RESUMEN
Flexible and green energy storage devices have a wide range of applications in prospective electronics and connected devices. In this study, a new eco-friendly bilayer separator and primary and secondary paper supercapacitors based on manganese dioxide (MnO2)/carbon black (CB) are developed. The bilayer separator is prepared via a two-step fabrication process involving freeze-thawing and nonsolvent-induced phase separation. The prepared bilayer separator exhibits superior porosity of 46%, wettability of 46.5°, and electrolyte uptake of 194% when compared with a Celgard 2320 trilayer separator (39%, 55.58°, and 110%). Moreover, lower bulk resistance yields a higher ionic conductivity of 0.52 mS cm-1 in comparison to 0.22 mS cm-1 for the Celgard separator. Furthermore, the bilayer separator exhibits improved mean efficiency of 0.44% and higher specific discharge capacitance of 13.53%. The anodic and cathodic electrodes are coated on a paper substrate using MnO2/CB and zinc metal-loaded CB composites. The paper supercapacitor demonstrates a high specific capacitance of 34.1 mF cm-2 and energy and power density of 1.70 µWh cm-2 and 204.8 µW cm-2 at 500 µA, respectively. In summary, the concept of an eco-friendly bilayer cellulose separator with paper-based supercapacitors offers an environmentally friendly alternative to traditional energy storage devices.
RESUMEN
The work described herein details the deployment of an optical fibre strand with five fibre Bragg grating (FBG) sensors for individual cell-level temperature monitoring of a three-cell lithium-ion battery pack. A polymer guide tube with 3D printed plinths is employed, resulting in high precision temperature readings with an average error of 0.97 °C, 1.33 °C, and 1.27 °C for FBG sensors on each battery cell, surpassing traditional thermocouple and platinum resistance sensors in some circumstances. The temperature response of FBGs positioned between battery cells demonstrates that, in addition to sensing temperature at the cell level, temperature data can be effectively acquired between cells, suggesting that FBGs may be used to monitor the heat radiated from individual cells in a battery pack.
