RESUMEN
The development of efficient electrocatalysts for hydrogen and oxygen evolution reactions (HER and OER) is pivotal for advancing cleaner and sustainable fuel production technologies. The conventional electrocatalysts have limited stability and higher overpotentials, and there is demand to explore advanced materials and synthesis methods. In this context, a novel bifunctional electrocatalyst has been devised through the phosphidation of tungsten molybdenum oxide (P-Mo0.69W0.31H0.98O3) at relatively low temperatures. This innovative approach aims to enhance the efficiency of HER and OER while minimizing the overpotential values and maintaining higher stability. Specifically, the individual performance of Mo0.69W0.31H0.98O3 has been significantly boosted by doping it with phosphorus at a low temperature of 300 °C. This doping process results in a unique morphology for the catalyst, leading to a notable improvement in OER/HER performances. P-Mo0.69W0.31H0.98O3 exhibits a potential of 320 mV at 10 mA cm-2 in a KOH electrolyte, demonstrating both high activity and long-term stability. Additionally, P-Mo0.69W0.31H0.98O3 exhibits commendable HER performance, requiring only 380 mV at 100 mA cm-2. This combination of efficient OER and HER performance positions P-Mo0.69W0.31H0.98O3 as representing a significant advancement in the field of electrocatalysis, additionally addressing the fundamental gap by providing stable and hybrid catalyst for various electrochemical devices. Given its cost-effectiveness and exceptional activity, P-Mo0.69W0.31H0.98O3 holds significant potential for advancing the field of electrocatalysis and contributing to the development of cleaner and sustainable fuel production methods.
RESUMEN
The advancement in electrocatalysis, particularly in the development of efficient catalysts for hydrogen and oxygen evolution reactions (HER and OER), is crucial for sustainable energy generation through processes like overall water splitting. A notable bifunctional electrocatalyst, CoFe2O4/Co7Fe3, has been engineered to facilitate both OER and HER concurrently, aiming to reduce overpotentials. In the pursuit of further enhancing catalytic efficiency, a morphological transformation has been achieved by introducing a sulphur source and multi-walled carbon nanotubes (MWCNTs) into the catalyst system, resulting in S-CoFe2O4/Co7Fe3/MWCNTs. This modification has significantly improved the activity for both OER and HER. An onset overpotential of 250 mV@10 mAcm-2 for the OER and 270 mV@50 mAcm-2 for the HER, indicating efficient catalytic activity at relatively low overpotentials. S-CoFe2O4/Co7Fe3/MWCNTs display an outstanding long-term stability in alkaline electrolytes, with minimal Tafel slopes of 77 mV/dec for the OER and 70 mV/dec for the HER, suggesting sustained catalytic performance over extended periods. Furthermore, when employed as both the cathode and anode in the context of complete water splitting, S-CoFe2O4/Co7Fe3/MWCNTs demonstrate an impressive cell voltage of 1.52 V at a current density of 10 mA cm-2 in a 1 M KOH solution, showcasing its viability for practical applications. Given its cost-effectiveness and superior activity, S-CoFe2O4/Co7Fe3/MWCNTs hold significant promise for widespread applications in overall water splitting electrocatalysis, contributing to the advancement of cleaner and sustainable fuel generation technologies.
