Harnessing the Chemical Functionality of Metal-Organic Frameworks Toward Removal of Aqueous Pollutants.

Wastewater treatment has been bestowed with a plethora of materials; among them, metal-organic frameworks (MOFs) are one such kind with exceptional properties. Besides their application in gas adsorption and storage, they are applied in many fields. In orientation toward wastewater treatment, MOFs have been and are being successfully employed to capture a variety of aqueous pollutants, including both organic and inorganic ones. This review sheds light on the postsynthetic modifications (PSMs) performed over MOFs to adsorb and degrade recalcitrant. Modifications performed on the metal nodes and the linkers have been explained with reference to some widely used chemical modifications like alkylation, amination, thiol addition, tandem modifications, and coordinate modifications. The boost in pollutant removal efficacy, reaction rate, adsorption capacity, and selectivity for the modified MOFs is highlighted. The rationale and the robustness of micromotor MOFs, i.e., MOFs with motor activity, and their potential application in the capture of toxic pollutants are also presented for readers. This review also discusses the challenges and future recommendations to be considered in performing PSM over a MOF concerning wastewater treatment.

Performance analysis of hydrochar derived from catalytic hydrothermal carbonization in the multicomponent emerging contaminant systems: Selectivity and modeling studies.

In this work, as an alternative to pyrochar, catalytic hydrothermal carbonization has been employed to synthesize hydrochar to eliminate emerging contaminants in multicomponent systems. The hydrochar has been synthesized using a single step catalytic hydrothermal carbonization at low temperature (200 °C) without any secondary activation with high specific surface area and very good adsorption efficiency for the removal of emerging contaminants. The synthesized hydrochar (HC200) was characterized using various analytical techniques and found to have porous structure with 114.84 m2.g-1 of specific surface area and also contained various oxygen-containing functionalities. The maximum adsorption efficiencies of 92.4 %, 85.4 %, and 82 % were obtained for ibuprofen, sulfamethoxazole, and bisphenol A, respectively. Humic acid, a naturally occurring organic compound had a negligible effect on the adsorption of the selected contaminants. The hydrochar's selectivity towards the emerging contaminants in binary and ternary multicomponent systems was in the order of ibuprofen > sulfamethoxazole > bisphenol A.

UiO-66 octahedrons for adsorptive removal of direct blue-6: process optimization, interaction mechanism, and phytotoxicity assessment.

The materials for water treatment have been evolving in multitude of dimensions, indicating the importance of water reuse and increasing level of water pollution around the globe. Among the various materials that are utilized in wastewater treatment, the material that has attracted the research community for the past decades is the metal organic framework (MOF). In this work one of the water stable and microporous MOF, UiO-66, and its aminated version has been employed to adsorb an anionic azo dye, direct blue-6 (DB-6), from the aqueous matrix. Performance of both the MOFs was compared to know the efficiency under varying solution conditions. The optimized parameters for DB-6 adsorption by UiO-66 was performed using response surface methodology. This numerical optimization was further extended with canonical and ridge analysis. Under optimal conditions, the materials were exhibiting a good adsorption capacity of 754.4 mg/g. The materials were analyzed in terms of morphology, crystallinity, thermal stability, and surface area using instruments like X-ray diffraction, electron microscopy, thermogravimetric analysis, and BET surface area analysis. The mechanism of interaction between UiO-66 and DB-6 molecule was elucidated with the help of XPS analysis which helps to know the main interacting group of UiO-66. This study was concluded with a phytotoxicity analysis of DB-6 and the antioxidant system of Vigna radiata assessed using pre and post adsorbed water.