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1.
Am J Ind Med ; 65(9): 701-707, 2022 09.
Artigo em Inglês | MEDLINE | ID: mdl-35899403

RESUMO

BACKGROUND: Workers fabricating engineered stone face high risk for exposure to respirable crystalline silica (RCS) and subsequent development of silicosis. In response, the California Division of Occupational Safety and Health (Cal/OSHA) performed targeted enforcement inspections at engineered stone fabrication worksites. We investigated RCS exposures and employer adherence to Cal/OSHA's RCS and respiratory protection standards from these inspections to assess ongoing risk to stone fabrication workers. METHODS: We extracted employee personal air sampling results from Cal/OSHA inspection files and calculated RCS exposures. Standards require that employers continue monitoring employee RCS exposures and perform medical surveillance when exposures are at or above the action level (AL; 25 µg/m3 ); exposures above the permissible exposure limit (PEL; 50 µg/m3 ) are prohibited. We obtained RCS and respiratory protection standard violation citations from a federal database. RESULTS: We analyzed RCS exposures for 152 employees at 47 workplaces. Thirty-eight (25%) employees had exposures above the PEL (median = 89.7 µg/m3 ; range = 50.7-670.7 µg/m3 ); 17 (11%) had exposures between the AL and PEL. Twenty-four (51%) workplaces had ≥1 exposure above the PEL; 7 (15%) had ≥1 exposure between the AL and PEL. Thirty-four (72%) workplaces were cited for ≥1 RCS standard violation. Twenty-seven (57%) workplaces were cited for ≥1 respiratory protection standard violation. CONCLUSIONS: Our investigation demonstrates widespread RCS overexposure among workers and numerous employer Cal/OSHA standard violation citations. More enforcement and educational efforts could improve employer compliance with Cal/OSHA standards and inform employers and employees of the risks for RCS exposure and strategies for reducing exposure.


Assuntos
Exposição Ocupacional , Silicose , California/epidemiologia , Poeira/análise , Humanos , Exposição por Inalação/efeitos adversos , Exposição por Inalação/análise , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/efeitos adversos , Exposição Ocupacional/análise , Exposição Ocupacional/prevenção & controle , Dióxido de Silício/análise , Silicose/epidemiologia , Silicose/prevenção & controle , Local de Trabalho
2.
J Occup Environ Hyg ; 19(12): 730-741, 2022 12.
Artigo em Inglês | MEDLINE | ID: mdl-36219680

RESUMO

With the advent of new sensing technologies and robust field-deployable analyzers, monitoring approaches can now generate valuable hazard information directly in the workplace. This is the case for monitoring respirable dust and respirable crystalline silica concentration levels. Estimating the quartz amount of a respirable dust sample by nondestructive analysis can be carried out using portable Fourier transform infrared spectroscopy (FTIR) units. Real-time respirable dust monitors, combined with small video cameras, allow advanced assessments using the Helmet-CAM methodology. These two field-based monitoring approaches, developed by the National Institute for Occupational Safety and Health (NIOSH), have been trialed in a sandstone quarry. Twenty-six Helmet-CAM sessions were conducted, and forty-one dust samples were collected around the quarry and analyzed on-site during two events. The generated data generated were used to characterize concentration levels for the monitored areas and workers, to identify good practices, and to illustrate activities that could be improved with additional engineered control technologies. Laboratory analysis of the collected samples complemented the field finding and provided an assessment of the performance of the field-based techniques. Only a fraction of the real-time respirable dust monitoring sessions data could be corrected with laboratory analysis. The average correction factor ratio was 5.0. Nevertheless, Helmet-CAM results provided valuable information for each session. The field-based quartz monitoring approach overestimated the concentration by a factor of 1.8, but it successfully assessed the quartz concentration trends in the quarry. The data collected could be used for the determination of a quarry calibration factor for future events. The quartz content in the dust was found to vary from 14% to 100%, and this indicates the need for multiple techniques in the characterization of respirable dust and quartz concentration and exposure. Overall, this study reports the importance of the adoption of field-based monitoring techniques when combined with a proper understanding and knowledge of the capabilities and limitations of each technique.


Assuntos
Poluentes Ocupacionais do Ar , Exposição Ocupacional , Humanos , Dióxido de Silício/análise , Poeira/análise , Quartzo/análise , Exposição Ocupacional/prevenção & controle , Exposição Ocupacional/análise , Exposição por Inalação/prevenção & controle , Exposição por Inalação/análise , Monitoramento Ambiental/métodos , Poluentes Ocupacionais do Ar/análise
3.
Am J Ind Med ; 64(5): 381-397, 2021 05.
Artigo em Inglês | MEDLINE | ID: mdl-33522624

