RESUMEN
Billions of internet connected devices used for medicine, wearables, and robotics require microbattery power sources, but the conflicting scaling laws between electronics and energy storage have led to inadequate power sources that severely limit the performance of these physically small devices. Reported here is a new design paradigm for primary microbatteries that drastically improves energy and power density by eliminating the vast majority of the packaging and through the use of high-energy-density anode and cathode materials. These light (50-80 mg) and small (20-40 µL) microbatteries are enabled though the electroplating of 130 µm-thick 94% dense additive-free and crystallographically oriented LiCoO2 onto thin metal foils, which also act as the encapsulation layer. These devices have 430 Wh kg-1 and 1050 Wh L-1 energy densities, 4 times the energy density of previous similarly sized microbatteries, opening up the potential to power otherwise unpowerable microdevices.
RESUMEN
Thin-film batteries that can be folded, bent, and even repeatedly creased with minimal or no loss in electrochemical performance have been demonstrated and systematically evaluated using two dynamic mechanical testing approaches for either controlled bending or creasing of flexible devices. The results show that mechanically robust and flexible Li-ion batteries (Li4Ti5O12//LiFePO4) based on the use of a nonwoven multiwalled carbon nanotube (MWNT) mat as a current collector (CC) exhibited a 14-fold decrease in voltage fluctuation at a bending strain of 4.2%, as compared to cells using traditional metal foil CCs. More importantly, MWNT-based full-cells exhibited excellent mechanical integrity through 288 crease cycles, whereas the foil full-cell exhibited continuously degraded performance with each fold and catastrophic fracture after only 94 folds. The enhancements due to MWNT CCs can be attributed to excellent interfacial properties as well as high mechanical strength coupled with compliancy, which allow the batteries to easily conform during mechanical abuse. These results quantitatively demonstrate the substantial enhancement offered in both mechanical and electrochemical stability which can be realized with traditional processing approaches when an appropriate choice of a flexible and robust CC is utilized.