Thermal Activation of Coal Gangue with Low Al/Si Ratio as Supplementary Cementitious Materials.

To effectively utilize coal gangue (CG) with low Al/Si ratio, the thermal activation method was used. The activated CG, as supplementary cementitious materials (SCMs), was added into ordinary Portland cement (OPC) to study its physical properties. The XRD results show that CG undergoes a phase transition from kaolinite to metakaolinite during activation. The NMR tests reveal that the low polymerization state Q3 is continuously broadened, and the Al coordination gradually changes from Al VI to Al V and Al IV. The CG particles are scale-like and glassy with a loose structure. By mixing the activated CG (under 800 °C) with cement (mass ratio = 3:7), the water demand of normal consistency increases by 7.2% and the initial and final setting times extend by 67 min and 81 min, respectively. The rough surface and loose structure of activated CG are the main factors contributing to the higher water demand of normal consistency. The micro-aggregate effect of the activated CG reduces the contact rate between the cement particles and water, and the interparticles, thus slowing down the process of hydration reaction, and leading to longer setting times.

New Deposit of Mordenite-Clinoptilolite in the Eastern Region of Cuba: Uses as Pozzolans.

This work describes the newly discovered zeolites in the eastern region of Cuba. In the researched area, there have been no previous studies of natural zeolite exploration. Therefore, the results shown here are new. The main object of this research is to analyse five samples of zeolites and demonstrate their pozzolanic capacity and the possibility of their usage in the industrial manufacturing of pozzolanic cements. The study of the samples was performed by X-ray diffraction (XRD), X-ray fluorescence (XRF) and scanning electron microscopy (SEM). A chemical analysis (CAQ) to determine the quality of the samples as pozzolans was performed, by determining the total SiO2, reactive SiO2, total CaO, reactive CaO, Al2O3, MgO and the insoluble residue (I.R.). Lastly, an eight-day pozzolanicity analysis (PA) was carried out to determine the pozzolanic reactivity of the samples. The results obtained by XRD, XRF and SEM established that the researched zeolite samples have two main zeolitic phases: mordenite and clinoptilolite. Altered volcanic glass, quartz and smectite (montmorillonite) are the secondary phases. The results of the chemical quality analysis (CAQ) showed that the samples contain a considerable amount of reactive SiO2 and reactive CaO, as well as a low content of insoluble residue, which reinforces their properties as pozzolans. The results of the pozzolanicity analysis (PA) concluded that the analysed samples actively react with Ca(OH)2 after eight days. Based on all the results mentioned above, it is established that both mordenite and clinoptilolite behave like pozzolans and can be recommended for the manufacture of pozzolanic cements, which have more effective properties than Portland cement, in terms of physical, chemical and mechanical strength, low heat of hydration, resistance to sulphates, low CO2 emissions to the atmosphere and negligible impacts on the environment.

Roles of Waste Glass and the Effect of Process Parameters on the Properties of Sustainable Cement and Geopolymer Concrete-A State-of-the-Art Review.

Recent research has revealed the promising potential of using waste glass (WG) as a binder or inert filler in cement and geopolymer concrete to deliver economic and environmental benefits to the construction sector. However, the outcomes obtained by different research groups are scattered and difficult to compare directly because of isolated process parameters. In this study, the roles and impacts of WG and process parameters on the performance of WG-added cement and geopolymer concrete are critically reviewed. This study reveals that the chemical and mineralogical composition, and particle size of WG, mix proportion, activation, and curing condition of concrete are the most important parameters that affect the dissolution behavior of WG and chemical reactivity between WG and other elements in concrete; consequently, these show impacts on properties of concrete and optimum WG level for various applications. These parameters are required to be optimized based on the guidelines for high pozzolanicity and less alkali-silica reactivity of WG in concrete. This review provides a critical discussion and guidelines on these parameters and the chemistry of WG in cement and geopolymer concrete for best practice and highlights the current challenges with future research directions.

A Mass Balance Approach for Thermogravimetric Analysis in Pozzolanic Reactivity R3 Test and Effect of Drying Methods.

The reactivity of supplementary cementitious materials (SCMs) is a key issue in the sustainability of cement-based materials. In this study, the effect of drying with isopropanol and acetone as well as the interpretation of thermogravimetric data on the results of an R3 test for evaluation of the SCM pozzolanic reaction were investigated. R3 samples consisting of calcium hydroxide, potassium hydroxide, potassium sulphate, water, and SCM were prepared. Besides silica fume, three different types of calcined clays were investigated as SCMs. These were a relatively pure metakaolin, a quartz-rich metakaolin, and a mixed calcined clay, where the amount of other types of clays was two times higher than the kaolinite content. Thermogravimetric analysis (TGA) was carried out on seven-day-old samples dried with isopropanol and acetone to stop the reaction processes. Additional calorimetric measurement of the R3 samples was carried out for evaluation of the reaction kinetics. Results show that drying with isopropanol is more suitable for analysis of R3 samples compared to acetone. The use of acetone results in increased carbonation and TGA mass losses until 40 (isothermal drying for 30 min) and 105 °C (ramp heating), indicating that parts of the acetone remain in the sample, causing problems in the interpretation of TGA data. A mass balance approach was proposed to calculate calcium hydroxide consumption from TGA data, while also considering the amount of carbonates in the sample and TGA data corrections of original SCMs. With this approach, an improvement of the linear correlation of TGA results and heat release from calorimetric measurement was achieved.