RESUMO

BACKGROUND: Informal sector electronic waste (e-waste) recovery produces toxic emissions resulting from burning e-waste to recover valuable metals. OBJECTIVES: To identify high-risk worker groups by measuring relative levels of personal inhalation exposure to particulate matter (PM) of fine (≤2.5 µm) and coarse (2.5-10 µm) fractions (PM2.5 and PM2.5-10, respectively) across work activities among e-waste workers, and to assess how wind conditions modify levels of PM by activity and site location. METHODS: At the Agbogbloshie e-waste site, 170 partial-shift PM samples and time-activity data were collected from participants (N = 105) enrolled in the GeoHealth cohort study. Personal sampling included continuous measures of size-specific PM from the worker's breathing zone and time-activity derived from wearable cameras. Linear mixed models were used to estimate changes in personal PM2.5 and PM2.5-10 associated with activities and evaluate effect modification by wind conditions. RESULTS: Mean (±standard deviation) personal PM2.5 and PM2.5-10 concentrations were 80 (± 81) and 123 (± 139) µg m-3 , respectively. The adjusted mean PM2.5 concentration for burning e-waste was 88 µg m-3 , a 28% increase above concentrations during non-recovery activities (such as eating). Transportation-related and burning activities were associated with the highest PM2.5-10 concentrations. Frequent changes in wind direction were associated with higher PM2.5 concentrations when burning, and high wind speeds with higher PM2.5-10 concentrations when dismantling e-waste downwind of the burning zone.


Assuntos
Poluição do Ar/análise , Resíduo Eletrônico , Exposição por Inalação/análise , Exposição Ocupacional/análise , Gerenciamento de Resíduos , Poluentes Atmosféricos/análise , Monitoramento Ambiental , Gana , Humanos , Exposição por Inalação/prevenção & controle , Metais , Exposição Ocupacional/prevenção & controle , Material Particulado/análise , Meios de Transporte
4.
J Occup Environ Hyg ; 18(6): 237-249, 2021 06.
Artigo em Inglês | MEDLINE | ID: mdl-33989130

RESUMO

The study assessed potential to exceed occupational exposure limits while spraying paint with and without a silver nanoparticle biocidal additive. A tradesperson performed the tasks in a sealed chamber with filtered air supply. Integrated air sampling entailed transmission electron microscopy with energy dispersive X-ray analysis, direct-reading of particle number concentrations, and determination of silver mass concentration by NIOSH Method 7300. Silver nanoparticles were primarily embedded in paint spray droplets but also observed as isolated particles. Using an α-level of 0.05, median nanoparticle number concentrations did not differ significantly when spraying conventional vs. biocidal paint, although statistically significant differences were observed at specific particle size ranges <100 nm. The geometric mean concentration of total silver while spraying biocidal paint (n = 6) was 2.1 µg/m3 (95% CI: 1.5-2.8 µg/m3), and no respirable silver was detected (<0.50 µg/m3). The results address a lack of silver nanoparticle exposure data in construction and demonstrate the feasibility of a practical sampling approach. Given similar conditions, the measurements suggest a low probability of exceeding a proposed silver nanoparticle exposure limit of 0.9 µg/m3 as an airborne 8-hr time-weighted average respirable mass concentration. A full workday of exposure to respirable silver at the highest possible level in this study (<0.50 µg/m3) would not exceed the exposure limit, although limitations in comparing short task-based exposures to an 8-hr exposure limit must be noted. There was airflow in the study chamber, whereas exposure levels could increase over time in work environments lacking adequate ventilation. Potential to exceed the exposure limit hinged upon the respirable fraction of the paint mist, which could vary by material and application method. Additional research would improve understanding of silver nanoparticle exposure risks among construction trades, and biological responses to these exposures. Given the potential for exposure variability on construction jobsites, safety and health professionals should be cognizant of methods to assess and control silver nanoparticle exposures.


Assuntos
Poluentes Ocupacionais do Ar , Nanopartículas Metálicas , Exposição Ocupacional , Poluentes Ocupacionais do Ar/análise , Poluentes Ocupacionais do Ar/toxicidade , Monitoramento Ambiental , Exposição por Inalação/análise , Nanopartículas Metálicas/toxicidade , Exposição Ocupacional/análise , Exposição Ocupacional/prevenção & controle , Pintura/toxicidade , Prata/toxicidade
5.
Occup Environ Med ; 77(4): 268-275, 2020 04.
Artigo em Inglês | MEDLINE | ID: mdl-32034033

RESUMO

OBJECTIVES: Since 2000 the European Industrial Minerals Association's Dust Monitoring Programme (IMA-DMP) has systematically collected respirable dust and respirable quartz measurements from 35 companies producing industrial minerals. The IMA-DMP initiative allowed for estimating overall temporal trends in exposure concentrations for the years 2002-2016 and for presenting these trends by type of mineral produced, by jobs performed and by time of enrolment into the DMP. METHODS: Approximately 32 000 personal exposure measurements were collected during 29 sampling campaigns during a 15-year period (2002-2016). Temporal trends in respirable dust and respirable quartz concentrations were studied by using linear mixed effects models. RESULTS: Concentrations varied widely (up to three to four orders of magnitude). However, overall decreases in exposure levels were shown for the European minerals industry over the 15-year period. Statistically significant overall downward temporal trends of -9.0% and -3.9% per year were observed for respirable dust and respirable quartz, respectively. When analyses were stratified by time period, no downward trends (and even slight increasing concentrations) were observed between 2008 and 2012, most likely attributable to the recent global economic crisis. After this time period, downward trends became visible again. CONCLUSIONS: Consistent and statistically significant downward trends were found for both exposure to respirable dust and respirable quartz. These downward trends became less or even reversed during the years of the global economic crisis. To our knowledge, this is the first time that analyses of long-term temporal trends point at an effect of a global economic crisis on personal exposure concentrations of workers from sites across Europe.


