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1.
Molecules ; 26(4)2021 Feb 15.
Artigo em Inglês | MEDLINE | ID: mdl-33672068

RESUMO

The evaluation and interpretation of the behavior of construction materials under fire conditions have been complicated. Over the last few years, artificial intelligence (AI) has emerged as a reliable method to tackle this engineering problem. This review summarizes existing studies that applied AI to predict the fire performance of different construction materials (e.g., concrete, steel, timber, and composites). The prediction of the flame retardancy of some structural components such as beams, columns, slabs, and connections by utilizing AI-based models is also discussed. The end of this review offers insights on the advantages, existing challenges, and recommendations for the development of AI techniques used to evaluate the fire performance of construction materials and their flame retardancy. This review offers a comprehensive overview to researchers in the fields of fire engineering and material science, and it encourages them to explore and consider the use of AI in future research projects.


Assuntos
Inteligência Artificial , Materiais de Construção/análise , Incêndios/prevenção & controle , Retardadores de Chama/análise , Aprendizado de Máquina , Redes Neurais de Computação
2.
Malar J ; 16(1): 213, 2017 05 22.
Artigo em Inglês | MEDLINE | ID: mdl-28532494

RESUMO

While long-lasting insecticidal nets (LLINs) and indoor residual spraying (IRS) are the cornerstones of malaria vector control throughout sub-Saharan Africa, there is an urgent need for the development of novel insecticide delivery mechanisms to sustain and consolidate gains in disease reduction and to transition towards malaria elimination and eradication. Insecticide-treated durable wall lining (ITWL) may represent a new paradigm for malaria control as a potential complementary or alternate longer-lasting intervention to IRS. ITWL can be attached to inner house walls, remain efficacious over multiple years and overcome some of the operational constraints of first-line control strategies, specifically nightly behavioural compliance required of LLINs and re-current costs and user fatigue associated with IRS campaigns. Initial experimental hut trials of insecticide-treated plastic sheeting reported promising results, achieving high levels of vector mortality, deterrence and blood-feeding inhibition, particularly when combined with LLINs. Two generations of commercial ITWL have been manufactured to date containing either pyrethroid or non-pyrethroid formulations. While some Phase III trials of these products have demonstrated reductions in malaria incidence, further large-scale evidence is still required before operational implementation of ITWL can be considered either in a programmatic or more targeted community context. Qualitative studies of ITWL have identified aesthetic value and observable entomological efficacy as key determinants of household acceptability. However, concerns have been raised regarding installation feasibility and anticipated cost-effectiveness. This paper critically reviews ITWL as both a putative mechanism of house improvement or more conventional intervention and discusses its future prospects as a method for controlling malaria and other vector-borne diseases.


Assuntos
Controle de Doenças Transmissíveis , Materiais de Construção/análise , Inseticidas , Malária/prevenção & controle , Controle de Mosquitos , Doença de Chagas/prevenção & controle , Controle de Doenças Transmissíveis/instrumentação , Controle de Doenças Transmissíveis/métodos , Habitação , Controle de Mosquitos/instrumentação , Controle de Mosquitos/métodos
3.
Inhal Toxicol ; 29(12-14): 555-566, 2017.
Artigo em Inglês | MEDLINE | ID: mdl-29336178

RESUMO

Although industrial uses of asbestos have declined since the 1970s, in recent years there has been a renewed interest in para-occupational ("take-home") exposure to these fibers. The aim of this study was to quantify the release of asbestos fibers, if any, during the shaking out of crocidolite- and chrysotile-contaminated clothing in a simulated at-home setting. An exposure study was conducted in which personal and area air samples were collected during the handling (i.e. shake-out) of work clothing (shirt and pants) previously worn by an operator who had cut asbestos-containing cement pipe. During eight "loading" events, the operator cut a historically representative asbestos-containing cement pipe (10% crocidolite and 25% chrysotile) using a powered abrasive saw. Subsequently, 30-minute air samples were collected during four "shake-out" events, each of which consisted of the handling of two complete sets of contaminated work clothes. Samples were analyzed in accordance with NIOSH methods 7400 and 7402. The mean phase contrast microscopy equivalent (PCME) airborne concentrations were 0.52 f/cc (SD = 0.34 f/cc) for total asbestos fibers, 0.36 f/cc (SD = 0.26 f/cc) for chrysotile and 0.17 f/cc (SD = 0.096 f/cc) for crocidolite. Based on likely estimates of the frequency of laundering activities, and assuming that the dusty clothing (1) is not blown off in the occupational setting using compressed air and (2) is not shaken out before entering the home, a family member handling the clothing could potentially have a lifetime cumulative exposure to chrysotile and crocidolite of approximately 0.20 f/cc-year and 0.096 f/cc-year, respectively.


