Efficient Synthesis of µ-A(BC)C Miktoarm Star Polymer Assemblies via Aqueous Photoinitiated Polymerization-Induced Self-Assembly.
Langmuir
; 40(32): 17098-17108, 2024 Aug 13.
Article
em En
| MEDLINE
| ID: mdl-39088262
ABSTRACT
In this study, green light-activated photoiniferter reversible addition-fragmentation chain transfer (RAFT) polymerization of glycerol methacrylate was performed using an ω,ω-heterodifunctional macro-RAFT agent. Because of the different RAFT controllability of two RAFT groups toward methacrylic monomers, only one RAFT group was activated under green light irradiation, leading to the formation of a diblock copolymer macro-RAFT agent with one RAFT group located at the chain end and the other RAFT group located between two blocks. The obtained diblock copolymer macro-RAFT agent was then used to mediate aqueous photoinitiated RAFT dispersion polymerization of diacetone acrylamide (DAAM), which formed µ-A(BC)C miktoarm star polymer assemblies with a diverse set of morphologies. Comparing with the ABC triblock copolymer, it was found that the architecture of the µ-A(BC)C miktoarm star polymer facilitated the formation of higher-order morphologies. Kinetic studies indicated that the aqueous photoinitiated RAFT dispersion polymerization exhibited ultrafast polymerization behavior, with quantitative monomer conversion being achieved within 5 min. Size exclusion chromatography analysis confirmed that good RAFT control was maintained during the polymerization. A morphological phase diagram for µ-A(BC)C miktoarm star polymer assemblies was constructed by varying the monomer concentration and the [DAAM]/[Macro-RAFT] ratio. We expect that this study not only develops an approach for the preparation of miktoarm star polymer assemblies but also provides mechanistic insights into the polymerization-induced self-assembly of nonlinear polymers.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Langmuir
Assunto da revista:
QUIMICA
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
China