Assuntos
Poluentes Ocupacionais do Ar/análise , Poeira/análise , Monitoramento Ambiental/métodos , Exposição por Inalação/análise , Exposição Ocupacional/análise , Quartzo/análise , Poluentes Ocupacionais do Ar/normas , Bases de Dados Factuais , Europa (Continente) , Humanos , Indústrias , Minerais , Exposição Ocupacional/normas , Exposição Ocupacional/estatística & dados numéricos
6.
J Occup Environ Hyg ; 16(5): 336-340, 2019 05.
Artigo em Inglês | MEDLINE | ID: mdl-31013200

RESUMO

Drilling large holes (e.g., 10-20 mm diameter) into concrete for structural upgrades to buildings, highways, bridges, and airport runways can produce concentrations of respirable silica dust well above the ACGIH® Threshold Limit Value (TLV® = 0.025 mg/m3). The aim of this study was to evaluate a new method of local exhaust ventilation, hollow bit dust extraction, and compare it to a standard shroud local exhaust ventilation and to no local exhaust ventilation. A test bench system was used to drill 19 mm diameter x 100 mm depth holes every minute for one hour under three test conditions: no local exhaust ventilation, shroud local exhaust ventilation, and hollow bit local exhaust ventilation. There were two trials for each condition. Respirable dust sampling equipment was placed on a "sampling" mannequin fixed behind the drill and analysis followed ISO and NIOSH methods. Without local exhaust ventilation, mean respirable dust concentration was 3.32 (± 0.65) mg/m3 with a quartz concentration of 16.8% by weight and respirable quartz dust concentration was 0.55 (± 0.05) mg/m3; 22 times the ACGIH TLV. For both LEV conditions, respirable dust concentrations were below the limits of detection. Applying the 16.8% quartz value, respirable quartz concentrations for both local exhaust ventilation conditions were below 0.007 mg/m3. There was no difference in respirable quartz dust concentrations between the hollow bit and the shroud local exhaust ventilation systems; both were below the limits of detection and well below the ACGIH TLV. Contractors should consider using either local exhaust ventilation method for controlling respirable silica dust while drilling into concrete.


Assuntos
Poluentes Ocupacionais do Ar/análise , Quartzo/análise , Ventilação/métodos , Indústria da Construção/instrumentação , Poeira/análise , Exposição por Inalação/análise , Exposição Ocupacional/prevenção & controle
7.
J Occup Environ Hyg ; 16(10): 685-693, 2019 10.
Artigo em Inglês | MEDLINE | ID: mdl-31389760

RESUMO

The floor polish removal (FPR) and reapplication (FPA) are important cleaning tasks in public buildings that have hard floor surfaces. Usually, the FPR and FPA are conducted once or twice a year, during the periodic cleaning of these buildings. The FPR can be performed either chemically (CFPR) or by using dry scrubber (DFPR), when the polish is ground from the floor. In this study, cleaning workers' exposure to volatile organic compounds (VOCs) and particulate matter (PM) during the FPR and FPA, and the differences in the exposures between the two FPR methods were investigated. In total, three buildings located in Central Finland were included, and total of six cleaning workers (two per building) participated in the study. In Buildings 1 and 2, the CFPR and FPA were performed and in Building 3, the DFPR was conducted. TVOC (total volatile organic compounds) concentrations in the breathing zone of the workers during the CFPR were 8,740 and 390 µg/m3 (SD 3,290 and 180 µg/m3) for Buildings 1 and 2, respectively. During the DFPR in Building 3, the average TVOC concentration was 400 µg/m3 (SD 180 µg/m3, stationary sampling). The TVOC concentrations during the FPA were high, 1,640 and 2,170 µg/m3 on average (SD 1,570 and 930 µg/m3) for Buildings 1 and 2, respectively. Glycol ethers were the most prominent VOCs during the CFPR and FPA, whereas carboxylic acids were the most common during the DFPR. The inhalable dust concentrations in the workers' breathing zone were noticeably higher during the DFPR (1.55 mg/m3 on average, SD 0.01 mg/m3) than the CFPR (0.24 mg/m3 on average, SD 0.05 mg/m3). Finnish occupational exposure limit value for organic inhalable dust is 5 mg/m3. As the products used during the CFPR and FPA contain glycol ethers and ethanolamines that are absorbed via the skin as well, the use of skin protection is recommended. Whereas the use of FFP3 respirators and skin protection are recommended during the DFPR to prevent the PM exposure.


