Dehydrative glycosylation with the Hendrickson reagent.
J Org Chem
; 76(21): 9122-6, 2011 Nov 04.
Article
em En
| MEDLINE
| ID: mdl-21970416
ABSTRACT
The Hendrickson reagent is able to perform efficiently dehydrative glycosylation of 1-hydroxyglycosyl donors. The reaction occurs under mild conditions through an anomeric oxophosphonium intermediate detected by nuclear magnetic resonance. Further insight into the mechanism was gained by (18)O labeling of anomeric OH.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Glicosídeos
/
Indicadores e Reagentes
Idioma:
En
Revista:
J Org Chem
Ano de publicação:
2011
Tipo de documento:
Article
País de afiliação:
Itália