State-of-the-art adsorption and adsorptive filtration based technologies for the removal of trace elements: A critical review.

Water and wastewater are contaminated with various types of trace elements that are released from industrial activities. Their presence, at concentrations above the permissible limit, will cause severe negative impacts on human health and the environment. Due to their cost-effectiveness, simple design, high efficiency, and selectivity, adsorption, and adsorptive filtration are techniques that have received lots of attention as compared to other water treatment techniques. Adsorption isotherms and kinetic studies help to understand the mechanisms of adsorption and adsorption rates, which can be used to develop and optimize different adsorbents. This state-of-the-art review provides and combines the advancements in different conventional and advanced adsorbents, biosorbents, and adsorptive membranes for the removal of trace elements from water streams. Herein, this review discusses the sources of different trace elements and their impact on human health. The review also covers the adsorption technique with a focus on various advanced adsorbents, their adsorption capacities, and adsorption isotherm modeling in detail. In addition, biosorption is critically discussed together with its mechanisms and biosorption isotherms. In the end, the application of various advanced adsorptive membranes is discussed and their comparison with adsorbents and biosorbents is systematically presented.

Application of MALDI-TOF MS for identification of environmental bacteria: A review.

Bacteria play a variety of roles in the environment. They maintain the balance in the ecosystem and provide different ecosystem services such as in biogeochemical cycling of nutrients, biodegradation of toxic pollutants, and others. Therefore, isolation and identification of different environmental bacteria are important to most environmental research. Due to the high cost and time associated with the conventional molecular techniques, matrix-assisted laser desorption ionization-time of flight mass spectrometry (MALDI-TOF MS) has gained considerable attention for routine identification of bacteria. This review aims to provide an overview of the application of MALDI-TOF MS in various environmental studies through bibliometric analysis and literature review. The bibliometric analysis helped to understand the time-variable application of MALDI-TOF MS in various environmental studies. The categorical literature review covers various environmental studies comprising areas like ecology, food microbiology, environmental biotechnology, agriculture, and plant sciences, which show the application of the technique for identification and characterization of pollutant-degrading, plant-associated, disease-causing, soil-beneficial, and other environmental bacteria. Further research should focus on bridging the gap between the phylogenetic identity of bacteria and their specific environmental functions or metabolic traits that can help in rapid advancements in environmental research, thereby, improving time and cost savings.

Functionalization of reverse osmosis membrane with graphene oxide and polyacrylic acid to control biofouling and mineral scaling.

The polyamide reverse osmosis (RO) membrane was modified with graphene oxide (GO), followed by polymerization of acrylic acid (used as an antiscalant) for the reduction of both biofouling and mineral scaling. After functionalization, the water contact angle reduced from 41.7 ± 4.5° for unmodified RO membrane to 24.4 ± 1.3° for the modified RO membranes, which showed that membrane hydrophilicity was significantly enhanced, in addition to the improvement in surface smoothness. The modified membranes were tested for their anti-scaling and anti-biofouling characteristics. When the mineral scaling test was performed using CaSO4 solution as feedwater, the permeate flux was reduced by only 3% as compared to the unmodified RO membrane which encountered up to 22% decline in flux by the end of the experiment. After the scaling test, the membrane surface was characterized by Scanning electron microscopy - energy-dispersive X-ray spectroscopy, Fourier transform infrared, and X-ray diffraction techniques. The results showed that the unmodified RO membrane was fully covered with gypsum precipitates. Whereas, the precipitates were detected only at the highly saturated zones of the water channel i.e. towards the exit of water flow. Additionally, the anti-bacterial test was performed through bacteriostasis rate determination, which showed that the modified membranes inhibited the growth of nearly 95% of the bacterial cells. Further experiments were also performed to investigate the inhibition of both scaling and biofouling by modified RO membranes. Thus, it was found that the polymer-modified GO coated RO membranes were able to diminish both gypsum scaling and biofilm formation demonstrating their potential to control different types of membrane fouling.

Investigating the effect of temperature on calcium sulfate scaling of reverse osmosis membranes using FTIR, SEM-EDX and multivariate analysis.

Membrane fouling is one of the major hurdles in widespread use of seawater reverse osmosis (SWRO) in desalination industry. There are various factors that affect the inorganic fouling or scaling of Reverse osmosis (RO) membranes. In this research, the effect of temperature on scaling of RO and Graphene oxide (GO) coated RO membrane by calcium sulfate was investigated. It was found that the increase in temperature enhanced the membrane scaling which was evident by the severe flux decline over time leading to increase in mass of crystals precipitated (Mt) and thickness of the scale layer. There was strong positive correlation (R2 ≥ 0.97) noted between Mt and the temperature. The results of SEM-EDX and XRD confirmed that the crystals formed under the experimental conditions are gypsum. Results of this research showed that there was no significant difference in terms of crystal morphology, scaling intensity and mechanism after modifying RO membrane with GO. It was noted that the morphology of the crystals varied from rod shaped to rosette structures under the influence of temperature. Furthermore, the results of FTIR helped to understand the mechanism of interaction between the membranes and the gypsum. The hydrophilicity of the scaled membrane was also measured to investigate the changes in the properties of the membrane after scaling.

Isolation, identification and biodiversity of antiscalant degrading seawater bacteria using MALDI-TOF-MS and multivariate analysis.

Seawater reverse osmosis (SWRO) is a commonly used desalination technique owing to its lesser environmental and economic impacts as compared to thermal desalination techniques. Antiscalants are used in SWRO to reduce membrane scaling caused by the supersaturation of salts present in feed water. However, to remain effective in reducing membrane scaling, antiscalants should be highly stable and resistant to biological degradation by seawater microorganisms. In this research, several bacteria from Qatar's seawater were isolated and screened for their ability to use antiscalants as a carbon and energy source. The biodiversity of antiscalant degrading seawater bacteria was demonstrated through combining the techniques of MALDI-TOF MS and principle component analysis. It was found that the bacteria isolated from Qatar's seawater such as H. aquamarina, H. elongata, P. fragi, P. stutzeri and others can degrade antiscalants and use them as a carbon and energy source. It was observed that the growth rates varied based on the type of antiscalant and the bacteria used. Among the tested strains, H. aquamarina, which is also known for its potential to cause biofouling, demonstrated the highest growth rates in antiscalants media. Thus, it was concluded that there is wide variety of bacteria in Qatar's seawater that can biodegrade the antiscalants; reducing their efficiency to combat membrane scaling. Since, these antiscalants will be used as a source of carbon and energy, microbial growth will increase resulting in enhanced membrane biofouling in SWRO.

Evaluating the effect of antiscalants on membrane biofouling using FTIR and multivariate analysis.

A combination of Fourier-transform infrared (FTIR) spectroscopy, multivariate analysis and conventional microbiological assays were utilized to characterize and differentiate membrane biofouling formed in the presence of antiscalants. Based on the FTIR spectra of biofouled reverse osmosis membranes obtained after incubating with antiscalants and H. aquamarina (as model microorganism), it was found that the biofouling intensity and composition was dependent on the type of antiscalants used. The growth of the bacterium was also highly affected by the type of antiscalants as shown by the colony forming unit (CFU) counts. By combining the techniques of principle component analysis (PCA) and FTIR, it was demonstrated that the biofouling was more intense and composed of proteins, polysaccharides and lipids, when polymer antiscalant was used. By applying PCA-FTIR with CFU counts, faster prediction of the effect of antiscalants on biofouling was made possible.