1.
Org Biomol Chem
; 21(42): 8593-8602, 2023 Nov 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-37861421
RESUMEN
A palladium-catalyzed decarboxylative α-allylation of thiazolidinones and azlactones with aza-π-allylpalladium zwitterionic intermediates, in situ generated from sulfonamido-substituted allylic carbonates, is successfully developed. This method allows the formation of a series of structurally diverse 5-alkylated thiazolidinones and 2-piperidones under mild conditions in moderate to high yields (up to 99% yield).