Assuntos
Poluentes Ocupacionais do Ar/análise , Amianto/análise , Vestuário , Materiais de Construção/análise , Exposição por Inalação/análise , Exposição Ocupacional/análise , Poluentes Ocupacionais do Ar/efeitos adversos , Amianto/efeitos adversos , Vestuário/efeitos adversos , Materiais de Construção/efeitos adversos , Humanos , Exposição por Inalação/efeitos adversos , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/efeitos adversos , Exposição Ocupacional/prevenção & controle
4.
Ann Occup Hyg ; 60(4): 519-24, 2016 May.
Artigo em Inglês | MEDLINE | ID: mdl-26826033

RESUMO

PURPOSE: To assess the effectiveness of local exhaust ventilation to control respirable crystalline silica exposures to acceptable levels during concrete dowel drilling. APPROACH: Personal breathing zone samples for respirable dust and crystalline silica were collected while laborers drilled holes 3.5 cm diameter by 36 cm deep in a concrete slab using a single-drill slab-riding dowel drill equipped with local exhaust ventilation. Data were collected on air flow, weather, and productivity. RESULTS: All respirable dust samples were below the 90 µg detection limit which, when combined with the largest sample volume, resulted in a minimum detectable concentration of 0.31 mg m(-3). This occurred in a 32-min sample collected when 27 holes were drilled. Quartz was only detected in one air sample; 0.09 mg m(-3) of quartz was found on an 8-min sample collected during a drill maintenance task. The minimum detectable concentration for quartz in personal air samples collected while drilling was performed was 0.02 mg m(-3). The average number of holes drilled during each drilling sample was 23. Over the course of the 2-day study, air flow measured at the dust collector decreased from 2.2 to 1.7 m(3) s(-1). CONCLUSIONS: The dust control performed well under the conditions of this test. The initial duct velocity with a clean filter was sufficient to prevent settling, but gradually fell below the recommended value to prevent dust from settling in the duct. The practice of raising the drill between each hole may have prevented the dust from settling in the duct. A slightly higher flow rate and an improved duct design would prevent settling without regard to the position of the drill.


Assuntos
Poluentes Ocupacionais do Ar/análise , Indústria da Construção , Poeira/análise , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Dióxido de Silício/análise , Ventilação/normas , Materiais de Construção/análise , Poeira/prevenção & controle , Monitoramento Ambiental/métodos , Humanos , Exposição por Inalação/análise , Exposição Ocupacional/análise , Quartzo/análise , Ventilação/métodos
5.
Ann Occup Hyg ; 58(9): 1155-67, 2014 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-25261456

RESUMO

OBJECTIVES: The task of grinding sandstone with a 5-inch angle grinder is a major source of exposure to respirable crystalline silica (RCS), known to cause diseases such as silicosis and lung cancer among workers who work with these materials. A shroud may be a suitable engineering control for this task. The objectives of this study were to evaluate the effectiveness of four commercially available shrouds at reducing respirable dust and RCS levels during the task of grinding sandstone using tools and accessories typical of restoration stone work. METHODS: The task of grinding sandstone with a 5-inch angle grinder, equipped with different grinding wheels, was carried out over three trials at a restoration stone masonry site. Photometric and RCS data were collected when a 5-inch grinder, equipped with different grinding wheels, was used to grind sandstone with and without a shroud. A total of 24 short duration samples were collected for each no shroud and with shroud combination. Worker feedback on the practicalities of each shroud evaluated was also collected. RESULTS: Respirable dust concentrations and RCS were both significantly lower (P < 0.001) when the grinders were equipped with a shroud compared with grinders without a shroud. Total geometric mean (GM) photometric respirable dust levels measured when grinding with a shroud were 0.5 mg m(-3), a reduction of 92% compared to grinding without a shroud (7.1 mg m(-3)). The overall GM RCS concentrations were reduced by the use of a shroud by 99%. GM photometric exposure levels were highest when using the Hilti 5-inch diamond grinding cup and Diamond turbo cup and lowest when using the Corundum grinding point. CONCLUSIONS: Concentrations of respirable dust and RCS can be significantly reduced by using commercially available shrouds while grinding sandstone with a 5-inch angle grinder in restoration stonework. The short-term photometric respirable dust and RCS measurements collected with and without a shroud indicate that dust and RCS concentrations are reduced by between 90 and 99%. Supplemental exposure controls such as respiratory protective equipment would be required to reduce worker 8-h time-weighted average RCS exposure to below the Scientific Committee on Occupational Exposure Limits recommended occupational exposure limit value of 0.05 mg m(-3) and the American Conference of Governmental Industrial Hygienists threshold limit value of 0.025 mg m(-3).


