A porous micro/nano-structured polyethylene film prepared using a picosecond laser for agricultural passive cooling.

Passive cooling materials, as a promising choice for mitigating the global energy crisis, have limited use as their cooling effects are usually weakened or lost by dust contamination. In this study, a passive cooling polyethylene (PE) film with self-cleaning properties is prepared by picosecond laser ablation. Numerous root-like hierarchical porous micro/nano-structures were obtained on the double side of the PE film. The outside (toward air) shows excellent self-cleaning, corrosion resistance, and anti-friction properties. The inside (towards crops) further reduced the transmittance and water vapor evaporation (keeping the soil moist). Compared with the pristine PE film, the transmittance of the as-prepared double-sided micro/nano-structured PE film decreased by about 40%. In addition, during the crop cultivation experiment, the temperature of the crop leaves was reduced by 2.7-7 °C and showed a higher plant height and greater leaf width under the cover of the laser-treated film. This demonstrates that the passive cooling PE film has an excellent temperature regulation ability and good practical application effects. This study proposes a simple strategy based on a picosecond laser for the preparation of passive cooling materials, which are beneficial for alleviating energy crises and promoting sustainable development.

Aluminum-Based Heterogeneous Surface for Efficient Solar Desalination and Fog Harvesting Processed by a Picosecond Laser.

Solar desalination and fog harvesting are two common ways to obtain fresh water, and both are promising methods to solve the water shortage problem. However, through either the fabrication of interfacial evaporators for solar desalination or the preparation of superwetting surfaces for fog harvesting, current methods suffer from long preparation times, high costs, and low efficiency. Herein, we report an efficient and simple method to process heterogeneous surfaces (HSs) on aluminum (Al) by picosecond laser processing combined with chemical treatment used for fog harvesting and seawater desalination. The as-prepared HS simultaneously consists of regular periodic stripe structures with superhydrophilicity and superhydrophobicity. The spacing of the superhydrophilic and superhydrophobic regions can be adjusted through the processing path. This surface has a 44% improvement in fog harvesting efficiency compared to a pristine Al sheet, which is 0.53 kg·m-2·h-1. Furthermore, it shows a high evaporation rate of 2.35 kg·m-2·h-1 under one sun irradiation with an energy efficiency of 52.39%. Such functional surfaces can be applied to obtain fresh water resources in both coastal regions and arid areas, where water mist is relatively abundant, providing reference and guidance for fresh water collection, and being a promising way to solve the water shortage problem.

Periodic Heterogeneous Surface with Superhydrophilic/Superhydrophobic Stripes Processed by a Picosecond Laser.

Heterogeneous surface with superhydrophilic/superhydrophobic stripes (HS-s/sS) has great practical significance, which can be used in fuel cell water management, condensation heat transfer enhancement, underwater drag reduction. Herein, a fast and simple method for uniform HS-s/sS on several mesh materials, including copper, stainless steel, and nickel, is achieved by using picosecond (ps) laser line-by-line scanning. Note that the scanning period between the lines is kept constant during processing, the HS-s/sS is formed by self-organized, while the similar structure cannot be processed on solid metal surfaces using the same parameters. The processing parameters, including scanning speed, defocus amount (DA), scanning period, and single pulse energy are systematically investigated to optimize HS-s/sS fabrication. It is found that the period of processed stripe on the mesh material is ∼1 mm, which is much larger than the scanning period. Interestingly, the as-prepared mesh surface show superhydrophobicity in the convex striped surface and superhydrophilicity in concave striped parts. The scanning electron microscopy results show that the structures on convex stripe are mainly composed of disordered hill-like structures, while the structures on the concave stripe mainly consist of periodic nanostripe structures. Moreover, the proportion of oxygen on the convex stripe is obviously higher than that on the concave stripe. The underlying mechanism of the HS-s/sS formation can be attributed to the interference between surface phonon polaritons (SPP) and the incident picosecond laser, as well as surface shock wave caused by the picosecond laser. We believe that such functional surfaces will be promising candidates for controlling liquid motion and fluid diversion processes.

Reversible Control between Sliding and Pinning on Femtosecond Laser-Treated Nickel Foam Slippery Surfaces.

