Constructing Highly Efficient Circularly Polarized Multiple-Resonance Thermally Activated Delayed Fluorescence Materials with Intrinsically Helical Chirality.
Adv Mater
; 35(42): e2305125, 2023 Oct.
Article
em En
| MEDLINE
| ID: mdl-37461260
ABSTRACT
Advanced circularly polarized multiple-resonance thermally activated delayed fluorescence (CP-MR-TADF) materials synergize the advantages of circularly polarized luminescence (CPL), narrowband emission, and the TADF characteristic, which can be fabricated into highly efficient circularly polarized organic light-emitting diodes (CP-OLEDs) with high color purity, directly facing the urgent market strategic demand of ultrahigh-definition and 3D displays. In this work, based on an edge-topology molecular-engineering (ETME) strategy, a pair of high-performance CP-MR-TADF enantiomers, (P and M)-BN-Py, is developed, which merges the intrinsically helical chirality into the MR framework. The optimized CP-OLEDs with (P and M)-BN-Py emitters and the newly developed ambipolar transport host PhCbBCz exhibit pure green emission with sharp peaks of 532 nm, full-width at half-maximum (FWHM) of 37 nm, and Commission Internationale de L'Eclairage (CIE) coordinates of (0.29, 0.68). Importantly, they achieve remarkable maximum external quantum efficiencies (EQEs) of 30.6% and 29.2%, and clear circularly polarized electroluminescence (CPEL) signals with electroluminescence dissymmetry factors (gEL s) of -4.37 × 10-4 and +4.35 × 10-4 for (P)-BN-Py and (M)-BN-Py, respectively.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Adv Mater
Assunto da revista:
BIOFISICA
/
QUIMICA
Ano de publicação:
2023
Tipo de documento:
Article