Assuntos
Poluentes Ocupacionais do Ar/análise , Materiais de Construção/análise , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Dióxido de Silício/análise , Indústria da Construção , Comportamento do Consumidor , Poeira/análise , Monitoramento Ambiental/métodos , Humanos , Exposição por Inalação/análise , Exposição Ocupacional/análise
6.
Gig Sanit ; (4): 40-4, 2014.
Artigo em Russo | MEDLINE | ID: mdl-25842493

RESUMO

There is experimentally established the change of the migratory activity of pollutants from building materials produced from blast furnace slag throughout their life cycle in the form of a nonlinear wave-like nature as there are appeared newly opened surfaces of a contact with aggressive waters in the process of gradual crushing of materials as a result of destructive mechanical effects on him and corrosive waters with varying pH values. There are established regularities of the migration activity ofpollutants (on the example of heavy metals) as directly dependent on the newly opening surface of the contact of the material with water having a various pH value. There is shown an expediency of introduction of alterations in the procedure for sanitary hygienic assessment of building materials with the addition of industrial waste (Methodical Instructions 2.1.674-97), allowing to take into account the migration of contaminants from them throughout the life cycle.


Assuntos
Materiais de Construção/análise , Poluição Ambiental/prevenção & controle , Resíduos Industriais , Metalurgia , Monitoramento Ambiental/métodos , Recuperação e Remediação Ambiental/métodos , Humanos , Concentração de Íons de Hidrogênio , Resíduos Industriais/análise , Resíduos Industriais/prevenção & controle , Resíduos Industriais/estatística & dados numéricos , Metais Pesados/análise , Federação Russa/epidemiologia
7.
Water Sci Technol ; 68(9): 1950-8, 2013.
Artigo em Inglês | MEDLINE | ID: mdl-24225094

RESUMO

Permeable pavements (PPs) have been in use as stormwater management systems in Canada and the United States for over 20 years. After years of exposure to sediment and debris build-up, surface clogging reduces the infiltration of stormwater and inhibits the hydraulic and environmental functions of the pavement. Removal of surface material has been shown to restore infiltration but the majority of studies have been limited to small-scale testing. This paper presents the results of small- and full-sized equipment testing aimed at restoring surface permeability, including the first testing of regenerative-air and vacuum-sweeping streetsweepers in Ontario. Maintenance achieved partial restoration of PP surface permeability. Post-treatment surface infiltration rates displayed large spatial variability, highlighting that localized conditions throughout the pavement have a confounding influence on the overall effectiveness of maintenance. The impact of maintenance may be improved by establishing regular cleaning intervals and developing instructional guidelines for pavement owners and equipment operators.


Assuntos
Materiais de Construção/análise , Recuperação e Remediação Ambiental/métodos , Hidrocarbonetos/química , Movimentos da Água , Poluição da Água/prevenção & controle , Monitoramento Ambiental , Ontário , Permeabilidade
8.
J Environ Manage ; 110: 27-32, 2012 Nov 15.
Artigo em Inglês | MEDLINE | ID: mdl-22705857

