RESUMEN
In the crystal structure of the polymeric title compound, {[Pb(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)]·H(2)O}(n), the six-coordinate Pb(II) ion is chelated by two 4-ethyl-benzoate (PEB) anions and is bridged by two nicotinamide (NA) ligands, forming a polymeric chain running along the b axis. The carboxyl-ate groups of the PEB ions are twisted away from the attached benzene rings by 4.0â (6) and 13.3â (5)°. The two benzene rings of the PEB ions bonded to the same metal ion are oriented at a dihedral angle of 87.4â (3)°. In the polymeric chain, the NA ligand is linked to one of the carboxyl-ate groups via N-Hâ¯O hydrogen bonding. In the crystal, adjacent polymeric chains inter-act via N-Hâ¯O and weak C-Hâ¯O hydrogen bonds; and the lattice water mol-ecule links with the polymeric chains via N-Hâ¯O and O-Hâ¯O hydrogen bonding. π-π stacking between the benzene and the pyridine rings [centroid-centroid distance = 3.805â (5)â Å] and weak C-Hâ¯π inter-actions are also observed in the crystal structure.
RESUMEN
The title Cu(II) complex, [Cu(C(9)H(9)O(2))(2)(C(10)H(14)N(2)O)(2)(H(2)O)(2)], contains two 4-ethyl-benzoate (PEB) ligands, two monodentate diethyl-nicotinamide (DENA) ligands and two water mol-ecules. The four O atoms in the equatorial plane around the Cu(II) ion form a slightly distorted square-planar arrangement, while the distorted octa-hedral coordination is completed by the two N atoms of the DENA ligands in the axial positions. Intra-molecular O-Hâ¯O hydrogen bonds link the water mol-ecules to the carboxyl-ate groups. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 4.6â (3) and 3.7â (2)°, while the pyridine rings and the benzene rings are oriented at dihedral angles of 6.82â (11) and 3.63â (14)°. In the crystal, inter-molecular O-Hâ¯O hydrogen bonds link the mol-ecules into chains propagating along [010]. C-Hâ¯O inter-actions and a π-π contact between the pyridine rings [centroid-centroid distance = 3.469â (2)â Å] are also observed.
RESUMEN
The title Zn(II) complex, [Zn(C(9)H(9)O(2))(2)(C(6)H(6)N(2)O)(2)], contains two 4-ethyl-benzoate and two nicotinamide monodentate ligands, leading to a distorted tetrahedral coordination of the Zn(II) ion. The dihedral angles between the carboxyl-ate groups and the adjacent benzene rings are 10.33â (13) and 2.38â (11)°, while opposite pyridine and benzene rings are oriented at dihedral angles of 68.46â (5) and 81.09â (6)°. In the crystal, inter-molecular N-Hâ¯O hydrogen bonds link the mol-ecules, forming a three-dimensional network. C-Hâ¯O inter-actions also occur as well as two weak C-Hâ¯π inter-actions involving the benzene rings.