1.
Chem Commun (Camb)
; 59(17): 2497-2500, 2023 Feb 23.
Artículo
en Inglés
| MEDLINE
| ID: mdl-36752765
RESUMEN
The first example of Pd(II)-catalyzed anomeric arylation of 3-aminosugars is reported by using an L,X-type transient directing group (TDG) approach combined with an external 2-pyridone ligand. The released free amine was in situ transformed into an azide function, which was then exploited in a CuAAC to increase the molecular complexity and prepare a variety of complex substituted C3-triazolo C-glycosides in good yields.