A review on titanium oxide nanoparticles modified metal-organic frameworks for effective CO2 conversion and efficient wastewater remediation.

Environmental pollution has been increasing since last decade due to increasing industrialisation and urbanisation. Various kinds ofenvironmental pollutants including carbon dioxide (CO2), dyes, pharmaceuticals, phenols, heavy metals along with many organic and inorganic species have been discovered in the various environmental compartments which possess harmful impacts tox human health, wildlife, and ecosystems. Thus, various efforts have been made through regulations, technological advancements, and public awareness campaigns to reduce the impact of the pollution. However, finding suitable alternatives to mitigate their impacts remained a challenge. Metal-organic frameworks (MOFs) are one of the advanced materials with unique features such as high porosity and stability which exhibit versatile applications in environmental remediation. Their composites with titanium oxide nanoparticles (TiO2) have been discovered to offer potential feature such as light harvesting capacity and catalytic activity. The composite integration and properties have been confirmed through characterization using surface area analysis, scanning electron/transmission electron microscopy, atomic force microscopy, fourier transformed infrared spectroscopy, X-ray diffraction analysis, X-ray photoelectron spectroscopy, thermogravimetric analysis, and others. Thus, this work rigorously discussed potential applications of the MOF@TiO2 nanomaterials for the CO2 capture and effective utilization in methanol, ethanol, acetone, acetaldehyde, and other useful products that served as fuel to various industrial processes. Additionally, the work highlights the effective performance of the materials towards photocatalytic degradation of both organic and inorganic pollutants with indepth mechanistic insights. The article will offer significant contribution for the development of sustainable and efficient technologies for the environmental monitoring and pollution mitigation.

Biopolymer-based beads for the adsorptive removal of organic pollutants from wastewater: Current state and future perspectives.

Among biopolymer-based adsorbents, composites in the form of beads have shown promising results in terms of high adsorption capacity and ease of separation from the effluents. This review addresses the potential of biopolymer-based beads to remediate wastewaters polluted with emerging organic contaminants, for instance dyes, active pharmaceutical ingredients, pesticides, phenols, oils, polyaromatic hydrocarbons, and polychlorinated biphenyls. High adsorption capacities up to 2541.76 mg g-1 for dyes, 392 mg g-1 for pesticides and phenols, 1890.3 mg g-1 for pharmaceuticals, and 537 g g-1 for oils and organic solvents have been reported. The review also attempted to convey to its readers the significance of wastewater treatment through adsorption by providing an overview on decontamination technologies of organic water contaminants. Various preparation methods of biopolymer-based gel beads and adsorption mechanisms involved in the process of decontamination have been summarized and analyzed. Therefore, we believe there is an urge to discuss the current state of the application of biopolymer-based gel beads for the adsorption of organic pollutants from wastewater and future perspectives in this regard since it is imperative to treat wastewater before releasing into freshwater bodies.

A review on the preparation, characterization and potential application of perovskites as adsorbents for wastewater treatment.

Perovskite are among the popular materials utilized in many areas of modern industrialization because of their low price, high stability, excellent oxidation activity, adsorptive, catalytic, optical, magnetic, electronic and ferroelectric properties. Over the years, widespread usage of perovskite nanoparticles has been reported due to its various applications which include an environmental catalyst, fuel cells, chemical sensors, magnetic materials, oxygen permeable membranes and adsorbents for wastewater treatment. Various synthetic methods such as the sol-gel method, proteic method, Pechini method, combustion, co-precipitation, and chelating precursor method have been applied in producing perovskites. Therefore, this review assembles the current knowledge on the processes involved in the preparation of perovskites, their characterizations and potential applications in wastewater treatment. Challenges and future opportunities of perovskite-based materials are discussed as well as obstacles against their extensive uses. Conclusions have also been drawn proposing a few suggestions for future research.

Microcrystalline cellulose (MCC) based materials as emerging adsorbents for the removal of dyes and heavy metals - A review.

In an attempt to overcome such threats posed by water pollution, various processes ranging from physical, chemical as well as biological were applied to get rid of wastewater pollutants. The simplicity, high efficiency and cheapness of an adsorption process make it the most widely used among various other processes. Adsorbents with different properties were used in the adsorption process but this paper was focused on reviewing various articles published by numerous researchers on the isolation of microcrystalline cellulose (MCC), a popular carbohydrate polymer from lignocellulosic biomass and utilization of MCC based materials as effective adsorbents for the successful removal of dyes and heavy metals from synthetic wastewater. The sudden interest on MCC and MCC-based materials as adsorbents cannot be separated from their excellent properties such as renewability, biodegradability, biocompatibility, economic value, non-toxicity, high mechanical properties and surface area. Upon comparison with established adsorbents reported from literature, MCC-based materials performed excellently well in the adsorption of dyes and heavy metals with Langmuir isotherm and pseudo-second order reported mostly as the best fit models for the generated equilibrium and kinetic data, respectively pointing at the distribution of adsorption sites to be homogeneous as well as the formation of monolayer adsorbate on their surfaces. The various thermodynamic studies reported further revealed the adsorption processes of both dyes and heavy metals onto MCC-based materials to be entropy driven processes, spontaneous, and endothermic. Finally, future research was suggested to focus on optimization to enhance the performance of the MCC-based adsorbents, carrying out the adsorption on real wastewater instead of synthetic ones as well as expanding the range of adsorbates to include other contaminants such as chlorophenols, herbicides, pesticides and others in addition to dyes and heavy metals.

An overview of chlorophenols as contaminants and their removal from wastewater by adsorption: A review.

In this review article, a significant number of published articles (over three decades) were consulted in order to provide comprehensive literature information about chlorophenols, their sources into the environment, classification, and toxicity, various wastewater treatment methods for their removal as well as the characteristics of their adsorption by various adsorbents. Organizing the scattered available information on a wide range of potentially effective adsorbents in the removal of chlorophenols is the principal objective of this article. Various adsorbents such as natural materials, waste materials from industries, agricultural by-products and biomass-based activated carbon in the removal of various chlorophenols have been compiled and discussed here. Crucial factors like temperature, solution pH, contact time and initial solution concentration are also reported and discussed here. The π-π dispersion interaction mechanism, hydrogen bonding formation mechanism, and the electron donor-acceptor complex mechanism were proposed for the chlorophenols adsorption onto various adsorbents with the help of current literature. Conclusions have been drawn proposing a few suggestions for future research on mitigating the effect of chlorophenols in the environment.

Physicochemical of microcrystalline cellulose from oil palm fronds as potential methylene blue adsorbents.

The present study sheds light on the physical and chemical characteristics of microcrystalline cellulose (MCC) isolated from oil palm fronds (OPF) pulps. It was found that the OPF MCC was identified as cellulose II polymorph, with higher crystallinity index than OPF α-cellulose (CrIOPFMCC: 71%>CrIOPFα-cellulose: 47%). This indicates that the acid hydrolysis allows the production of cellulose that is highly crystalline. BET surface area of OPF MCC was found to be higher than OPF α-cellulose (SBETOPFMCC: 5.64m2g-1>SBETOPFα-cellulose:Qa0 2.04m2g-1), which corroborates their potential as an adsorbent. In batch adsorption studies, it was observed that the experimental data fit well with Langmuir adsorption isotherm in comparison to Freundlich isotherm. The monolayer adsorption capacity (Qa0) of OPF MCC was found to be around 51.811mgg-1 and the experimental data fitted well to pseudo-second-order kinetic model.