Assuntos
Poluentes Ocupacionais do Ar/análise , Poeira/análise , Zeladoria/métodos , Exposição por Inalação/análise , Exposição Ocupacional/análise , Compostos Orgânicos Voláteis/análise , Ácidos Carboxílicos/análise , Éteres/análise , Pisos e Cobertura de Pisos , Glicóis/análise , Humanos , Óleos Industriais , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle
8.
J Occup Environ Hyg ; 15(3): 194-203, 2018 03.
Artigo em Inglês | MEDLINE | ID: mdl-29157164

RESUMO

In bakeries, high concentrations of flour dust can exist and ovens release particles into the air as well. Particle concentrations (mass, number) and number size distribution may vary considerably but the variation is not commonly studied. Furthermore, the role of the smallest size fractions is rarely considered in the exposure assessment due to their small mass. The objectives of this work were to find out how concentrations and number size distribution of fine and nanoparticles vary in a traditional Finnish bakery and to determine the exposure of a dough maker to the nanoparticle fraction of the inhalable dust. Two measurement campaigns were carried out in a traditional, small-scale bakery. Sampling was performed at the breathing zone of the dough maker and three stationary locations: baking area, oven area, and flour depository. Both real-time measurements and conventional gravimetric sampling were conducted. Nanoparticle fraction of the inhalable dust was determined using an IOM sampler with a customized precyclone. Number concentration of fine and nanoparticles, and mass concentrations of both the inhalable dust and nanoparticles were high. The nanoparticle fraction was 9-15% of the inhalable dust at the breathing zone of the dough maker. Different sources, such as ovens and doughnut baking affected the number size distribution. Flour dust contained nanoparticles but most of the fine and nanoparticles were released into the air from the oven operations. However, nanoparticles are not a primary concern in bakeries compared to health effects linked to the large flour particles such as flour-induced sensitization or asthma and development of occupational rhinitis.


Assuntos
Poluentes Ocupacionais do Ar/análise , Poeira/análise , Indústria de Processamento de Alimentos , Exposição Ocupacional/análise , Finlândia/epidemiologia , Farinha/análise , Humanos , Exposição por Inalação/análise , Nanopartículas/análise , Tamanho da Partícula
9.
J Occup Environ Hyg ; 15(6): 455-465, 2018 06.
Artigo em Inglês | MEDLINE | ID: mdl-29580185

RESUMO

Erionite is a naturally occurring fibrous mineral found in many parts of the world, including the western United States. Inhalational exposure to erionite fibers in some localities is associated with health effects similar to those caused by asbestos exposure, including malignant mesothelioma. Therefore, there is concern regarding occupational exposures in the western United States. Currently, there are no standard sampling and analytical methods for airborne erionite fibers, as well as no established occupational exposure limits. Due to the potential adverse health effects, characterizing and minimizing exposures is prudent. Crystalline silica also occurs naturally in areas where erionite is found, principally as the mineral quartz. Work activities involving rocks containing quartz and soils derived from those rocks can lead to exposure to respirable crystalline silica (RCS). The typically dry and dusty environment of the western United States can increase the likelihood of exposures to aerosolized rocks and soils, but inhalation exposure is also possible in more humid conditions. In this case study, we describe several outdoor occupational environments with potential exposures to erionite and RCS. We describe our method for evaluating those exposures and demonstrate: (1) the occurrence of occupational exposures to airborne erionite and RCS, (2) that the chemical make-up of the erionite mineral can be determined, and (3) that effective dust control practices are needed to reduce employee exposures to these minerals.


Assuntos
Exposição Ocupacional/análise , Dióxido de Silício/análise , Zeolitas/análise , Indústria da Construção , Agricultura Florestal , Humanos , Exposição por Inalação/análise , Montana , National Institute for Occupational Safety and Health, U.S. , Exposição Ocupacional/prevenção & controle , Material Particulado/análise , South Dakota , Estados Unidos , Wyoming
10.
Inhal Toxicol ; 29(12-14): 555-566, 2017.
Artigo em Inglês | MEDLINE | ID: mdl-29336178

RESUMO

Although industrial uses of asbestos have declined since the 1970s, in recent years there has been a renewed interest in para-occupational ("take-home") exposure to these fibers. The aim of this study was to quantify the release of asbestos fibers, if any, during the shaking out of crocidolite- and chrysotile-contaminated clothing in a simulated at-home setting. An exposure study was conducted in which personal and area air samples were collected during the handling (i.e. shake-out) of work clothing (shirt and pants) previously worn by an operator who had cut asbestos-containing cement pipe. During eight "loading" events, the operator cut a historically representative asbestos-containing cement pipe (10% crocidolite and 25% chrysotile) using a powered abrasive saw. Subsequently, 30-minute air samples were collected during four "shake-out" events, each of which consisted of the handling of two complete sets of contaminated work clothes. Samples were analyzed in accordance with NIOSH methods 7400 and 7402. The mean phase contrast microscopy equivalent (PCME) airborne concentrations were 0.52 f/cc (SD = 0.34 f/cc) for total asbestos fibers, 0.36 f/cc (SD = 0.26 f/cc) for chrysotile and 0.17 f/cc (SD = 0.096 f/cc) for crocidolite. Based on likely estimates of the frequency of laundering activities, and assuming that the dusty clothing (1) is not blown off in the occupational setting using compressed air and (2) is not shaken out before entering the home, a family member handling the clothing could potentially have a lifetime cumulative exposure to chrysotile and crocidolite of approximately 0.20 f/cc-year and 0.096 f/cc-year, respectively.


