Emerging Technologies Supporting the Transition to a Circular Economy in the Plastic Materials Value Chain.

Plastic waste has come to the forefront of academic and political debates as a global problem that demands an urgent solution. Promoted by policymakers, academia, and corporations alike, the circular economy model presents a viable path to reach more sustainable levels of development. Emerging and disruptive technologies can catalyse the transition to a circular economy, but their application to the transition of the plastic materials realm is not fully understood. Based on a systematic review of the literature, this paper aims to understand the role of key emerging technologies in the transition towards a circular economy in the plastic materials value chain, their potential impact, as well as the barriers of adoption and diffusion. Employing the ReSOLVE framework, the analysis reveals that rather than individual technologies, four technology sets associated with Industry 4.0, distributed economies, bio-based systems, and chemical recycling stand as major enablers of this transition. The complementarity of technologies and the change needed from a systemic perspective are discussed along with a proposal for governance and practical implementation pathway to overcome barriers and resistance to the transition.

Techno-economics of carbon preserving butanol production using a combined fermentative and catalytic approach.

This paper presents a novel process for n-butanol production which combines a fermentation consuming carbon dioxide (succinic acid fermentation) with subsequent catalytic reduction steps to add hydrogen to form butanol. Process simulations in Aspen Plus have been the basis for the techno-economic analyses performed. The overall economy for the novel process cannot be justified, as production of succinic acid by fermentation is too costly. Though, succinic acid price is expected to drop drastically in a near future. By fully integrating the succinic acid fermentation with the catalytic conversion the need for costly recovery operations could be reduced. The hybrid process would need 22% less raw material than the butanol fermentation at a succinic acid fermentation yield of 0.7g/g substrate. Additionally, a carbon dioxide fixation of up to 13ktonnes could be achieved at a plant with an annual butanol production of 10ktonnes.