Neurophysiological Assessment of An Innovative Maritime Safety System in Terms of Ship Operators' Mental Workload, Stress, and Attention in the Full Mission Bridge Simulator.

The current industrial environment relies heavily on maritime transportation. Despite the continuous technological advances for the development of innovative safety software and hardware systems, there is a consistent gap in the scientific literature regarding the objective evaluation of the performance of maritime operators. The human factor is profoundly affected by changes in human performance or psychological state. The difficulty lies in the fact that the technology, tools, and protocols for investigating human performance are not fully mature or suitable for experimental investigation. The present research aims to integrate these two concepts by (i) objectively characterizing the psychological state of mariners, i.e., mental workload, stress, and attention, through their electroencephalographic (EEG) signal analysis, and (ii) validating an innovative safety framework countermeasure, defined as Human Risk-Informed Design (HURID), through the aforementioned neurophysiological approach. The proposed study involved 26 mariners within a high-fidelity bridge simulator while encountering collision risk in congested waters with and without the HURID. Subjective, behavioral, and neurophysiological data, i.e., EEG, were collected throughout the experimental activities. The results showed that the participants experienced a statistically significant higher mental workload and stress while performing the maritime activities without the HURID, while their attention level was statistically lower compared to the condition in which they performed the experiments with the HURID (all p < 0.05). Therefore, the presented study confirmed the effectiveness of the HURID during maritime operations in critical scenarios and led the way to extend the neurophysiological evaluation of the HFs of maritime operators during the performance of critical and/or standard shipboard tasks.

Utilization of montmorillonite nanocomposite incorporated with natural biopolymers and benzyl functionalized dicationic imidazolium based ionic liquid coated fiber for solid-phase microextraction of organochlorine pesticides prior to GC/MS and GC/ECD.

A novel montmorillonite clay (MMT) bionanocomposite modified with chitosan (CH), carboxymethyl cellulose (CMC), and benzylimidazolium based dicationic ionic liquid with tetraethylene glycol linker (DIL) was fabricated on stainless steel wire by in situ process. The MMT-CH-CMC-DIL coated solid-phase microextraction (SPME) fiber was examined for the determination of organochlorine pesticides (OCPs) in real samples by HS-SPME-GC method using mass spectrometry (MS) and electron capture detector (ECD). Under optimized conditions, the proposed method exhibited low limits of detection (0.5 ng L-1 with MS and 0.1 ng L-1 with ECD detection), good linearities (R2 = 0.9972-0.9993 with MS and 0.9987-0.9998 with ECD detection), favorable single-fiber repeatability, and fiber-to-fiber reproducibility (less than 8.2% and 9.9% for both types of detection) and high reusability around 125 cycles. Recovery studies were carried out for OCPs in tap water, green tea, and milk samples to verify the applicability of the developed SPME-GC method.

Chitosan and dicationic ionic liquid intercalated clay-coated solid-phase microextraction fiber for determination of sixteen polycyclic aromatic hydrocarbons in coffee and tea samples.

In the present study, solid-phase microextraction (SPME) fiber was prepared by coating clay (MMT)-chitosan (CH) and dicationic ionic liquid (DIL) onto the stainless-steel wire step by step. The characterization of fibers was performed by Fourier transform infrared spectroscopy, thermal analysis, x-ray diffraction analysis, and scanning electron microscopy. The prepared fibers were evaluated for separation and determination of 16 polycyclic aromatic hydrocarbons (PAHs) in coffee and tea samples in headspace- and direct immersion-SPME by coupling with gas chromatography/mass spectrometry. The analytical performance of MMT/CH/DIL fibers was carried out for the extraction of PAHs and compared with the performance of carboxen/polydimethylsiloxane (CAR/PDMS) and divinylbenzene/CAR/PDMS (DVB/CAR/PDMS) fibers under optimized conditions. The wider linear ranges between 0.001 and 25 µg L-1 with a coefficient of determination above 0.9962, low limits of detection between 0.0001 and 0.05 µg L-1 and good intra-day repeatability from 2.45 to 6.48 % and fiber-to-fiber reproducibility from 3.19 % to 8.82 % were obtained for all PAHs in both methods with MMT/CH/octyl (O)-DIL fiber. The extraction recoveries of coffee and tea samples ranged from 87.5 to 112 % using the MMT/CH/O-DIL fiber in both SPME methods.