Assuntos
Poluentes Ocupacionais do Ar/análise , Amianto/análise , Vestuário , Materiais de Construção/análise , Exposição por Inalação/análise , Exposição Ocupacional/análise , Poluentes Ocupacionais do Ar/efeitos adversos , Amianto/efeitos adversos , Vestuário/efeitos adversos , Materiais de Construção/efeitos adversos , Humanos , Exposição por Inalação/efeitos adversos , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/efeitos adversos , Exposição Ocupacional/prevenção & controle
11.
J Occup Environ Hyg ; 14(1): 40-48, 2017 01.
Artigo em Inglês | MEDLINE | ID: mdl-27869548

RESUMO

Workers are exposed to dust in broiler chicken production during daily work activities. Poultry dust may contain inflammatory agents (e.g., endotoxin) and inhalation exposure has been associated with pulmonary symptoms. Current practice to reduce worker exposure to poultry dust is the use of respiratory protection (e.g., elastomeric face-piece respirator with a P100 and ammonia chemical cartridge). Limited research has been conducted to evaluate engineering controls to reduce dust and ammonia concentrations in broiler chicken production; therefore, the purpose of this research was to evaluate the effectiveness of a water sprinkling system to reduce inhalable dust and ammonia concentrations in a broiler chicken house. Inhalable dust and ammonia concentrations were measured daily for the production cycle of a flock of broiler chickens (63 days). Inhalable dust was measured gravimetrically using an inhalable sampler and ammonia was measured by a direct reading sensor. Sampling was performed on a stationary mannequin inside two broiler chicken houses. One house used a sprinkler cooling system to deliver a water mist throughout the house and the second house was an untreated control. The sprinkler system activated after day 5 of chicken placement, releasing water periodically from 6 am to 10 pm. The amount of sprinkling increased at day 10 and day 15 as recommended by the manufacturer. Geometric mean (GM) inhalable dust concentrations measured in the treatment house (5.5 mg/m3) were not different (p = 0.33) than those found in the control house (6.0 mg/m3). The GM ammonia concentrations were also not different (p = 0.34) across the treatment and control house [10.6 ppm (GSD: 1.80); GM 9.51 ppm (GSD: 1.77)], respectively. The use of cost effective engineering, administrative and personal exposure controls are needed in the poultry industry to effectively reduce worker's exposure to hazardous concentrations of dust and ammonia.


Assuntos
Poluentes Ocupacionais do Ar/análise , Poeira/análise , Exposição por Inalação/análise , Exposição Ocupacional/análise , Animais , Ambiente Controlado , Monitoramento Ambiental , Humanos , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Aves Domésticas
12.
J Occup Environ Hyg ; 14(6): 438-447, 2017 06.
Artigo em Inglês | MEDLINE | ID: mdl-28278063

RESUMO

This article presents air and surface sampling data collected over the first two years since beryllium was introduced as a target material at the National Ignition Facility. Over this time, 101 experiments with beryllium-containing targets were executed. The data provides an assessment of current conditions in the facility and a baseline for future impacts as new, reduced regulatory limits for beryllium are being proposed by both the Occupational Safety and Health Administration and Department of Energy. This study also investigates how beryllium deposits onto exposed surfaces as a result of x-ray vaporization and the effectiveness of simple decontamination measures in reducing the amount of removable beryllium from a surface. Based on 1,961 surface wipe samples collected from entrant components (equipment directly exposed to target debris) and their surrounding work areas during routine reconfiguration activities, only one result was above the beryllium release limit of 0.2 µg/100 cm2 and 27 results were above the analytical reporting limit of 0.01 µg/100 cm2, for a beryllium detection rate of 1.4%. Surface wipe samples collected from the internal walls of the NIF target chamber, however, showed higher levels of beryllium, with beryllium detected on 73% and 87% of the samples during the first and second target chamber entries (performed annually), respectively, with 23% of the samples above the beryllium release limit during the second target chamber entry. The analysis of a target chamber wall panel exposed during the first 30 beryllium-containing experiments (cumulatively) indicated that 87% of the beryllium contamination remains fixed onto the surface after wet wiping the surface and 92% of the non-fixed contamination was removed by decontaminating the surface using a dry wipe followed by a wet wipe. Personal airborne exposures assessed during access to entrant components and during target chamber entry indicated that airborne beryllium was not present in workers' breathing zones. All the data thus far have shown that beryllium has been effectively managed to prevent exposures to workers during routine and non-routine work.