Bioinspired slippery surfaces with excellent abilities, such as antifouling, anticorrosion, and drag reduction, have gained increasing attention due to their multifunction in chemistry, biology, and medicine. However, the present thermally responsive methods used for in situ paraffin-infused slippery surfaces (PISS) are usually based on a surface heat source or certain specific photothermal materials, which seriously hinders their practical applications. Herein, we present a kind of in situ PISS processed by femtosecond laser on nickel (Ni) foam with reversible droplet behavior between sliding and pinning controlled by a point heat source. By alternately loading and unloading the point heat source, switchable wettability for liquid droplets can be achieved. The reaction time of this smart surface to the temperature change is 4.47 ± 1.14 s. The relationship between droplet volumes and inclined angles on four different surfaces is quantitatively investigated. Furthermore, the as-prepared PISS display an impressive self-healing ability. In addition, by flexibly changing the action path of the point heat source, the droplet can realize the movement of different curves. This functional surface and in situ control method will be a promising candidate for manipulating droplet directional sliding behavior and smart temperature-responsive surfaces.

Highly Sensitive Dual Parameter Sensor Based on a Hybrid Structure with Multimode Interferometer and Fiber Bragg Grating Fabricated by Femtosecond Laser.

A hybrid sensing configuration for simultaneous measurement of strain and temperature based on fiber Bragg grating (FBG) written in an offset multimode fiber (MMF) interferometer using femtosecond laser pulse is proposed and demonstrated. A Mach-Zehnder interferometer is formed by splicing a section of MMF between two single-mode fibers (SMFs) and a high interference fringe of up to 15 dB is achieved. The sensing experimental results show a strain sensitivity of -1.17 pm/µÎµ and 0.6498 pm/µÎµ for the dip of MZI and Bragg peak, while a temperature sensitivity of 42.84 pm/°C and 19.96 pm/°C is measured. Furthermore, the matrix analysis has found that the strain and temperature resolution of the sensor are as high as ±12.36 µÎµ and ±0.35 °C, respectively. In addition, the sensor has merits of simple fabrication, good spectral quality, and high resolution, which shows attractive potential applications in dual-parameter sensing.

Femtosecond laser double pulse Bessel beam ablation of silicon.

Here, a double pulse Bessel beam was acquired by modulating a femtosecond laser Gaussian beam from both spatial and temporal scales. The double pulse Bessel beam ablation of silicon was studied systematically. The experimental results showed that when the time delay was 0.5 ps, the ablation efficiency slightly increased. As the time delay increased from 0.5 to 100 ps, the ablation rate was significantly suppressed, which could be attributed to the fact that the time delay was longer than the time for free electron density reaching its maximum value approximately 150 fs. Moreover, the morphology of the ablation spot indicated that the time delay had a significant effect on the changes in morphology. More importantly, a different time delay affected the percentage of oxygen on the processed spot. Finally, using the double pulse Bessel beam ablation of silicon, controllable antireflection and superhydrophobic functional surfaces could be easily obtained.

Study on ablation threshold of fused silica by liquid-assisted femtosecond laser processing.

The femtosecond laser machining of fused silica in air and liquids is studied. The ablation threshold of fused silica is reduced from 2.22 to ${1.02}\;{{\rm J/cm}^2}$1.02J/cm2. In order to explore the ablation mechanism fabricated in a liquid medium, the absorption characteristics of water and alcohol are studied. It is found that alcohol could absorb more laser energy than water. By analyzing the variation trend of laser-induced electron density based on an ionization model, we find that alcohol requires lower laser energy to reach the electron density standard and form plasma than water and fused silica. Besides, we observe that a laser will induce bubbles in liquids after the formation of plasma, and the bubbles in alcohol will cause stronger impact pressure to the surface of fused silica than those in water. Therefore, the mechanism of threshold reduction should be owed to the assistance of liquids with different characteristics.

Substrate-independent, switchable bubble wettability surfaces induced by ultrasonic treatment.

