Zn-doped mesoporous hydroxyapatites and their antimicrobial properties.

Recently, zinc-based materials have gained immense attention as antimicrobial agents. In this study, zinc-doped mesoporous hydroxyapatites (HAps) with various Zn contents were prepared by co-precipitation using a phosphoprotein as the porous template. The use of the phosphoprotein as the porous template resulted in the formation of zinc-doped mesoporous HAps (mHAps) with large pores and specific surface area (182 m2 g-1), as indicated by the nitrogen adsorption/desorption measurements. The formation of the zinc-doped HAps was confirmed by various analytical techniques such as X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and X-ray photoelectron spectroscopy. The biomaterials prepared in this study were used as antimicrobial agents against gram-positive (Staphylococcus aureus) and gram-negative (Escherichia coli) bacteria. The Zn2%-mHAp sample showed the maximum bacterial inhibitory concentrations of 50 ± 5% and 77 ± 5% for the Gram-positive and Gram-negative bacteria, respectively. The antibacterial activity of the mHAp samples depended strongly on their Zn2+ content. Thus, the use of a biotemplate and Zn2+ ions is an efficient approach for the formation of novel HAp-based biomaterials with promising antibacterial properties. This synthesis approach will pave a new pathway for the functionalization of other materials for different biomedical applications.

Probing the Site-Selective Doping in SrSnO3:Eu Oxides and Its Impact on the Crystal and Electronic Structures Using Synchrotron Radiation and DFT Simulations.

The impact of Eu3+ doping at the Sr2+ and Sn4+ sites in SrSnO3 on its structural and electronic properties was studied and correlated with the photocatalytic efficiency. The compounds were synthesized using a modified Pechini method. Refinement of the synchrotron X-ray diffraction (S-XRD) data showed that the samples had an orthorhombic Pbnm symmetry. The incorporation of Eu into the lattice led to increased short- and long-range disorder, inducing additional distortion in the SnO6. XANES measurements revealed that mixed Eu valences (Eu3+ and Eu2+) were present in Eu-doped samples, and DFT calculations confirmed the presence of these ions at Sr2+/Sr4+ sites in the SrSnO3, resulting in changes in the electronic behavior. The catalytic performance toward Remazol yellow dye photodegradation and the catalysts' surface properties were also evaluated. The catalytic efficiency followed the order of Sr(Sn0.99Eu0.01)SnO3 > (Sr0.99Eu0.01)SnO3 > SrSnO3. The order was clearly related to selected-site doping that changed the degree of the inter- and intraoctahedral distortion and the introduction of different Eu midgap states, which apparently favor charge separation upon photoexcitation during photocatalysis. The results shown here are of great importance to the functionalization of SrSnO3 and other perovskite materials by lanthanoid ions, especially Eu3+, for effective applications as photocatalysts.