RESUMO

Conservation and preservation of freshwater is increasingly becoming important as the global population grows. Presently, enormous volumes of freshwater are used to mix concrete. This paper reports experimental findings regarding the feasibility of using treated effluents as alternatives to freshwater in mixing concrete. Samples were obtained from three effluent sources: heavy industry, a palm-oil mill and domestic sewage. The effluents were discharge into public drain without danger to human health and natural environment. Chemical compositions and physical properties of the treated effluents were investigated. Fifteen compositional properties of each effluent were correlated with the requirements set out by the relevant standards. Concrete mixes were prepared using the effluents and freshwater to establish a base for control performance. The concrete samples were evaluated with regard to setting time, workability, compressive strength and permeability. The results show that except for some slight excesses in total solids and pH, the properties of the effluents satisfy the recommended disposal requirements. Two concrete samples performed well for all of the properties investigated. In fact, one sample was comparatively better in compressive strength than the normal concrete; a 9.4% increase was observed at the end of the curing period. Indeed, in addition to environmental conservation, the use of treated effluents as alternatives to freshwater for mixing concrete could save a large amount of freshwater, especially in arid zones.


Assuntos
Materiais de Construção/análise , Eliminação de Resíduos Líquidos/métodos , Águas Residuárias/análise , Águas Residuárias/química , Conservação dos Recursos Naturais , Água Doce , Resíduos Industriais/análise , Óleo de Palmeira , Óleos de Plantas/análise , Esgotos/análise , Eliminação de Resíduos Líquidos/economia , Poluição Química da Água/prevenção & controle
9.
J Occup Environ Hyg ; 9(3): 157-65, 2012.
Artigo em Inglês | MEDLINE | ID: mdl-22394370

RESUMO

Dust reduction equipment adapted for single-person operation was evaluated for gas-powered, commercially available cut-off saws during concrete curb cutting. Cutting was performed without dust control and with two individual exposure control methods: wet suppression and local exhaust ventilation (LEV). The wet suppression system comprised a two-nozzle spray system and a 13.3-L hand-pressurized water supply system with an optimum mean flow rate of 0.83 L/min for 16 min of cutting. The LEV system consisted of a spring-loaded guard, an 18.9-L collection bag, and a centrifugal fan with an estimated exhaust rate of 91 ft(3)/min. Task-based, personal filter samples were obtained for four saw operators during cutting durations of 4 to 16 min on five job sites. Seventeen filter samples were collected without dust control, 14 with wet suppression, and 12 with LEV, yielding a geometric mean respirable dust concentration of 16.4 mg/m(3), 3.60 mg/m(3), and 4.40 mg/m(3), respectively. A dust reduction of 78.0% for wet suppression and 73.2% for LEV was observed vs. no dust control. A statistically significant difference (p < 0.001) was also revealed for wet suppression and LEV when compared with no dust control; however, a significant difference (p = 0.09) was not observed between wet suppression and LEV. Despite these significant dust reductions, workers are still projected to exceed the ACGIH 8-hr time-weighted average threshold limit value for quartz (0.025 mg/m(3)) in less than 1 hr of cutting for both dust control methods. Further research is still needed to improve dust reduction and portability of both control methods, but the current LEV system offers important advantages, including a drier, less slippery work area and year-round functionality in cold weather.


Assuntos
Materiais de Construção/análise , Poeira/análise , Exposição por Inalação/prevenção & controle , Exposição Ocupacional/prevenção & controle , Equipamentos de Proteção , Dióxido de Silício/análise , Humanos , Exposição Ocupacional/análise , Ventilação
10.
Waste Manag Res ; 30(9): 981-90, 2012 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-22843348

RESUMO

Strategies for enhancing environmental management are a key focus for the government in the UK. Using a manufacturing company from the construction sector as a case study, this paper evaluates selected interventionist techniques, including environmental teams, awareness raising and staff training to improve environmental performance. The study employed a range of methods including questionnaire surveys and audits of energy consumption and generation of waste to examine the outcomes of the selected techniques. The results suggest that initially environmental management was not a focus for either the employees or the company. However, as a result of employing the techniques, the company was able to reduce energy consumption, increase recycling rates and achieve costs savings in excess of £132,000.


