Role of carbon quantum dots on Nickel titanate to promote water oxidation reaction under visible light illumination.

Water oxidation reaction (WOR) is the heart for overall water splitting owing to its sluggish kinetics. Herein, carbon quantum dots (CQDs) are studied as co-catalyst to promote WOR by loading them on NiTiO3 (NTO) photocatalyst. The performance can be obtained in a fold of 7 compared with pristine NTO in power-based photocatalytic system, and strong stability has received with preserving the output for at least 10 h. The CQDs have also demonstrated to load on NTO based photoanode for WOR, and a 6 times increasement has realized. In-situ characterizations have acquired to study the roles of CQDs for WOR and found that CQDs can facilitate the chemical adsorption of water molecules, and meanwhile promote the formation of hydroxyl radical as transition states of WOR. This demonstration presents a clue to understand the role of carbon in photocatalytic system to promote WOR and encourage its uses for advanced photoredox catalytic reactions.