Assuntos
Poluentes Ocupacionais do Ar/análise , Poluentes Radioativos do Ar/análise , Berílio/análise , Contaminação de Equipamentos , Exposição Ocupacional/análise , Poluentes Ocupacionais do Ar/toxicidade , Poluentes Radioativos do Ar/toxicidade , Berílio/toxicidade , California , Descontaminação/métodos , Monitoramento Ambiental/métodos , Humanos , Exposição por Inalação/efeitos adversos , Exposição por Inalação/análise , Exposição Ocupacional/efeitos adversos , Exposição Ocupacional/prevenção & controle , Volatilização , Raios X
13.
J Occup Environ Hyg ; 14(12): 955-964, 2017 12.
Artigo em Inglês | MEDLINE | ID: mdl-28837406

RESUMO

Biomedical researchers use of inhalational anesthetics has increased in recent years. Use of isoflurane as an inhalational anesthetic may result in human exposure to waste anesthetic gas. Potential health effects from exposure include genotoxic and hepatotoxic effects with some evidence of teratogenic and reproductive effects. Research suggests that exposure to waste anesthetic gas within human hospital settings has improved substantially but exposures to biomedical researchers and veterinarians still requires improvement. A number of biomedical research facilities are located at The University of Queensland, Australia, where researchers and animal handlers are potentially exposed to waste isoflurane gas. There is limited published data on the exposures received by biomedical researchers performing routine procedures. This project aimed to assess isoflurane exposure received during routine rodent anesthetic protocols performed at the university. Atmospheric concentrations of isoflurane were assessed via two methods-personal active gas sampling using sorbent tubes and direct readings using infrared spectroscopy. Total procedure and isoflurane exposure times ranged from 135-268 min. Personal sorbent tube sampling detected isoflurane levels from below detectable limits (<0.01 ppm) to a Time Weighted Average for the task (TWA-Task) of 6.20 ppm (0.73 ± 9.13). Participants were not exposed to isoflurane outside of the sampling period during the remainder of the workday. TWA-8 hr adjusted levels ranged from below the limit of detection to 1.76 ppm isoflurane (0.69 ppm ± 0.61 ppm). The infrared spectroscopy readings taken in the breathing zone of participants ranged from 0.1-68 ppm. Results indicate that if adequately controlled through good room ventilation, effective active gas scavenging and well constructed anesthetic equipment, waste anesthetic exposures are minimal. However, where industry standards are not met exposures may occur, including some high peak exposures.


Assuntos
Poluentes Ocupacionais do Ar/análise , Anestesia por Inalação/veterinária , Anestésicos Inalatórios/análise , Exposição por Inalação/análise , Isoflurano/análise , Exposição Ocupacional/análise , Poluição do Ar em Ambientes Fechados/análise , Poluição do Ar em Ambientes Fechados/prevenção & controle , Animais , Monitoramento Ambiental , Feminino , Humanos , Queensland , Roedores , Universidades , Ventilação/métodos
14.
Ann Occup Hyg ; 60(3): 387-401, 2016 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-26602453

RESUMO

The welding of shear stud connectors to structural steel in construction requires a prolonged stooped posture that exposes ironworkers to biomechanical and welding fume hazards. In this study, biomechanical and welding fume exposures during stud welding using conventional methods were compared to exposures associated with use of a prototype system that allowed participants to weld from an upright position. The effect of base material (i.e. bare structural beam versus galvanized decking) on welding fume concentration (particle number and mass), particle size distribution, and particle composition was also explored. Thirty participants completed a series of stud welding simulations in a local apprenticeship training facility. Use of the upright system was associated with substantial reductions in trunk inclination and the activity levels of several muscle groups. Inhalable mass concentrations of welding fume (averaged over ~18 min) when using conventional methods were high (18.2 mg m(-3) for bare beam; 65.7 mg m(-3) for through deck), with estimated mass concentrations of iron (7.8 mg m(-3) for bare beam; 15.8 mg m(-3) for through deck), zinc (0.2 mg m(-3) for bare beam; 15.8 mg m(-3) for through deck), and manganese (0.9 mg m(-3) for bare beam; 1.5 mg m(-3) for through deck) often exceeding the American Conference of Governmental Industrial Hygienists Threshold Limit Values (TLVs). Number and mass concentrations were substantially reduced when using the upright system, although the total inhalable mass concentration remained above the TLV when welding through decking. The average diameters of the welding fume particles for both bare beam (31±17 nm) through deck conditions (34±34 nm) and the chemical composition of the particles indicated the presence of metallic nanoparticles. Stud welding exposes ironworkers to potentially high levels of biomechanical loading (primarily to the low back) and welding fume. The upright system used in this study improved exposure levels during stud welding simulations, but further development is needed before field deployment is possible.


