Mechanistic insights and applications of lignin-based ultraviolet shielding composites: A comprehensive review.

Lignin is a green aromatic polymer constructed from repeating phenylpropane units, incorporating features such as phenolic hydroxyl groups, carbonyl groups, and conjugated double bonds that serve as chromophores. These structural attributes enable it to absorb a wide spectrum of ultraviolet radiation within the 250-400 nm range. The resulting properties make lignin a material of considerable interest for its potential applications in polymers, packaging, architectural decoration, and beyond. By examining the structure of lignin, this research delves into the structural influence on its UV-shielding capabilities. Through a comparative analysis of lignin's use in various UV-shielding applications, the study explores the interplay between lignin's structure and its interactions with other materials. This investigation aims to elucidate the UV-shielding mechanism, thereby offering insights that could inform the development of high-value applications for lignin in UV-shielding composite materials.

Rapid, tunable synthesis of porous carbon xerogels with expanded graphite and their application as anodes for Li-ion batteries.

The present work reports a rapid, tunable synthesis of resorcinol-formaldehyde (RF) carbon xerogels and their potential application as anode materials for lithium-ion battery. An iron-containing deep eutectic solvent (DES) is applied as both reaction medium and catalyst for the polymerization and graphitization. Water at different levels is employed as a co-solvent to mediate the polymerization and phase separation processes to produce a more-developed porous structure. The established binary-solvent synthesis strategy greatly simplifies the RF carbon xerogel preparation processes with a very short sol-gel time and a more acceptable ambient pressure drying. A duplex carbon configuration of rich microporosity (SBET = 566 m2 g-1) and expanded nanographite is achieved in the binary-solvent system with a DES mass fraction of 70%. The integrated structural merit is highly favorable for lithium storage, showing a reversible capacity of 633 mA h g-1 at 0.1 A g-1 and an excellent rate performance (205 mA h g-1 at 5 A g-1) as well as superior cycling stability.

Choline chloride-zinc chloride deep eutectic solvent mediated preparation of partial O-acetylation of chitin nanocrystal in one step reaction.

An efficient and one step production of acetylated and esterified chitin nanocrystals (CNCs) was successfully achieved using choline chloride-zinc chloride deep-eutectic solvent (ChCl-ZnCl2 DES). In this method, ChCl-ZnCl2 DES with a mole ratio of 1:2, was used for the esterification and O-acetylation of chitin at 90 °C for 3 h and 6 h. This strategy consisted in using ChCl-ZnCl2 DES as a green and non-volatile solvent for chitin under heterogeneous condition that, upon addition of acetic anhydride or acetic acid, simultaneous acetylation or esterification and hydrolysis occurred. The DES act as an efficient catalysis of the functional reaction. The acetylation and hydrolysis proceeded efficiently and the yield of partial acetylated CNCs was ca. 61.6% with DS (degree of substitution) of 0.23 under the optimized conditions. Acetic acid was used to substituted acid anhydride to produce CNCs. The yield of acetic acid induced CNCs was ca. 62.0% with higher DS of 0.34. A thorough investigation of the physicochemical characteristics changes of chitin pointed out that the main skeletal structure of obtained CNCs was intact. The thermal stability of CNCs decreased after treated by ChCl/ZnCl2. In addition, thermal stability of CNCs functionalized with acetic acid is lower than the ones functionalized with acetic anhydride. DES showed low expenditure and toxicity. This approach provides a novel method for production of functional chitin nanocrystals.