Comprehensive study on the hydrochar for adsorption of Cd(II): preparation, characterization, and mechanisms.

ABSTRACT

Hydrothermal carbonization process via converting invasive plants into functional materials may provide a novel strategy to comprehensively control and utilized the exotic invasive plants. In this study, Eupatorium adenophorum was utilized to fabricate the hydrochar via hydrothermal carbonization process, which was further applied to remove Cd(II). The results showed that the hydrochar was a mesoporous material with abundant O-containing functional groups (OFPs) on the surface. The adsorption isotherms were fitted by both the Langmuir and Freundlich models, and the maximum adsorption amount achieved 24.53 mg/g. The adsorption dynamics were governed by surface adsorption and film diffusion. pH and ionic strength can exert a strong influence on the adsorption efficiency. The mechanisms on the adsorption of Cd(II) on the hydrochar concluded the pore-filling effects, electrostatic interactions, ion exchange, precipitation, coordination with π electrons, and surface complexation with the OFPs, such as hydroxyl, carboxylic, phenol, acetyl, and ester groups. Thus, hydrothermal carbonization process may provide a promising technique to fabricate the hydrocar for the treatment of Cd(II), which may facilitate comprehensive control of invasive plants and boost to the carbon neutrality.