Chromium(VI) Oxyfluoride Dianions, [Cr2 O4 F6 ]2- and [CrO2 F4 ]2- ; Syntheses and Structures of [XeF5 ]2 [Cr2 O4 F6 ], [XeF5 ]2 [Cr2 O4 F6 ] â nX (X=HF, n=4; X=XeOF4 , n=2), and [XeF5 ][Xe2 F11 ][CrO2 F4 ].

Bortolus, Mark R; Mercier, Hélène P A; Schrobilgen, Gary J

Chromium(VI) Oxyfluoride Dianions, [Cr₂ O₄ F₆ ]^2- and [CrO₂ F₄ ]^2- ; Syntheses and Structures of [XeF₅ ]₂ [Cr₂ O₄ F₆ ], [XeF₅ ]₂ [Cr₂ O₄ F₆ ] â nX (X=HF, n=4; X=XeOF₄ , n=2), and [XeF₅ ][Xe₂ F₁₁ ][CrO₂ F₄ ].

Bortolus, Mark R; Mercier, Hélène P A; Schrobilgen, Gary J.

Afiliação

Bortolus MR; Department of Chemistry, McMaster University, Hamilton, ON L8S 4M1, Canada.
Mercier HPA; Department of Chemistry, McMaster University, Hamilton, ON L8S 4M1, Canada.
Schrobilgen GJ; Department of Chemistry, McMaster University, Hamilton, ON L8S 4M1, Canada.

Chemistry ; 30(10): e202303059, 2024 Feb 16.

Article em En | MEDLINE | ID: mdl-37847124

Palavras-chave

Raman spectroscopy; X-ray crystallography; chromium(VI) oxyfluoro-dianions; hyper-valent compounds; quantum-chemical calculations; xenon(VI) chemistry; σ-hole bonds

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2024 Tipo de documento: Article País de afiliação: Canadá

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