1.
Chem Commun (Camb)
; 58(51): 7152-7155, 2022 Jun 23.
Artículo
en Inglés
| MEDLINE
| ID: mdl-35667557
RESUMEN
We report a phosphine-directed ruthenium-catalyzed C8-selective alkylation of naphthalenes with alkenes. This protocol provides straightforward access to a large library of electron-rich C8-alkyl substituent 1-naphthphosphines, which outperformed common commercial phosphines and their precursors in the Pd-catalyzed Suzuki-Miyaura coupling of aryl bromides with alkylboronic acid.