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Codehydrocoupling (with various inorganic hydrides) followed by stannane-capping (with Ph2SnHCI) of 1,1-dihydrotetraphenylsilole (1) and 1,1-dihydrotetraphenylgermole (2) (9:1 mol ratio) produces electroluminescent stannane-terminated poly(silole-co-germole)s (3) in high yield. The polymerization yield and molecular weight with Selectride increase in the order L-Selectride < N-Selectride < K-Selectride. The molecular weights increase in the order L-Selectride < Red-Al < N-Selectride < K-Selectride < Super-Hydride. The copolymer 3, a good candidate for PLED fabrication, emits at 523 nm and are electroluminescent at 521 nm. The fluorescence quantum yield of 3 in toluene is (1.61 +/- 0.29) x 10(-2). The emission color is green. The maximum brightness of the device is 3,750 cd/m2 with a luminous power efficiency of 0.67 Im/W.
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The roles of the Fc receptor (FcR) in protection or inflammatory disease after respiratory syncytial virus (RSV) vaccination and infection remain unknown. Virus-like particles containing RSV fusion proteins (RSV F-VLPs) induce T-helper type 1 antibody responses and protection against RSV. Heterologous RSV F-VLP prime and formalin-inactivated RSV (FI-RSV) boost vaccination has been reported to be effective in providing protection without inflammatory disease. Here, we investigated whether the FcRγ-chain is important for immune protection by the heterologous F-VLP and FI-RSV vaccination using FcRγ-chain knockout (-/-) mice. RSV F-VLP-primed and FI-RSV-boosted FcRγ -/- mice displayed less protective efficacy, as shown by higher lung viral titers upon RSV challenge, compared to RSV F-VLP-primed and FI-RSV-boosted immunized wild-type mice. RSV F-VLP and FI-RSV immunization induced lower levels of neutralizing activity and interferon-γ-producing CD8 T-cells in the bronchoalveolar lavage cells of FcRγ -/- mice than in those of wild-type mice. In addition, FcRγ -/- mice displayed a trend of enhancing lung histopathology after RSV vaccination and infection. This study suggests that the FcRγ-chain plays an important role in inducing antiviral protection and CD8 T-cell responses in RSV F-VLP prime and FI-RSV boost vaccination after RSV infections.
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TiO2/SiO2 catalysts were loaded on carbon nanofibers (CNF) support by sol-gel preparation and followed by a dip-coating and heat treatment up to 900 degrees C in inert atmosphere. The photocatalytic activities of the catalysts (TiO2/SiO2)/CNF were tested by the photocatalytic degradation rate of methylene blue (MB) under UV irradiation. It was found that (TiO2/SiO2)/CNF showed a higher photocatalytic activity than TiO2/CNF only. It was analyzed that SiO2 contributed to an increase the photo catalytic activity by suppressing the phase transformation of the TiO2 crystals from anatase to rutile on the heat treatment up to 900 degrees C.
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Polyacrylonitrile (PAN)-based nanocomposite fibers were prepared by co-precipitation of different amounts of Fe(II) and Fe(III) in an alkaline medium to get iron oxide impregnated nanofibers. Nanofibers web were prepared from blend solution of PAN containing different concentrations (1, 2 and 3 wt%) of ferrous (Fe2+)/ferric (Fe3+) solution in the 1:2 molar ratio in an effort to further improvement of the porosity and thereby, electrical properties. Electrospun fibers containing various concentrations of iron salts were then treated with KOH solution to produce nanosized magnetite particles in situ within the PAN nanofibers by precipitating Fe2+ ions or mixture of Fe2+ and Fe3+ ions. Such nanoscale particles homogeneously dispersed in PAN nanofibers to form the three-dimensional network structure. The homogeneously dispersed nanoparticles of iron oxide in and on the PAN carbon nanofibers produced the network structure of reasonably well-aligned configuration. Composite nanofibers morphologies and surface properties were discussed utilizing the combined techniques viz., field emission scanning electron microscope (FE-SEM), particle size analyzer, surface area and pore size distribution measurements.
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Si-Si/Si-O dehydrocoupling of hydrosilanes with alcohols (1:1.5 mole ratio), catalyzed by group VIII metallocenes Cp2M' (M' = Co, Ni) which converted to Co(O)/nickel(O) colloidal nanoparticles, produced poly(alkoxysilane)s in one-pot in high yield. The hydrosilanes include p-X-C6H4SiH3 (X = H, CH3, OCH3, F), PhCH2SiH3, and (PhSiH2)2. The alcohols include MeOH, EtOH, 'PrOH, PhOH, and CF3(CF2)2CH2OH. The weight average molecular weight of the poly(alkoxysilane)s were in the range of 600 to 8100. The dehydrocoupling reactions of phenylsilane with ethanol (1:3 mole ratio) in the presence of the nanocolloid catalyst gave only triethoxyphenylsilane as product.