Assuntos
Conservação de Recursos Energéticos/métodos , Indústria da Construção , Resíduos Industriais/prevenção & controle , Gerenciamento de Resíduos/métodos , Conservação de Recursos Energéticos/economia , Materiais de Construção/análise , Inglaterra , Resíduos Industriais/economia , Gerenciamento de Resíduos/economia , Resíduos/análise
11.
Indoor Air ; 20(3): 196-203, 2010 06.
Artigo em Inglês | MEDLINE | ID: mdl-20408902

RESUMO

UNLABELLED: Chronic human exposure to formaldehyde is significantly increased by indoor sources. However, information is lacking on why these exposures appear to persist in older homes with aging sources. We use data from the Relationships of Indoor, Outdoor, and Personal Air study to evaluate 179 residences, most of which were older than 5 years. We assess the dependence of indoor formaldehyde concentrations (C(in)) on building type and age, whole-house air exchange rate, indoor temperature, and seasonal changes. Indoor formaldehyde had mean and median concentrations of 17 ppb, and primarily originated from indoor sources. The factors we analyzed did not explain much of the variance in C(in), probably because of their limited influence on mechanisms that control the long-term release of formaldehyde from aging pressed-wood products bound with urea-formaldehyde (UF) resins. We confirmed that the mitigating effects of ventilation on C(in) decrease with time through the analysis of data for new homes available in the literature, and through models. We also explored source control strategies and conclude that source removal is the most effective way to decrease chronic exposures to formaldehyde in existing homes. For new homes, reducing indoor sources and using pressed-wood with lower UF content are likely the best solutions. PRACTICAL IMPLICATIONS: Formaldehyde concentrations in homes due to indoor sources appear to persist throughout the lifetime of residences. Increases in ventilation rates are most effective in decreasing indoor concentrations in new homes where formaldehyde levels are high or when homes are tight. Consequently, other alternatives need to be promoted such as decreasing the amount of pressed-wood products with urea-formaldehyde (UF) resins in homes or reducing the UF content in these materials.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar em Ambientes Fechados/análise , Materiais de Construção/análise , Monitoramento Ambiental , Formaldeído/análise , Habitação , Madeira , Poluentes Atmosféricos/química , Poluição do Ar em Ambientes Fechados/prevenção & controle , Humanos , Umidade , Estações do Ano , Temperatura , Fatores de Tempo , Ventilação
12.
J Air Waste Manag Assoc ; 60(10): 1262-8, 2010 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-21090554

RESUMO

Particles emitted from gravel processing sites are one contributor to worsening air quality in Taiwan. Major pollution sources at gravel processing sites include gravel and sand piles, unpaved roads, material crushers, and bare ground. This study analyzed fugitive dust emission characteristics at each pollution source using several types of particle samplers, including total suspended particulates (TSP), suspended particulate (PM10), fine suspended particulate (PM2.5), particulate sizer, and dust-fall collectors. Furthermore, silt content and moisture in the gravel were measured to develop particulate emission factors. The results showed that TSP (< 100 microm) concentrations at the boundary of gravel sites ranged from 280 to 1290 microg/m3, which clearly exceeds the Taiwan hourly air quality standard of 500 microg/m3. Moreover, PM10 concentrations, ranging from 135 to 550 microg/m3, were also above the daily air quality standard of 125 microg/m3 and approximately 1.2 and 1.5 times the PM2.5 concentrations, ranging from 105 to 470 microg/m3. The size distribution analysis reveals that mass mean diameter and geometric standard deviation ranged from 3.2 to 5.7 microm and from 2.82 to 5.51, respectively. In this study, spraying surfactant was the most effective control strategy to abate windblown dust from unpaved roads, having a control efficiency of approximately 93%, which is significantly higher than using paved road strategies with a control efficiency of approximately 45%. For paved roads, wet suppression provided the best dust control efficiencies ranging from 50 to 83%. Re-vegetation of disturbed ground had dust control efficiencies ranging from 48 to 64%.


Assuntos
Poluentes Atmosféricos/análise , Poluição do Ar/prevenção & controle , Materiais de Construção/análise , Poeira/análise , Poeira/prevenção & controle , Material Particulado/análise , Monitoramento Ambiental , Umidade , Estações do Ano , Taiwan
13.
Environ Sci Pollut Res Int ; 27(8): 8507-8525, 2020 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-31907809

