Magnetic Fe3O4 nanoparticles loaded guava leaves powder impregnated into calcium alginate hydrogel beads (Fe3O4-GLP@CAB) for efficient removal of methylene blue dye from aqueous environment: Synthesis, characterization, and its adsorption performance.

In the present work, a novel Fe3O4-GLP@CAB was successfully synthesized via a co-precipitation procedure and applied for the removal of methylene blue (MB) from aqueous environment. The structural and physicochemical characteristics of the as-prepared materials were explored using a variety of characterization methods, including pHPZC, XRD, VSM, FE-SEM/EDX, BJH/BET, and FTIR. The effects of several experimental factors on the uptake of MB using Fe3O4-GLP@CAB were examined through batch experiments. The highest MB dye removal efficiency of Fe3O4-GLP@CAB was obtained to be 95.2 % at pH 10.0. Adsorption equilibrium isotherm data at different temperatures showed an excellent agreement with the Langmuir model. The adsorption uptake of MB onto Fe3O4-GLP@CAB was determined as 136.7 mg/g at 298 K. The kinetic data were well-fitted by the pseudo-first-order model, indicating that physisorption mainly controlled it. Several thermodynamic variables derived from adsorption data, like as ΔGo, ΔSo, ΔHo, and Ea, accounted for a favourable, spontaneous, exothermic, and physisorption process. Without seeing a substantial decline in adsorptive performance, the Fe3O4-GLP@CAB was employed for five regeneration cycles. Because they can be readily separated from wastewater after treatment, the synthesized Fe3O4-GLP@CAB was thus regarded as a highly recyclable and effective adsorbent for MB dye.

Carboxylate-functionalized dragon fruit peel powder as an effective adsorbent for the removal of Rhodamine B (cationic dye) from aqueous solution: adsorption behavior and mechanism.

In this study, we used a simple and low-toxicity chemical treatment to make a carboxylate-functionalized dragon fruit peel powder (CF-DFPP) from dragon fruit peel to improve its capacity for adsorbing Rhodamine B (RhB) from an aqueous medium. Field Emission-Scanning Electron Microscopy/Energy-Dispersive X-ray (FE-SEM/EDX), point of zero charges (pHPZC), Brunauer-Emmett-Teller (BET), and Fourier Transform Infrared (FT-IR) analyses were performed to characterize the adsorbent materials. The adsorption performance and mechanism for the removal of RhB were examined. The kinetic, isotherm and thermodynamic parameters were employed to evaluate the adsorption mechanism. Compared to other models, the Langmuir isotherm and PSO kinetic models better defined the experimental data. CF-DFPP adsorbent exhibited a maximum adsorption efficiency of 228.7 mg/g at 298 K for RhB adsorption. Thermodynamic analysis revealed that the adsorption of RhB by CF-DFPP was spontaneous (ΔGo < 0) and exothermic (ΔHo < 0) nature of the process. Different eluting agents were used in desorption tests, and NaOH was revealed to have greater desorption efficiency (96.8%). Furthermore, regeneration examinations revealed that the biosorbent could effectively retain RhB, even after six adsorption/desorption cycles. These findings demonstrated that the CF-DFPP might be a novel material for removing RhB from an aqueous medium.

Covid-19 and energy sector: Unique opportunity for switching to clean energy.

The novel coronavirus (2019-nCoV) was extended to 213 countries globally by August 2021. The world has been threatened by rising infection rates and emerged as the catastrophic event in the field of health triggering the international emergency panic button. COVID-19's sudden arrival wreaked havoc on the world economic picture, particularly in the energy sector. A steep drop in oil prices, as well as an imbalance in energy, was the result of strict travel restrictions, fewer transportation options, and people's fears of a flu pandemic. However, confined mobility and a drop in energy demand coated the environment with a silver line and drowned the nation's economic opportunities. Industrial transport, and not to mention every conventional energy-related thing, is completely devastated, but renewables were immunized. Wind, solar, hydrothermal, hydrogen, biomass-based energy systems were on high gear yielding maximum results in counterbalancing the demand-supply chain. Moreover, the pandemic created an opportunity to showcase the importance of renewable energy and tackle the difficult emergency like now. In addition to this, the mindset of the investors was slowly fading away from conventional fuels and shifting towards renewable energy. However, it is too early to state the booming renewables at the moment, and no idea about its long-time survival. Thus, the present review gives a clear picture of the current status of fossils and renewables, the impact of a pandemic, energy investments, government policy standings, threats, and opportunities, and finally, the key takeaways avoiding energy scarcity in once a lifetime disaster situation.

Adsorption of Reactive Red 195 from aqueous medium using Lotus (Nelumbo nucifera) leaf powder chemically modified with dimethylamine: characterization, isotherms, kinetics, thermodynamics, and mechanism assessment.

NOVELTY STATEMENT: In the modern era, dyes are inevitable and their surging usage leads to colossal contamination of aqueous streams, thereby threatening both the land and aquatic species. One among such dye is anionic Reactive Red 195 (RR 195), and traceable even at minute concentrations of aqueous streams, posing a severe threat to living species. Moreover, RR 195 is highly recalcitrant offering resistance to biodegradation due to the presence of an azo (-N=N-) group within its structure. Thus, there is a definite need to address the issue of eliminating RR 195 from industrial wastewater effluents. In lieu of this, the primitive objective of this study is to test the effectiveness of the natural adsorbent lotus leaf (Nelumbo nucifera) for the selective sorption of RR 195 from the aqueous stream. Although ample literature is available on the direct utilization of lotus leaf as adsorbent, yet no study was performed on the chemical modification (dimethylamine) of the aforementioned adsorbent. Hence, an attempt has been made in this direction to add a new sorbent into the adsorbents database.