Surfaces with switchable bubble wettability have attracted increasing interest due to their wide applications in the field of underwater drag reduction, gas collection and site water treatment. In this paper, a fast, simple and substrate-independent method that achieved reversible switching between underwater superaerophilicity and superaerophobicity on femtosecond laser induced superhydrophobic surfaces by alternative ultrasonic treatment in water and drying in air was reported. After laser processing, the as-prepared superhydrophobic surface showed underwater superaerophilicity due to the trapped air layer. In contrast, after ultrasonic treatment, the trapped air layer was removed and after being dipped into water again, the surfaces showed underwater superaerophobicity. The underwater superaerophobic surface easily recovered its superaerophilicity by drying the sample in air. Therefore, the as-prepared superhydrophobic surfaces could capture or repel air bubbles in water by selectively switching between underwater superaerophilicity and superaerophobicity. Furthermore, by combining hole processing and double side treatment, the sample allowed bubbles to pass through when the surface had underwater superaerophilicity and the sample intercepted the bubbles when the surface had underwater superaerophobicity. This switchable bubble wettability may provide an efficient route for gas bubble and water separation.

Ultrafast nano-structuring of superwetting Ti foam with robust antifouling and stability towards efficient oil-in-water emulsion separation.

Massive discharging of oily wastewater has a serious impact on the ecological environment and human health. However, the rapid development of an efficient separation membrane exhibiting anti-fouling and long-term stability for highly emulsified oily wastewater separation remains a challenge. Herein, a superwettable porous Ti foam was fabricated via a facile and ultrafast strategy of femtosecond laser direct writing. The obtained surface possessed numerous nanoparticle-covered nanoripple structures with intriguing superhydrophilicity and underwater superoleophobicity. Further, the laser-treated foam possessed high porosity and exhibited an excellent performance separating oil-in-water emulsions. A high permeation flux up to ∼1900 L m-1 h-1 was achieved, with a separation efficiency of >99% under a negative pressure (-5 kPa). Moreover, the as-prepared foam exhibited outstanding properties of anti-oil fouling and stability, indicating robust reusability for long-term separation application. This work may provide an efficient and low-cost route for overcoming future large-scale oily wastewater separation issues.

Ultrafast Achievement of a Superhydrophilic/Hydrophobic Janus Foam by Femtosecond Laser Ablation for Directional Water Transport and Efficient Fog Harvesting.

Water scarcity is a serious global challenge, especially in arid and desert regions. Functional devices for directional water transport and fog collection have received increasing attention. Existing methods and technologies suffer from low fog-collecting efficiencies, complicated fabrication processes, and high fabrication costs. Herein, we report a simple and low-cost method to rapidly fabricate nanoparticle-covered microstructures on one side of a copper foam surface, using one-step femtosecond laser direct writing technology, which enormously improved processing efficiency. The resulting foam exhibits superhydrophilic/hydrophobic Janus properties. The foam allows water droplets to pass from the hydrophobic side to the superhydrophilic side, but not in the opposite direction. The Janus foam can therefore be used for harvesting water in fog environments, and the maximum water-collecting efficiency is 3.7 g cm-2 h-1, which is much better than existing data. The Janus foam exhibits excellent stability during abrasion and hydraulic wash tests. This water-collecting design may provide an efficient route for overcoming future water shortages.

Femtosecond laser induced robust periodic nanoripple structured mesh for highly efficient oil-water separation.

Marine oil spills have induced severe water pollution and threatened sea ecosystems, which also result in a loss of energy resources. To deal with this problem, much work has been done for using superhydrophobic or superhydrophilic mesh for oil-water separation. Nevertheless, there are still great challenges in the rapid fabrication of extremely durable mesh with superwetting properties, particularly considering the highly efficient oil-water separation. In this study, we present a simple, efficient method to fabricate superhydrophilic and underwater superoleophobic stainless steel mesh surfaces with one-step femtosecond laser induced periodic nanoripple structures. The as-prepared mesh shows high separation efficiency, which is higher than 99% for various oil-water mixtures. More importantly, the wettability and the separation efficiency of the fabricated mesh show no obvious change after the abrasion tests and corrosion tests, indicating that the as-prepared samples possess robust stability. This study provides an efficient route for constructing durable and highly efficient separation mesh, which can be applied in the cleanup of large-scale oil spills in the near future.