Polymer network comprised of steroidal rotors as promising storage material.

In this paper, we report a new generation of polymeric networks as potential functional material based on changes in molecular dynamics in the solid state. The material is obtained by free radical polymerization of a diacrylate derivative bearing a steroid (stator) and a 1,4-diethynyl-phenylene-d4 fragment (rotator). Polymer research using the PALS technique complements the knowledge about nanostructural changes occurring in the system in the temperature range -115 °C - +190 °C. It indicates the presence of two types of free nanovolumes in the system and the occurrence of phase transitions. The polymer is characterized using 1 H NMR, 2 H Solid Echo NMR, ATR-FTIR and Raman spectroscopies, thermal analysis, and porosimetry. It is proved that the applied procedure leads to the formation of a novel porous organic material containing multiple molecular rotors.

Scavenging Radionuclide by Shapeable Porous Materials.

Nuclear energy is a competitive and environmentally friendly low-carbon energy source. It is seen as an important avenue for satisfying energy demands, responding to the energy crisis, and mitigating global climate change. However, much attention has been paid to achieving the effective treatment of radionuclide ions produced in nuclear waste. Initially, advanced adsorbents were mainly available in powder form, which meant that additional purification processes were usually required for separation and recovery in industrial applications. Therefore, to meet the practical requirements of industrial applications, materials need to be molded and processed into forms such as beads, membranes, gels, and resins. Here, we summarize the fabrication of porous materials used for capturing typical radionuclide ions, including UO2 2+, TcO4 -, IO3 -, SeO3 2-, and SeO4 2-.

Fluorescent Porous Materials Based on Aggregation-induced Emission for Biomedical Applications.

Fluorescent porous materials based on aggregation-induced emission (AIE) are growing into a sparkling frontier in biomedical applications. Exploring those materials represents a win-win integration and has recently progressed at a rapid pace, mainly benefiting from intrinsic advantages including tunable pore size and structure, strong guest molecule encapsulation ability, superior biocompatibility, and photophysical outcomes. With the great significance and rapid progress in this area, this review provides an integrated picture on AIE luminogen-based porous materials. It encompasses inorganic, organic, and inorganic-organic porous materials, exploring fundamental concepts and the relationship between AIE performance and material design and highlighting significant breakthroughs and the latest trends in biomedical applications. In addition, some critical challenges and future perspectives in the development of AIE luminogen-based porous materials are also discussed.