Coal bottom ash derived zeolite (SSZ-13) for the sorption of synthetic anion Alizarin Red S (ARS) dye.

SSZ-13 zeolite was successfully synthesized from coal bottom ash (CBA) upon hydrothermal treatment for selective sorption of Alizarin Red S (ARS) dye. The characterization of CBA, and SSZ-13 were performed using BET, SEM, FTIR, XRF, and XRD techniques. The optimal fusion ratio (CBA: NaOH) was identified as 1:3, resulting zeolite SSZ-13 with a specific surface area of 206.6 m2/g, compared to raw CBA (7.81 m2/g). The kinetics, isotherms, and thermodynamics of the ARS adsorption onto the SSZ-13, and CBA were assessed under various conditions. The results indicated that the adsorption phenomenon is optimal under acidic medium (pH = 2 for CBA, pH = 3 for SSZ-13); at ambient room temperature of 298 K; adsorbent dosage of 0.03 g, contact time of 120 min. Further, the equilibrium data fitted well to Langmuir isotherm (qe = 210.75 mg/g), following pseudo-second-order kinetics. Moreover, the chemisorption phenomenon is clearly described using Elovich kinetic model. Various thermodynamic parameters signifies the adsorption phenomenon is spontaneous, and endothermic in nature. Finally, regeneration studies revealed the sensitivity of SSZ-13 zeolite towards 0.1 M NaOH/EtOH eluent in recovery and the possibility of reuse to five successive adsorption/desorption cycles. Thus, hydrothermal treatment of CBA has potential in producing zeolites suitable to adsorption.

A shock like no other: coronavirus rattles commodity markets.

The novel coronavirus (2019-nCoV) originated in China has now covered around 213 countries globally. It has posed health calamities which have threatened the world with the emergence. Owing to the number of confirmed cases still rising every day, it has now become a phase of an international health emergency. Sudden outbreak of coronavirus disease 2019 (COVID-19) has brought global declines in the commodity process. This has majorly affected the demand as well as supply of the commodities. The oil market has been severely affected due to the outrageous collapse in the demand majorly due to travel restrictions which has also caused the steepest decline in oil prices. The prices of both precious and industrial metals have also fallen, although the price drop is less than that of oil prices. The agriculture industry is one of the least affected so far by this pandemic due to its indirect relation with economic activities. However, the ultimate impact of COVID-19 pandemic will greatly depend on the severity and duration of its outspread, but it is expected to have long-lasting implications.

Correction to: The consequences of coronavirus outbreak on commodity markets.

[This corrects the article DOI: 10.1007/s10668-020-00934-4.].

Inconsistencies of e-waste management in developing nations - Facts and plausible solutions.

Electronic and electrical equipment (EEE) became an integral part of daily life and had an immense influence on the economy. The skyrocketing demand, progressive technologies, and high dependency resulted in inconceivable utilization of EEE. However, these scientific expansions shortened the life span of EEE, thereby generating massive volumes of waste electronic and electrical equipment (WEEE). On a global perspective, Oceania generates a per capita of 17.3 kg/inh (inhabitants), followed by Europe 16.6 kg/inh, America 11.6 kg/inh, Asia 4.2 kg/inh and the least contribution by Africa 1.9 kg/inh. As known, EEE comprises complex metallic and non-metallic fractions causing severe discrepancies within the ecosystem, endangering the living species; if not dealt with properly. Thus, there is a pressing need of immediate addressal on the effective e-waste management strategies both from developed and developing countries. On the spin side, the separation of the precious fractions from the EEE on the end-of-life may be a twin dimensional strategy of economic addition, and plummeting the alarming level threats to ecology. However, these menaces are well tackled by the developed countries to some extent by the stringent law enactments, establishing proper recycling facilities, and trading to the underdeveloped and developing nations. But, the majority of the developing and under developed nations lacks the statutes, gaps in policy making, socio-economic-cultural barriers, technology, and the appropriate treatment facilities. In addition, the review identified ten major shortfalls (10L's) refraining the effective e-waste management, especially in the developing and under developed nations. Among which, integration of the formal and informal sectors, mandated network registry, stringent law enforcements, regulated transboundary movements, manufacturers responsibility, consumer awareness and improved eco designs, investing on effective recycling facilities, and improved disposal facilities holds the key. Further, replacing the traditional and conventional procedures with the futuristic and eco-friendly approaches such as chelation, inducing ionic liquids, integrated processes or hybrid technologies, micro factories, photo catalysis, and green adsorption will substantially harness the current barriers of the e-waste management. Finally, the present review will be a thorough glancing for the future research of e-waste management of meso-micro-macro scales.

Progressive utilisation prospects of coal fly ash: A review.

The rapid surge in global energy needs has paved way for the development of various alternatives to natural resources every now and then. However, dependence on coal-based energy has not reduced greatly. Thus, massive quantities of coal fly ash (CFA) are generated worldwide, which is a serious threat to ecology owing to constraints associated with its storage and disposal. There exists a pressing and ongoing need to develop new, and green product streams from CFA to reduce the threat to the environment. The present review begins with an emphasis on the generation, physicochemical properties, and potential dangers of CFA. Then, it focuses on impending applications such as synthesis of geopolymers (alternative to cement), silica aerogels (insulating materials), carbon nanotubes (carbon allotropes) for electronic devices, and the separation of radioactive isotopes as well as rare earth elements from CFA. Furthermore, the review analyses factors restraining the motive for effective management strategies that drives utilisation of CFA (either in raw and processed state) for new product streams. Finally, the review elucidates the role of CFA as an emerging input in delivering eco-friendly amenities and future derivatives.