Assuntos
Poluentes Ocupacionais do Ar , Ergonomia , Exposição por Inalação/análise , Exposição Ocupacional/prevenção & controle , Soldagem/métodos , Adulto , Fenômenos Biomecânicos , Gases/análise , Humanos , Pessoa de Meia-Idade , Tamanho da Partícula
15.
Ann Occup Hyg ; 60(2): 263-9, 2016 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-26403363

RESUMO

Personal 8-h shift exposure to respirable dust, diesel engine exhaust emissions (DEEE) (as respirable elemental carbon), and respirable crystalline silica of workers involved in constructing an underground metro railway tunnel was assessed. Black carbon (BC) concentrations were also assessed using a MicroAeth AE51. During sprayed concrete lining (SCL) activities in the tunnel, the geometric mean (GM) respirable dust exposure level was 0.91mg m(-3), with the highest exposure measured on a back-up sprayer (3.20mg m(-3)). The GM respirable crystalline silica concentration for SCL workers was 0.03mg m(-3), with the highest measurement also for the back-up sprayer (0.24mg m(-3)). During tunnel boring machine (TBM) activities, the GM respirable dust concentration was 0.54mg m(-3). The GM respirable elemental carbon concentration for all the TBM operators was 18 µg m(-3); with the highest concentration measured on a segment lifter. The BC concentrations were higher in the SCL environment in comparison to the TBM environment (daily GM 18-54 µg m(-3) versus 3-6 µg m(-3)). This small-scale monitoring campaign provides additional personal data on exposures experienced by underground tunnel construction workers.


Assuntos
Poeira/análise , Exposição por Inalação/análise , Mineração , Exposição Ocupacional/análise , Emissões de Veículos/análise , Poluentes Ocupacionais do Ar/análise , Carbono/análise , Carbono/normas , Monitoramento Ambiental/métodos , Humanos , Londres , Dióxido de Silício/análise
16.
Ann Occup Hyg ; 60(4): 519-24, 2016 May.
Artigo em Inglês | MEDLINE | ID: mdl-26826033

RESUMO

PURPOSE: To assess the effectiveness of local exhaust ventilation to control respirable crystalline silica exposures to acceptable levels during concrete dowel drilling. APPROACH: Personal breathing zone samples for respirable dust and crystalline silica were collected while laborers drilled holes 3.5 cm diameter by 36 cm deep in a concrete slab using a single-drill slab-riding dowel drill equipped with local exhaust ventilation. Data were collected on air flow, weather, and productivity. RESULTS: All respirable dust samples were below the 90 µg detection limit which, when combined with the largest sample volume, resulted in a minimum detectable concentration of 0.31 mg m(-3). This occurred in a 32-min sample collected when 27 holes were drilled. Quartz was only detected in one air sample; 0.09 mg m(-3) of quartz was found on an 8-min sample collected during a drill maintenance task. The minimum detectable concentration for quartz in personal air samples collected while drilling was performed was 0.02 mg m(-3). The average number of holes drilled during each drilling sample was 23. Over the course of the 2-day study, air flow measured at the dust collector decreased from 2.2 to 1.7 m(3) s(-1). CONCLUSIONS: The dust control performed well under the conditions of this test. The initial duct velocity with a clean filter was sufficient to prevent settling, but gradually fell below the recommended value to prevent dust from settling in the duct. The practice of raising the drill between each hole may have prevented the dust from settling in the duct. A slightly higher flow rate and an improved duct design would prevent settling without regard to the position of the drill.


Assuntos
Poluentes Ocupacionais do Ar/análise , Indústria da Construção , Poeira/análise , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Dióxido de Silício/análise , Ventilação/normas , Materiais de Construção/análise , Poeira/prevenção & controle , Monitoramento Ambiental/métodos , Humanos , Exposição por Inalação/análise , Exposição Ocupacional/análise , Quartzo/análise , Ventilação/métodos
17.
J Occup Environ Hyg ; 13(11): 817-28, 2016 11.
Artigo em Inglês | MEDLINE | ID: mdl-27135749

RESUMO

The classification of Respirable Crystalline Silica (RCS) as carcinogenic for humans has drawn greater attention to crystalline silica exposure in the workplace in recent years, leading to recommendations by safety and health bodies in Europe and the U.S. for lower occupational exposure limits. In view of this new scenario, the present study examined quartz dustiness, as quartz handling is a major source of crystalline silica in the workplace. The study was conducted on test samples with different mean particle sizes, prepared from several commercial quartzes. The quartz particle samples were characterised and the influence of certain quartz particle parameters on quartz dustiness was determined. The results indicate that quartz dustiness may be significantly affected by mean particle size, specific surface area, the Hausner ratio, and fine particle content. The study shows that, in order to minimise the adverse health effects associated with the inhalation of crystalline silica, quartz dustiness may be deemed a key factor in controlling the generation of fugitive quartz emissions during quartz processing, both into the outside atmosphere (air pollution) and inside the facilities (occupational health).


Assuntos
Exposição por Inalação/análise , Exposição Ocupacional/análise , Quartzo/análise , Dióxido de Silício/análise , Poeira/análise , Humanos , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Tamanho da Partícula , Local de Trabalho
18.
J Occup Environ Hyg ; 13(9): 718-24, 2016 09.
Artigo em Inglês | MEDLINE | ID: mdl-27074062

RESUMO

Rotary-type percussion dowel drilling machines, which drill horizontal holes in concrete pavement, have been documented to produce respirable crystalline silica concentrations above recommended exposure criteria. This places operators at potential risk for developing health effects from exposure. United States manufacturers of these machines offer optional dust control systems. The effectiveness of the dust control systems to reduce respirable dust concentrations on two types of drilling machines was evaluated under controlled conditions with the machines operating inside large tent structures in an effort to eliminate secondary exposure sources not related to the dowel-drilling operation. Area air samples were collected at breathing zone height at three locations around each machine. Through equal numbers of sampling rounds with the control systems randomly selected to be on or off, the control systems were found to significantly reduce respirable dust concentrations from a geometric mean of 54 mg per cubic meter to 3.0 mg per cubic meter on one machine and 57 mg per cubic meter to 5.3 mg per cubic meter on the other machine. This research shows that the dust control systems can dramatically reduce respirable dust concentrations by over 90% under controlled conditions. However, these systems need to be evaluated under actual work conditions to determine their effectiveness in reducing worker exposures to crystalline silica below hazardous levels.


