1.
Phys Rev Lett
; 117(25): 256102, 2016 Dec 16.
Artículo
en Inglés
| MEDLINE
| ID: mdl-28036213
RESUMEN
X-ray reflectivity (XR) and atomistic molecular dynamics (MD) simulations, carried out to determine the structure of the oil-water interface, provide new insight into the simplest liquid-liquid interface. For several oils (hexane, dodecane, and hexadecane) the XR shows very good agreement with a monotonic interface-normal electron density profile (EDP) broadened only by capillary waves. Similar agreement is also found for an EDP including a sub-Å thick electron depletion layer separating the oil and the water. The XR and MD derived depletions are much smaller than reported for the interface between solid-supported hydrophobic monolayers and water.
2.
Phys Rev Lett
; 105(20): 209401; author reply 209402, 2010 Nov 12.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21231271