Light-driven transport of microparticles with phase-gradient metasurfaces.

Optical tweezers have opened numerous possibilities for precise control of microscopic particles for applications in life science and soft matter research and technology. However, traditional optical tweezers employ bulky conventional optics that prevents construction of compact optical manipulation systems. As an alternative, we present an ultrathin silicon-based metasurface that enables simultaneous confinement and propulsion of microparticles based on a combination of intensity and phase-gradient optical forces. The metasurface is constructed as a water-immersion line-focusing element that enables trapping and transport of 2µm particles over a wide area within a thin liquid cell. We envisage that the type of multifunctional metasurfaces reported herein will play a central role in miniaturized optical sensing, driving, and sorting of microscopic objects, such as cells or other biological entities.

Stiffness control in dual color tomographic volumetric 3D printing.

Tomographic volumetric printing (TVP) physically reverses tomography to offer fast and auxiliary-free 3D printing. Here we show that wavelength-sensitive photoresins can be cured using visible ([Formula: see text] nm) and UV ([Formula: see text] nm) sources simultaneously in a TVP setup to generate internal mechanical property gradients with high precision. We develop solutions of mixed acrylate and epoxy monomers and utilize the orthogonal chemistry between free radical and cationic polymerization to realize fully 3D stiffness control. The radial resolution of stiffness control is 300 µm or better and an average modulus gradient of 5 MPa/µm is achieved. We further show that the reactive transport of radical inhibitors defines a workpiece's shape and limits the achievable stiffness contrast to a range from 127 MPa to 201 MPa according to standard tensile tests after post-processing. Our result presents a strategy for controlling the stiffness of material spatially in light-based volumetric additive manufacturing.

Bioinspired Microstructured Polymer Surfaces with Antireflective Properties.

Over the years, different approaches to obtaining antireflective surfaces have been explored, such as using index-matching, interference, or micro- and nanostructures. Structural super black colors are ubiquitous in nature, and biomimicry thus constitutes an interesting way to develop antireflective surfaces. Moth-eye nanostructures, for example, are well known and have been successfully replicated using micro- and nanofabrication. However, other animal species, such as birds of paradise and peacock spiders, have evolved to display larger structures with antireflective features. In peacock spiders, the antireflective properties of their super black patches arise from relatively simple microstructures with lens-like shapes organized in tightly packed hexagonal arrays, which makes them a good candidate for cheap mass replication techniques. In this paper, we present the fabrication and characterization of antireflective microarrays inspired by the peacock spider's super black structures encountered in nature. Firstly, different microarrays 3D models are generated from a surface equation. Secondly, the arrays are fabricated in a polyacrylate resin by super-resolution 3D printing using two-photon polymerization. Thirdly, the resulting structures are inspected using a scanning electron microscope. Finally, the reflectance and transmittance of the printed structures are characterized at normal incidence with a dedicated optical setup. The bioinspired microlens arrays display excellent antireflective properties, with a measured reflectance as low as 0.042 ± 0.004% for normal incidence, a wavelength of 550 nm, and a collection angle of 14.5°. These values were obtained using a tightly-packed array of slightly pyramidal lenses with a radius of 5 µm and a height of 10 µm.

Polarization-Dependent All-Dielectric Metasurface for Single-Shot Quantitative Phase Imaging.

Phase retrieval is a noninterferometric quantitative phase imaging technique that has become an essential tool in optical metrology and label-free microscopy. Phase retrieval techniques require multiple intensity measurements traditionally recorded by camera or sample translation, which limits their applicability mostly to static objects. In this work, we propose the use of a single polarization-dependent all-dielectric metasurface to facilitate the simultaneous recording of two images, which are utilized in phase calculation based on the transport-of-intensity equation. The metasurface acts as a multifunctional device that splits two orthogonal polarization components and adds a propagation phase shift onto one of them. As a proof-of-principle, we demonstrate the technique in the wavefront sensing of technical samples using a standard imaging setup. Our metasurface-based approach fosters a fast and compact configuration that can be integrated into commercial imaging systems.

Nonlinear optical vortex coronagraph.

A nonlinear optical vortex coronagraph (n-OVC) based on sum-frequency generation (SFG) in a periodically poled lithium niobate (PPLN) crystal is presented. We demonstrate an n-OVC by mixing the image of an on-axis point source ($ {\lambda _s} = 1.6\;{\unicode{x00B5}{\rm m}} $λs=1.6µm) inside the PPLN crystal with a pump beam (${\lambda _p} = 1064\;{\rm nm}$λp=1064nm) imprinted with a helical phase profile from a vector vortex mask (topological charge ${l} = 2$l=2). Due to quasi-phase matching and orbital angular momentum conservation, a coronagraphic image is produced at the SFG wavelength (${\lambda _{\rm up}}\sim 630\;{\rm nm}$λup∼630nm). We validate that the n-OVC is tunable to signal wavelength but only requires a vortex mask operating at the pump wavelength. The acceptance bandwidth of the SFG process provides the n-OVC a degree of achromaticity even with a monochromatic vortex mask. The n-OVC exhibits an inner working angle of $ \sim {\lambda _s}/{D}$∼λs/D and an experimental contrast of ${{10}^{ - 4}}$10-4 at $3{\lambda _s}/{D}$3λs/D.

Optical catapulting of microspheres in mucus models-toward overcoming the mucus biobarrier.

The generalized phase contrast method is employed as an efficient "phase-only" laser beam-shaping technique in an optical setup built for catapulting microspheres through simple mucus models. The influence of the laser power and mucin concentration on the motion of the microspheres is investigated in terms of instant and average velocities on a 250-µm trajectory, corresponding to the mucus thickness in the human gastrointestinal tract. Increasing the laser power leads to higher velocities in all the tested samples, while increasing the mucin concentration leads to significant velocity decrease for similar laser input power. However, velocities of up to 95 µm · s - 1 are demonstrated in a 5% mucin simple mucus model using our catapulting system. This study contributes to understanding and overcoming the challenges of optical manipulation in mucus models. This paves the way for efficient optical manipulation of three-dimensional-printed light-controlled microtools with the ability to penetrate the mucus biobarrier for in vitro drug-delivery studies.

Natural convection induced by an optically fabricated and actuated microtool with a thermoplasmonic disk.

Two-photon polymerization was employed for fabricating microtools amenable to optical trapping and manipulation. A disk feature was included as part of the microtools and further functionalized by electron-beam deposition. The nanostructured gold layer on the disk facilitates off-resonant plasmonic heating upon illumination with a laser beam. As a consequence, natural convection characterized by the typical toroidal shape resembling that of Rayleigh-Bénard flow can be observed. A velocity of several µm·s-1 is measured for 2 µm microspheres dispersed in the surroundings of the microtool. To the best of our knowledge, this is the first time that thermoplasmonic-induced natural convection is experimentally demonstrated using a mobile heat source.