Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives.
J Org Chem
; 89(9): 6074-6084, 2024 May 03.
Article
em En
| MEDLINE
| ID: mdl-38626391
ABSTRACT
A PPh3Au[B(C6F5)4]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o-Quinodimethane (o-QDM) intermediate's extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Org Chem
Ano de publicação:
2024
Tipo de documento:
Article