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1.
Science ; 353(6306): 1424-1427, 2016 09 23.
Artículo en Inglés | MEDLINE | ID: mdl-27608666

RESUMEN

One of the most repeatable phenomena seen in the atmosphere, the quasi-biennial oscillation (QBO) between prevailing eastward and westward wind jets in the equatorial stratosphere (approximately 16 to 50 kilometers altitude), was unexpectedly disrupted in February 2016. An unprecedented westward jet formed within the eastward phase in the lower stratosphere and cannot be accounted for by the standard QBO paradigm based on vertical momentum transport. Instead, the primary cause was waves transporting momentum from the Northern Hemisphere. Seasonal forecasts did not predict the disruption, but analogous QBO disruptions are seen very occasionally in some climate simulations. A return to more typical QBO behavior within the next year is forecast, although the possibility of more frequent occurrences of similar disruptions is projected for a warming climate.

2.
Spectrochim Acta A Mol Biomol Spectrosc ; 60(14): 3235-42, 2004 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-15561604

RESUMEN

The design and operation of an apparatus for studying infrared spectra of weakly-bound complexes is described in detail. A pulsed supersonic jet expansion is probed using a tunable Pb-salt diode laser spectrometer operated in a rapid-scan mode. The jet may be fitted with either pinhole or slit shaped nozzles, the former giving lower effective rotational temperatures, and the latter giving sharper spectral lines. Notable features of the apparatus include use of a toroidal multi-pass mirror system to give over 100 passes of the laser through the supersonic jet, use of the normal laser controller for laser sweeping during both setup and data acquisition, and use of a simple semi-automated wavenumber calibration procedure. Performance of the apparatus is illustrated with observed spectra of the van der Waals complex He-OCS, and the seeded helium clusters He(N)-OCS and He(N)-CO.


Asunto(s)
Técnicas de Química Analítica/instrumentación , Rayos Láser , Técnicas de Química Analítica/métodos , Predicción , Sustancias Macromoleculares/química , Programas Informáticos , Espectrofotometría Infrarroja/instrumentación , Espectrofotometría Infrarroja/métodos , Espectrofotometría Infrarroja/tendencias
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