Elevating Discharge Voltage of Li2CO3-Routine Li-CO2 Battery over 2.9â
V at an Ultra-Wide Temperature Window.
Angew Chem Int Ed Engl
; 63(34): e202407303, 2024 Aug 19.
Article
em En
| MEDLINE
| ID: mdl-38837854
ABSTRACT
The Li-CO2 batteries utilizing greenhouse gas CO2 possess advantages of high energy density and environmental friendliness. However, these batteries following Li2CO3-product route typically exhibit low work voltage (<2.5â
V) and energy efficiency. Herein, we have demonstrated for the first time that cobalt phthalocyanine (CoPc) as homogeneous catalyst can elevate the work plateau towards 2.98â
V, which is higher than its theoretical discharge voltage without changing the Li2CO3-product route. This unprecedented discharge voltage is illustrated by mass spectrum and electrochemical analyses that CoPc has powerful adsorption capability with CO2 (-7.484â
kJ mol-1) and forms discharge intermediate of C33H16CoN8O2. Besides high discharge capacity of 18724â
mAh g-1 and robust cyclability over 1600â
hours (1000â
mAh g-1 cut-off) at a current density of 100â
mA g-1, the batteries show high temperature adaptability (-30-80 °C). Our work is paving a promising avenue for the progress of high-efficiency Li-CO2 batteries.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
China