1.
Angew Chem Int Ed Engl
; 56(37): 11263-11267, 2017 09 04.
Artículo
en Inglés
| MEDLINE
| ID: mdl-28640395
RESUMEN
Deprotonation of [(cAAC)BH2 (CN)] provided clean access to the stable boryl anion, [(cAAC)BH(CN)]- . Whereas the addition of soft electrophiles occurred at the nucleophilic boron center, harder silyl electrophiles added to the harder terminal cyano nitrogen. The resulting [(cAAC)BH(CNSiPh3 )] species behaved like a silylium boryl nucleophile as well as a neutral silylisonitrile borylene.