RESUMO

The extensive waste produced in construction and demolition activities affects the ecological environment, impeding green development in countries worldwide, including China. China has paid increasing attention to managing construction and demolition waste (CDW). However, most of the existing research only qualitatively studies the factors affecting the recycling of CDW and does not reveal the critical factors. Therefore, based on stakeholder theory and the grey-DEMATEL method, this paper aims to identify and quantitatively analyze the critical factors in CDW recycling from the perspective of China. This paper drew the following conclusions: (1) Stakeholders in China's CDW recycling mainly include the government, CDW production units, and CDW recycling units. (2) Public policy, government subsidies, media promotion, human resources, cost, environmental awareness, technological innovation, and supply chain management are the eight dimensions with 13 factors that constitute CDW recycling in China. (3) For the total relations between factors affecting the recycling of CDW in China, the most influential factor is specific legislation and regulations. The factor with the highest degree of prominence is environmental awareness. The factor with the largest net cause value is the rationality of disposal and landfill charges. The factor with the largest net effect value is experienced construction workers. (4) The critical factors in China's CDW recycling include specific legislation and regulations, mandatory degree of normative standards, environmental awareness, the supply of raw materials for CDW recycling units, and the sale of remanufactured products. Finally, this paper identifies the following management implications: (1) the government should prioritize the task of improving specific legislation and regulations, with a focus on a mandatory degree of normative standards. (2) CDW production units should put the task of improving environmental awareness high on their agenda, with a focus on the supply of raw materials for recycling units. (3) CDW recycling units should prioritize the issue of the sale of remanufactured products. This paper also provides a theoretical basis for revealing the critical factors of CDW recycling in other countries or regions.


Assuntos
Indústria da Construção , Materiais de Construção/análise , Reciclagem/métodos , Gerenciamento de Resíduos , China , Indústria da Construção/economia , Materiais de Construção/economia , Humanos , Resíduos Industriais , Gerenciamento de Resíduos/métodos
14.
J Environ Manage ; 90(11): 3436-42, 2009 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-19540649

RESUMO

Combining the use of photocatalysts with cementitious materials is an important development in the field of photocatalytic air pollution mitigation. This paper presents the results of a systematic study on assessing the effectiveness of pollutant degradation by concrete surface layers that incorporate a photocatalytic material - Titanium Dioxide. The photocatalytic activity of the concrete samples was determined by photocatalytic oxidation of nitric oxide (NO) in the laboratory. Recycled glass cullets, derived from crushed waste beverage bottles, were used to replace sand in preparing the concrete surface layers. Factors, which may affect the pollutant removal performance of the concrete layers including glass color, aggregate size and curing age, were investigated. The results show a significant enhancement of the photocatalytic activity due to the use of glass cullets as aggregates in the concrete layers. The samples fabricated with clear glass cullets exhibited threefold NO removal efficiency compared to the samples fabricated with river sand. The light transmittance property of glass was postulated to account for the efficiency improvement, which was confirmed by a separate simulation study. But the influence of the size of glass cullets was not evident. In addition, the photocatalytic activity of concrete surface layers decreased with curing age, showing a loss of 20% photocatalytic activity after 56-day curing.


Assuntos
Materiais de Construção/análise , Vidro/química , Titânio/química , Poluição do Ar/prevenção & controle , Conservação dos Recursos Naturais , Óxidos de Nitrogênio/análise , Óxidos de Nitrogênio/química , Porosidade
15.
Waste Manag ; 29(1): 390-403, 2009 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-18367391

RESUMO

Heavy metal-bearing waste usually needs solidification/stabilization (s/s) prior to landfill to lower the leaching rate. Cement is the most adaptable binder currently available for the immobilisation of heavy metals. The selection of cements and operating parameters depends upon an understanding of chemistry of the system. This paper discusses interactions of heavy metals and cement phases in the solidification/stabilisation process. It provides a clarification of heavy metal effects on cement hydration. According to the decomposition rate of minerals, heavy metals accelerate the hydration of tricalcium silicate (C3S) and Portland cement, although they retard the precipitation of portlandite due to the reduction of pH resulted from hydrolyses of heavy metal ions. The chemical mechanism relevant to the accelerating effect of heavy metals is considered to be H+ attacks on cement phases and the precipitation of calcium heavy metal double hydroxides, which consumes calcium ions and then promotes the decomposition of C3S. In this work, molecular models of calcium silicate hydrate gel are presented based on the examination of 29Si solid-state magic angle spinning/nuclear magnetic resonance (MAS/NMR). This paper also reviews immobilisation mechanisms of heavy metals in hydrated cement matrices, focusing on the sorption, precipitation and chemical incorporation of cement hydration products. It is concluded that further research on the phase development during cement hydration in the presence of heavy metals and thermodynamic modelling is needed to improve effectiveness of cement-based s/s and extend this waste management technique.