Assuntos
Indústria da Construção , Poeira/prevenção & controle , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Material Particulado/análise , Poluentes Ocupacionais do Ar/análise , Materiais de Construção , Monitoramento Ambiental , Exposição por Inalação/análise , Exposição Ocupacional/análise
19.
J Occup Environ Hyg ; 13(7): 538-48, 2016 07.
Artigo em Inglês | MEDLINE | ID: mdl-26913983

RESUMO

Asphalt pavement milling machines use a rotating cutter drum to remove the deteriorated road surface for recycling. The removal of the road surface has the potential to release respirable crystalline silica, to which workers can be exposed. This article describes an evaluation of respirable crystalline silica exposures to the operator and ground worker from two different half-lane and larger asphalt pavement milling machines that had ventilation dust controls and water-sprays designed and installed by the manufacturers. Manufacturer A completed milling for 11 days at 4 highway construction sites in Wisconsin, and Manufacturer B completed milling for 10 days at 7 highway construction sites in Indiana. To evaluate the dust controls, full-shift personal breathing zone air samples were collected from an operator and ground worker during the course of normal employee work activities of asphalt pavement milling at 11 different sites. Forty-two personal breathing zone air samples were collected over 21 days (sampling on an operator and ground worker each day). All samples were below 50 µg/m(3) for respirable crystalline silica, the National Institute for Occupational Safety and Health recommended exposure limit. The geometric mean personal breathing zone air sample was 6.2 µg/m(3) for the operator and 6.1 µg/m(3) for the ground worker for the Manufacturer A milling machine. The geometric mean personal breathing zone air sample was 4.2 µg/m(3) for the operator and 9.0 µg/m(3) for the ground worker for the Manufacturer B milling machine. In addition, upper 95% confidence limits for the mean exposure for each occupation were well below 50 µg/m(3) for both studies. The silica content in the bulk asphalt material being milled ranged from 7-23% silica for roads milled by Manufacturer A and from 5-12% silica for roads milled by Manufacturer B. The results indicate that engineering controls consisting of ventilation controls in combination with water-sprays are capable of controlling occupational exposures to respirable crystalline silica generated by asphalt pavement milling machines on highway construction sites.


Assuntos
Poluentes Ocupacionais do Ar/análise , Indústria da Construção , Exposição por Inalação/análise , Exposição Ocupacional/análise , Dióxido de Silício/análise , Poeira/análise , Monitoramento Ambiental , Humanos , Hidrocarbonetos , Indiana , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Wisconsin
20.
J Occup Environ Hyg ; 13(3): 177-84, 2016.
Artigo em Inglês | MEDLINE | ID: mdl-26554925

RESUMO

According to the National Fire Protection Association there were 487,500 structural fires in the U.S. in 2013. After visible flames are extinguished firefighters begin the overhaul stage where remaining hot spots are identified and further extinguished. During overhaul, a significant amount of potentially hazardous chemicals can remain in the ambient environment. Previous research suggests that the use of air purifying respirators fitted with chemical, biological, radiological, and nuclear (CBRN) canisters may reduce occupational exposure. This study used large scale burns of representative structural materials to perform side-by-side, filtering, and service-life evaluations of commercially available CBRN filters using two head forms fitted with full-face respirators and a dynamic breathing machine. Three types of CBRN canisters and one non-CBRN cartridge were challenged in repetitive post-fire environments. Tests were conducted with two different breathing volumes and rates for two sampling durations (0-15 min and 0-60 min). Fifty-five different chemicals were selected for evaluation and results indicate that 10 of the 55 chemicals were present in the post-fire overhaul ambient environment. Acetaldehyde and formaldehyde were found to be the only two chemicals detected post filter but were effectively filtered to below ACGIH TLVs. Counter to our prior published work using continuous flow filter evaluation, this study indicates that, regardless of brand, CBRN filters were effective at reducing concentrations of post-fire ambient chemicals to below occupational exposure limits. However, caution should be applied when using CBRN filters as the ambient formaldehyde level in the current study was 8.9 times lower than during the previous work.


Assuntos
Bombeiros , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Dispositivos de Proteção Respiratória , Acetaldeído/análise , Poluentes Ocupacionais do Ar/análise , Incêndios , Formaldeído/análise , Substâncias Perigosas/análise , Humanos , Exposição por Inalação/análise , Manequins , Exposição Ocupacional/análise
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