The Corrosion Inhibition of Montmorillonite Nanoclay for Steel in Acidic Solution.

The aim of this research is to study the anticorrosive behavior of a coating consisting of modified montmorillonite nanoclay as an inorganic green inhibitor. The anticorrosion protection for mild steel in 1.0 M HCl solution is studied via weight loss, electrochemical methods, SEM, and XRD. The results proved that montmorillonite nanoclay acts as a good inhibitor with a mixed-type character for steel in an acidic solution. Both anodic and cathodic processes on the metal surface are slowed down. There is a clear direct correlation between the added amount of montmorillonite nanoclay and the inhibition efficiency, reaching a value of 75%. The inhibition mechanism involves the adsorption of the montmorillonite nanoclay onto the metal surface. Weight loss experiments are carried out with steel samples in 1.0 M HCl solution at room temperature, and the same trend of inhibition is produced. SEM was used to image the surface at the different stages of the corrosion inhibition process, and also to examine the starting nanoclay and steel. XRD was used to characterize the nanoparticle structure of the coating. Montmorillonite nanoclay is an environmentally friendly material that improved the corrosion resistance of mild steel in an acidic medium.

A novel co-processed olive tree leaves biomass for lead adsorption from contaminated water.

Olive farming is one of the key agricultural activities in Jordan, where nearly 70% of the cultivated land in Jordan is covered with olive trees. Olive harvesting generates massive quantities of agricultural waste which will be an environmental burden if not managed properly. The present study introduces the use of novel co-processed biomass extracted from the olive tree leaves for the adsorption of lead from contaminated water. Several biomass co-processing techniques using different concentrations of sodium hydroxide, phosphoric acid, and the Dead Sea water were investigated and their effect on the removal efficiency was demonstrated. Moreover, the effect of several parameters on the adsorption efficiency including biomass particle size, solution pH, contact time, adsorbent amount, and lead ion concentration was explored. It was inferred that biomass co-processing enhanced the adsorption capacity of lead. It was also found that the adsorption efficiency increased with decreasing biomass particle size due to the increase in surface area. The highest lead removal was attained at an efficiency value of 70% for the 0.1 mm particle size and at a maximum adsorption capacity recorded at pH 5. The foregoing had a negatively charged biomass surface which, as such, favored the cationic adsorption (pHPZC values around 2.8-4.5). For lead biosorption, the process was a rapid process whereby most adsorption was observed within the first 20 min. Concurrently, there were no considerable changes in lead removal thereafter. Theoretically, this was attributed to the decrease in the available adsorption sites on the biomass surface. On the other hand, a continuous increase in the removal efficiency was recorded upon increasing the adsorbent amount. However, there was a continuous decline in the removal efficiency upon an increase in the initial lead concentration. The experimental data were fitted well with Langmuir isotherm (indicating a monolayer adsorption isotherm), while kinetic data showed the best fit with a pseudo-second-order kinetic model.