Assuntos
Materiais de Construção/análise , Metais Pesados/química , Eliminação de Resíduos/métodos , Conservação dos Recursos Naturais/métodos , Poluição Ambiental/prevenção & controle
16.
Waste Manag ; 29(1): 321-8, 2009 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-18406595

RESUMO

Discarded computer monitors and television sets are identified as hazardous materials due to the high content of lead in their cathode ray tubes (CRTs). Over 98% of lead is found in CRT glass. More than 75% of obsolete electronics including TV and CRT monitors are in storage because appropriate e-waste management and remediation technologies are insufficient. Already an e-waste tsunami is starting to roll across the US and the whole world. Thus, a new technology was developed as an alternative to current disposal methods; this method uses a concrete composite crosslinked with minute amounts of biopolymers and a crosslinking agent. Commercially available microbial biopolymers of xanthan gum and guar gum were used to encapsulate CRT wastes, reducing Pb leachability as measured by standard USEPA methods. In this investigation, the synergistic effect of the crosslinking reaction was observed through blending two different biopolymers or adding a crosslinking agent in biopolymer solution. This CRT-biopolymer-concrete (CBC) composite showed higher compressive strength than the standard concrete and a considerable decrease in lead leachability.


Assuntos
Biopolímeros/química , Materiais de Construção/análise , Apresentação de Dados , Chumbo/química , Eliminação de Resíduos/métodos , Ácidos Bóricos/química , Eletrônica , Poluição Ambiental/prevenção & controle , Galactanos/química , Vidro , Substâncias Perigosas/análise , Mananas/química , Estrutura Molecular , Gomas Vegetais/química , Polissacarídeos Bacterianos/química
17.
J Occup Environ Hyg ; 6(10): 624-31, 2009 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-19626530

RESUMO

Several sources of man-made vitreous fibers (MMVFs) may exist in an office environment causing irritation symptoms among occupants. In 258 office buildings, the occurrence and density of settled MMVFs on surfaces were measured by two sampling methods. Altogether, 1113 samples of settled dust were collected from surfaces with plastic bags and gelatine tape and were analyzed with a scanning electron microscope and a stereomicroscope, respectively. Tape samples from 68 buildings were collected from frequently cleaned (n = 162) and seldom cleaned (n = 57) room surfaces in 56 and 29 offices, respectively, and from supply air ducts (n = 24) in 10 offices. MMVFs longer than 20 microm were counted with a stereomicroscope. Irritation symptoms were recorded with a questionnaire. More than 60% of the surface dust and almost 90% of the samples collected from supply air ducts contained MMVFs. The density of MMVFs longer than 20 microm ranged from < 0.1 to 5 fiber cm(- 2). The mean density of the MMVFs was about two times higher on the seldom cleaned surfaces than on the frequently cleaned surfaces. The density was usually under 0.2 MMVF cm(- 2) in surface dust of offices without emission sources of MMVFs. The measurements combined with qualitative analysis of settled dust can help to localize relevant sources of fiber emissions. Altogether, in 40% of the buildings, several occupants had repeated irritation symptoms that were verified by occupational health care personnel.


Assuntos
Poluentes Ocupacionais do Ar/análise , Poluição do Ar em Ambientes Fechados/análise , Materiais de Construção/análise , Poeira/análise , Fibras Minerais/análise , Poluição do Ar em Ambientes Fechados/estatística & dados numéricos , Materiais de Construção/estatística & dados numéricos , Poeira/prevenção & controle , Monitoramento Ambiental , Finlândia , Fibras Minerais/estatística & dados numéricos , Local de Trabalho
18.
Environ Sci Pollut Res Int ; 26(19): 19228-19240, 2019 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-31069650