Recycling of waste glass as aggregate in cement-based materials.

Glass is a common material made from natural resources such as sand. Although much of the waste glass is recycled to make new glass products, a large proportion is still being sent to landfill. Glass is a useful resource that is non-biodegradable, occupying valuable landfill space. To combat the waste glass that is heading to landfill, alternative recycling forms need to be investigated. The construction industry is one of the largest CO2 emitters in the world, producing up to 8% of the global CO2 to produce cement. The use of sand largely depletes natural resources for the creation of mortars or concretes. This review explores the possibilities of incorporating waste glass into cement-based materials. It was found waste glass is unsuitable as a raw material replacement to produce clinker and as a coarse aggregate, due to a liquid state being produced in the kiln and the smooth surface area, respectively. Promising results were found when incorporating fine particles of glass in cement-based materials due to the favourable pozzolanic reaction which benefits the mechanical properties. It was found that 20% of cement can be replaced with waste glass of 20 µm without detrimental effects on the mechanical properties. Replacements higher than 30% can cause negative impacts as insufficient amounts of CaCO3 remain to react with the silica from the glass, known as the dilution effect. As the fine aggregate replacement for waste glass increases over 20%, the mechanical properties decrease proportionally; however, up to 20% has similar results to traditionally mixes.

Effect of Fineness of Basaltic Volcanic Ash on Pozzolanic Reactivity, ASR Expansion and Drying Shrinkage of Blended Cement Mortars.

This study focuses on evaluating the effect of the fineness of basaltic volcanic ash (VA) on the engineering properties of cement pozzolan mixtures. In this study, VA of two different fineness, i.e., VA fine (VF) and VA ultra-fine (VUF) and commercially available fly ash (FA) was used to partially replace cement. Including a control and a hybrid mix (10% each of VUF and FA), eleven mortar mixes were prepared with various percentages of VA and FA (10%, 20% and 30%) to partially replace cement. First, material characterization was performed by using X-ray florescence (XRF), X-ray powder diffraction (XRD), particle size analysis, and a modified Chappelle test. Then, the compressive strength development, alkali silica reactivity (ASR), and drying shrinkage of all mortar mixes were investigated. Finally, XRD analysis on paste samples of all mixes was performed to assess their pozzolanic reactivity at ages of 7 and 91 days. The results showed increased Chappelle reactivity values with an increase in the fineness of the VA. Mortars containing high percentages of VUF (20% and 30%) showed almost equal compressive strength compared to corresponding FA mortars at all ages, however, the hybrid mix (10% VUF + 10% FA) exhibited higher strength than that of the reference mix (100% cement), particularly, at 91 days. At low percentages (10%), ASR expansion in both VF and VUF mortars was higher compared to the corresponding FA mortar and the opposite behavior was observed at high percentages (20% and 30%). Among all the mixes including the control, mortar with VUF was found to be most effective in controlling drying shrinkages at all ages. The rate of consumption of calcium hydroxide (Ca(OH)2) for pastes containing VUF and FA was almost the same, while VF showed low Ca(OH)2 intensity. These results indicate that an increase in the fineness of VA significantly improvs performance, and therefore, it could be a feasible substitute for commercial admixtures in cement composites.

Pozzolanic Reactivity of Silica Fume and Ground Rice Husk Ash as Reactive Silica in a Cementitious System: A Comparative Study.

This study comparably assessed the pozzolanic effect of silica fume (SF) and ground rice husk ash (RHA) as supplementary cementing materials on the properties of blended cement pastes and concretes. A commonly commercial silica fume (SF) and locally-produced rice husk ash (RHA) samples with two finenesses (one with larger size than cement and the other with smaller size than cement) were used in this study. Material properties of SF and RHA were experimentally characterized. Hydration and mechanical properties of cement pastes incorporating SF and RHA were determined by thermogravimetric analysis (TGA) and compressive strength tests, respectively. Properties of concretes regarding workability, mechanical property, durability, and microstructure were evaluated. Results showed that, although the finely ground RHA used in this study possessed lower SiO2 content and higher particle size compared to SF, it exhibited comparable pozzolanic reactivity with SF due to the nano-scale pores on its each single particle, leading to a higher specific surface area. The optimal replacement levels of SF and RHA were 10% by weight of cement in pastes and concretes. Although addition of SF and RHA led to a significant reduction in slump for the fresh mixtures, inclusion of up to 30% of SF or 15% of ground RHA did not adversely affect the strength of concretes. At the same mix, incorporation of finely-ground RHA in cement composites provided comparable mechanical properties, hydration degree, and durability with SF blended cement composites, owing to the porous structure and high specific surface area of RHA particles. Microstructure morphology analysis of concretes explored by scanning electron microscopy (SEM) further validated the strength and the durability test results.