RESUMO

The accumulation of desulfurization ash from coal-fired power plants can lead to serious waste of land resources and environmental safety problems. This work presents an experimental study on the feasibility of recycling original desulfurization ash as the main raw materials, and a new green grouting material was prepared. The results indicate that a desulfurization ash-based grouting fire prevention material which was prepared according to the following ingredient design (a water-to-solid ratio of 1.0:1 and a hydroxyethyl cellulose content of 0.09% desulfurization ash, 12% quicklime, 0.6% Na2SO4, and 0.05% triethanolamine, 80 °C curing). The slurry's viscosity meets requirements, and its suspension, liquidity, and consolidation strength are better than those of clay under the same conditions. In addition, the grouting material's inhibitor ratio is increased with temperature increase, which means it has good flame retardancy. Environmental performance tests concluded that when desulfurization ash as-recycled admixture is used for the preparation of grouting fire prevention material, from the technique point of view, the environmental safety of them is very good.


Assuntos
Cinza de Carvão/química , Materiais de Construção/análise , Poluição Ambiental/prevenção & controle , Incêndios/prevenção & controle , Reciclagem/métodos , Sulfatos/análise
19.
Environ Sci Pollut Res Int ; 25(5): 4371-4386, 2018 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-29181758

RESUMO

This work is focused on the development of an innovative multi-analytical methodology to estimate the impact suffered by building materials in coastal environments. With the aim of improving the in situ spectroscopic assessment, which is often based on XRF and Raman spectrometers, diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy was implemented in the diagnosis study. In this way, the additional benefits from DRIFT were compared to the usual in situ analyses of building materials, which often have interferences from fluorescence and reststrahlen effects. The studies were extended to the laboratory scale by µ-X-ray fluorescence (µ-XRF) cross-section mapping and ion chromatography (IC), and the IC quantitative data were employed to develop thermodynamic models using the ECOS-RUNSALT program, with the aim of rationalizing the behavior of soluble salts with variations in the temperature and the relative humidity (RH). The multi-analytical methodology allowed identification of the most significant weathering agents and classification of the severity of degradation according to the salt content. The suitability of a DRIFT portable device to analyze these types of matrices was verified. Although the Kramers-Kronig algorithm correction proved to be inadequate to decrease the expected spectral distortions, the assignment was successfully performed based on the secondary bands and intensification of the overtones and decreased the time needed for in situ data collection. In addition, the pollutants' distribution in the samples and the possible presence of dangerous compounds, which were not detected during the in situ analysis campaigns, provided valuable information to clarify weathering phenomena.


Assuntos
Materiais de Construção/análise , Monitoramento Ambiental/métodos , Poluentes Ambientais/análise , Oceano Atlântico , Clima , Espanha
20.
Chemosphere ; 197: 451-456, 2018 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-29360598

RESUMO

This report describes the use of porous concrete at the bottom of a sewage trap to prevent runoff of non-point heavy metals into receiving waters, and, secondarily, to reduce total runoff volume during heavy rains in urbanized areas while simultaneously increasing the recharge volume of heavy-metal-free water into underground aquifers. This idea has the advantage of preventing clogging, which is fundamentally very important when using pervious materials. During actual field experiments, two important parameters were identified: maximum adsorption weight of lead and zinc by the volume of porous concrete, and heavy metal recovery rate by artificial acidification after adsorption. To understand the effect of ambient heavy metal concentration, a simple mixing system was used to adjust the concentrations of lead and zinc solutions. The concrete blocks used had been prepared for a previous study by Harada & Komuro (2010). The results showed that maximum adsorption depended on the ambient concentration, expressed as the linear isothermal theory, and that recovery depended on the final pH value (0.5 or 0.0). The dependence on pH is very important for recycling the porous concrete. A pH of 0.5 is important for recycling both heavy metals, especially zinc, (8.0-22.1% of lead and 42-74% of zinc) and porous concrete because porous concrete has not been heavily damaged by acid. However, at a pH of 0.0, the heavy metals could be recovered: 30-60% of the lead and 75-125% of the zinc. At a higher pH, such as 2.0, no release of heavy metals occurred, indicating the safety to the environment of using porous concrete, because the lowest recorded pH of rainfall in Japan is. 4.0.


Assuntos
Materiais de Construção/análise , Chumbo/análise , Poluição Química da Água/prevenção & controle , Zinco/análise , Adsorção , Japão , Metais Pesados/análise , Porosidade , Chuva , Reciclagem , Esgotos , Poluição Química da Água/análise , Poluição Química da Água/estatística & dados numéricos
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